• Title/Summary/Keyword: low tin

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A Study on Properties Cu-Sn Matrix Used in Diamond Wheel for Grinding Glass (Diamond Wheel용 Cu-Sn 기지의 유리연삭에 미치는 특성에 관한 연구)

  • Choi, Sung-Kook;Suh, Hyung-Suck;Choe, Jeong-Cheol
    • Journal of Korea Foundry Society
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    • v.12 no.4
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    • pp.317-325
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    • 1992
  • Diamond is the hardest material known to humans, also possesses the highest thermal conductivity and a very low thermal expansion coefficient. Therefore, these properties of diamond make them logical choices for many difficult grinding application. Bonding material is a very important factor to performance of a grinding wheel. Grinding glass constitutes one of the major application areas of diamond grinding wheels, and Cu-Sn tin bronze matrix is widely used as a metal bond of diamond wheel in grinding glass but these studies are rarely reported. The bronze test pieces excluding diamond are sintered by the method of hot sizing respectively at $600^{\circ}C$, $650^{\circ}C$, $700^{\circ}C$, with a composition(Cu-10wt%Sn) on ${\alpha}$ phase and two compositions(Cu-20wt%Sn and Cu-23wt%Sn) on ${\alpha}+{\beta}$ phase. The rupture strength of Cu-10wt%Sn is highest. The bronze bonded diamond wheels are manufactured by same conditions as the bronze test pieces. The results of grinding ratio of wheels are highest in case of Cu-10wt%Sn bonded wheel sintered at $650^{\circ}C$ and grinding power is highest in same composition sintered at $700^{\circ}C$.

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Application of an Interferometric Biosensor Chip to Biomonitoring an Endocrine Disruptor

  • Kim, Byung-Woo;Lim, Sung-Hyuk
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.9 no.2
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    • pp.118-126
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    • 2004
  • Recombinant E.coli ACV 1003 (recA::lacZ) releasing ${\beta}$-galactosidase by a SOS regulon system, when exposed to DNA-damaging compounds, have been used to effectively monitor endocrine disruptors. Low enzyme activity of less than 10 units/mL, corresponding to a $\mu\textrm{g}$/L(ppb) range of an endocrine disruptor (tributyl tin, bisphenol A. etc.), can be rapidly determined, not by a conventional time-consuming and tedious enzyme assay, but by an alternative interferometric biosensor. Heavily boron-doped porous silicon for application as an interferometer, was fabricated by etching to form a Fabry-Perot fringe pattern, which caused a change in the refractive index of the medium including ${\beta}$-galactosidase. In order to enhance the immobilization of the porous silicon surface, a calyx crown derivative (ProLinker A) was applied, instead of a conventional biomolecular affinity method using biotin. This resulted in a denser linked formation. The change in the effective optical thickness versus ${\beta}$-galactosidase activity, showed a linear increase up to a concentration of 150 unit ${\beta}$-galactosidase/mL, unlike the sigmoidal increase pattern observed with the biotin.

Fatigue Strength Assessment of A Longitudinal Hatch Coaming in a 3800 TEU Containership by ABS Dynamic Approach

  • Cui, Weicheng;Yang, Chunwen;Hu, Jiajun
    • Journal of Ship and Ocean Technology
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    • v.3 no.4
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    • pp.35-51
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    • 1999
  • Fatigue strength assessment procedures have been implemented in the ship design rules by many classification societies. However, a large variation tin the details of the different approaches exists in practically all aspects influding load history assessment, stress evaluation and fatigue strength assessment. In order to assess the influences of thesd variations on the prediction of fatigue lives. a comparative study is organized by the ISSC Committee III.2 Fatigue and Fracture. A pad detail on the top of longitudinal hatch coaming of a panamax container vessel is selected for fatigue calculation. The work described in this paper is one set of results of this comparative study in which the ABS dynamics approach is applied. Through this analysis the following conclusions can be drawn. (1) With the original ABS approach, the fatigue life of this pad detail is very low, only 2.398 years. (2) The treatment of the stillwater bending moment in the ABS approach might be a source of conservatism. If the influence of stillwater bending moment is ignored, then the fatigue life for this pad detail is 7.036 years. (3) The difference between the nominal stress approach and the hot spot stress approach for this pad detail is about 26%.

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Preparation of Large Area $TiO_2$ Thin Films by Low Pressure Chemical Vapor Deposition

  • Jeon, Byeong-Su;Lee, Jung-Gi;Park, Dal-Geun;Sin, Se-Hui
    • Korean Journal of Materials Research
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    • v.4 no.8
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    • pp.861-869
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    • 1994
  • Chemical vapor deposition using titanium tetra isopropoxide(TTIP) was employed to investigate effects of process parameters on the uniformity of $TiO_{2}$this films deposited on Indium Tin Oxide (ITO)coated glass. Deposition experiments were carried out at temperatures ranging from $300^{\circ}C$ to $400^{\circ}C$ under the pressure of 0.5~2 torrin a cold wall reactor which can handle 200mm substrate. It was found that the growth rate of $TiO_{2}$was closely related to the reaction temperature and the ractant gas compositions. Apparent activation energy for the deposition rate was 62.7lkJ/mol in the absence of $O_{2}$ and 100.4kj/mol in the presence of $O_{2}$, respectively. Homogeneous reactions in the gas phase were promoted when the total pressure of the reactor was increased. Variance in the film thickness was less than a few percent, but at high deposition rates film thickness was less uniform. Effects of reaction temperature on $TiO_{2}$ thin film characteristic was investigated with SEM, XRD and AES.

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Effect of RF Power on SnO Thin Films Obtained by Sputtering (스퍼터링에 의해 제조된 SnO 박막의 RF 파워에 따른 특성 연구)

  • Um, Joseph;Roh, Byeong-Min;Kim, Sungdong;Kim, Sarah Eunkyung
    • Journal of the Korean Ceramic Society
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    • v.49 no.5
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    • pp.399-403
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    • 2012
  • SnO thin films were fabricated by rf reactive sputtering on borosilicate substrates with an Sn target and Ar/$O_2$ gas mixture. The effect of rf power on the structural, electrical, and optical properties of SnO thin films was investigated with XRD, AFM, SEM, Hall effect measurements, and UV-Vis spectrometer. As a plasma power increased the crystallinity with a preferred orientation of SnO thin films was improved and the grain size slightly increased. However the grains were coalesced and excessively irregular in shape. The electrical conductivity of SnO thin films demonstrated a relatively low p-type conductivity of 0.024 $(Wcm)^{-1}$ at a higher power condition. Lastly, SnO thin films had poor optical transmittance in the visible range as a plasma power increased.

Cobalt Redox Electrolytes in Dye-Sensitized Solar Cells : Overview and Perspectives (염료감응 태양전지용 코발트 전해질의 최신 연구동향 및 전망)

  • Kwon, Young Jin;Kim, Hwan Kyu
    • Current Photovoltaic Research
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    • v.2 no.1
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    • pp.18-27
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    • 2014
  • Dye-sensitized solar cells (DSSCs), developed two decades ago, are considered to be an attractive technology among various photovoltaic devices because of their low cost, accessible dye chemistry, ease of fabrication, high power conversion efficiency, and environmentally friendly nature. A typical DSSCs consists of a dye-coated $TiO_2$ photoanode, a redox electrolyte, and a platinum (Pt)-coated fluorine-doped tin oxide (FTO) counter electrode. Among them, redox electrolytes have proven to be extremely important in improving the performance of DSSCs. Due to many drawbacks of iodide electrolytes, many research groups have paid more attention to seeking other alternative electrolyte systems. With regard to this, one-electron outer sphere redox shuttles based on cobalt complexes have shown promising results: In 2014, porphyrin dye (SM315) with the cobalt (II/III) redox couple exhibited a power conversion efficiency of 13% in DSSCs. In this review, we will provide an overview and perspectives of cobalt redox electrolytes in DSSCs.

AZO Transparent Electrodes for Semi-Transparent Silicon Thin Film Solar Cells (AZO 투명 전극 기반 반투명 실리콘 박막 태양전지)

  • Nam, Jiyoon;Jo, Sungjin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.6
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    • pp.401-405
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    • 2017
  • Because silicon thin film solar cells have a high absorption coefficient in visible light, they can absorb 90% of the solar spectrum in a $1-{\mu}m$-thick layer. Silicon thin film solar cells also have high transparency and are lightweight. Therefore, they can be used for building integrated photovoltaic (BIPV) systems. However, the contact electrode needs to be replaced for fabricating silicon thin film solar cells in BIPV systems, because most of the silicon thin film solar cells use metal electrodes that have a high reflectivity and low transmittance. In this study, we replace the conventional aluminum top electrode with a transparent aluminum-doped zinc oxide (AZO) electrode, the band level of which matches well with that of the intrinsic layer of the silicon thin film solar cell and has high transmittance. We show that the AZO effectively replaces the top metal electrode and the bottom fluorine-doped tin oxide (FTO) substrate without a noticeable degradation of the photovoltaic characteristics.

Metallized Electrospun Nanofiber webs with Bulckled Configuration for Highly Transparent and Stretchable Conductors

  • Jin, Yusung;Hwang, Sunju;Jeong, Soo-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.363.1-363.1
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    • 2016
  • Transparent and stretchable conductors are expected to be an essential component in future stretchable optoelectronic devices. Until now, two main methods have been commonly employed to fabricate transparent and stretchable conductors by using metal nanomaterials: creating buckling configurations and creating network configurations. In this report, a novel strategy for obtaining transparent and stretchable conductors is presented, one that employs these two main approaches simultaneously. To the best of our knowledge, this proposed configuration of a buckled long nanofiber network in this study has not yet been reported. In order to provide the transparent conductors with dual mode stretchability originating from simultaneous buckled and network configurations, a buckled Au@polyvinylpyrrolidone (PVP) nanofiber network (hereafter referred to BANN for convenience) was fabricated by transferring Au-metallized electrospun PVP nanofibers onto a prestrained polydimethylsiloxane (PDMS) substrate. Our BANN shows considerably lower strain sensitivity of resistance than that of straight Au@PVP nanofiber network. Durability tests conducted by performing cyclic tensile strain reveal that the relative change in resistance of BANN (prestrain = 20%) is quite small after 1000 cycles. We also demonstrate that this BANN exhibits superior performance over widely used indium tin oxide conductors with regard to high optical transmittance and low sheet resistance.

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Supercapacitive properties of nickel sulfide coated titanium dioxide nanoparticles

  • Gang, Jin-Hyeon;Ryu, Il-Hwan;Hong, Da-Jeong;Kim, Geu-Rin;Im, Sang-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.156.1-156.1
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    • 2016
  • Nickel sulfide (NiS) is one of the most promising candidates as an electrode material for supercapacitors due to its good capacitive properties, high electrical conductivity and low cost. In addition to the development of the new electrode materials, nanostructuring the electrode surface is one of the main issues in enhancing the capacitive performance of the supercapacitors because the increased surface area can improve the charge transfer and energy storage processes occurring at the electrode surface. However, most nanofabrication techniques require complicated and delicate nanoprocesses, and hence are not suitable for practical use. In this work, we developed a simple method to fabricate nanostructured NiS electrodes by depositing NiS onto $TiO_2$ nanoparticles. First, $TiO_2$ nanoparticles were spin-coated on a fluorine-doped tin oxide (FTO) substrate, and then NiS layers were deposited onto the $TiO_2$ nanoparticles by consecutive dip-coatings in the solutions containing nickel and sulfur precursors. This nanostructured NiS electrode showed significantly improved capacitive properties compared to the electrode of NiS films deposited without $TiO_2$ nanoparticles. The asymmetric full-cell supercapacitor with this nanostructured NiS electrode and activated carbon electrode was also fabricated and investigated.

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Effects of Heat Treatment Temperature and Cooling Method on Microstructure and Hardness of Cu-22Sn alloy (열처리 온도 및 냉각방법이 Cu-22Sn합금의 미세조직 및 경도변화에 미치는 영향)

  • Jeong, Museob;Shin, Ari;Han, Jun Hyun
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.3
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    • pp.104-110
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    • 2018
  • The effects of heat treatment time and cooling method on microstructure and mechanical property of Cu-22wt%Sn alloy were discussed. ${\alpha}+{\delta}$ mixed phase structure was obtained in air-cooled specimens after heat treatment at 775, 750, and $700^{\circ}C$ for 1 hour. On the other hand, in water-cooled specimens, ${\alpha}+{\beta}^{\prime}$ martensite mixed phase was obtained. In the case of water-cooled specimens, the hardness value decreased with decreasing heat treatment temperature because the volume fraction of ${\alpha}$ phase with low hardness value increased as the heat treatment temperature decreased. In water-cooled specimen after heat treatment at $600^{\circ}C$, ${\gamma}^{\prime}$ martensite was formed instead of ${\beta}^{\prime}$ martensite. The hardness value of ${\gamma}^{\prime}$ martensite was lower than those of ${\beta}^{\prime}$ and ${\delta}$ phases.