• Title/Summary/Keyword: low temperature reduction

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The Emission of NO2 and NH3 in Selective Catalytic Reduction over Manganese Oxide with NH3 at Low Temperature (망간계 금속산화물을 이용한 저온 선택적 촉매 환원 반응에서 NO2와 NH3 배출)

  • Kim, Sung Su;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.18 no.3
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    • pp.255-261
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    • 2007
  • The catalytic behavior of the manganese oxides was studied for the selective catalytic reduction with ammonia at a low temperature condition under $200^{\circ}C$. Outlet unreacted ammonia increases with decreasing temperature and increasing $NH_3/NOx$ mole ratio, however $NO_2$ shows an opposite result. $NO_2$ is generated by the adsorption of NO on the catalyst and the following oxidization to nitrates. Unreacted NH3 slip is not observed even at the $NH_3/NOx$ feed ratio above 1.0 due to the reaction between formed nitrates on the catalyst and adsorbed ammonia. The addition of Zr increases $NO_2$ generation, whereas the addition of CeO2 on the catalyst decreases $NO_2$ generation. Furthermore, the additon of the metal oxide induce DeNOx efficiency to reduce.

THE COMPARATIVE STUDY OF THERMAL INDUCTIVE EFFECT BETWEEN INTERNAL CONNECTION AND EXTERNAL CONNECTION IMPLANT IN ABUTMENT PREPARATION (구강내에서 임플랜트 지대주 형성 시 내부연결방식과 외부연결방식간의 열전달 효과 비교)

  • Huh, Jung-Bo;Ko, Sok-Min
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.1
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    • pp.60-70
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    • 2007
  • Statement of problem: The cement-type abutment would be needed for the reduction of its body in order to correct the axis and to assure occlusal clearance. In the case of intraoral preparation, there is a potential risk that generated heat could be transmitted into the bone-implant interface, where it can cause deterioration of tissues around the implant and failed osseointegration. Purpose: The purpose of this study was to assess the difference of the heat transmitting effect on external and internal connection implant types under various conditions. Material and method: For evaluating the effects of alternating temperature, the thermocoupling wires were attached on 3 areas of the implant fixture surface corresponding to the cervical, middle, and apex. The abutments were removed 1mm in depth horizontally with diamond burs and were polished for 30 seconds at low speed with silicone points using pressure as applied in routine clinical practice. Obtained data were analyzed using Mann-Whitney rank-sum test and Wilcoxon / Kruskal-Wallis Tests. Result: Increased temperature on bone-implant interface was evident without air-water spray coolant both at high speed reduction and low speed polishing (p<.05). But, the difference between connection types was not shown. Conclusion: The reduction procedure of abutment without using proper coolant leads to serious damage of oral tissues around the implant irrespective of external and internal connection type.

Comparisons of Low Temperature Combustion Characteristics between Diesel and Biodiesel According to EGR control (EGR 제어를 통한 디젤 및 바이오디젤의 저온연소 특성 비교)

  • Lee, Yong-Gyu;Jang, Jae-Hoon;Lee, Sun-Youp;Oh, Seung-Mook
    • Journal of ILASS-Korea
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    • v.16 no.3
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    • pp.119-125
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    • 2011
  • Due to the oxygen contents in biodiesel, application of the fuel to compression ignition engines has significant advantages in terms of lowering PM formation in the combustion chamber. In recent days, considerable studies have been performed to extend the low temperature combustion regime in diesel engines by applying biodiesel fuel. In this work, low temperature combustion characteristics of biodiesel blends in dilution controlled regime were investigated at a fixed engine operating condition in a single cylinder diesel engine, and the comparisons of engine performances and emission characteristics between biodiesel and conventional diesel fuel were carried out. Results show that low temperature combustion can be achieved at $O_2$ concentration of around 7~8% for both biodiesel and diesel fuels. Especially, by use of biodiesel, noticeable reduction (maximum 50% of smoke was observed at low and middle loads compared to conventional diesel fuel. In addition, THC(total hydrocarbon) and CO(Carbon monoxide) emissions decreased by substantial amounts for biodiesel fuel. Results also indicate that even though about 10% loss of engine power as well as 14% increase of fuel consumption rate was observed due to lower LHV(lower heating value) of biodiesel, thermal efficiencies for biodiesel fuel were slightly elevated because of power recovery phenomenon.

Microwave Dielectric Properties of $ZnWO_4$ Ceramics ($ZnWO_4$ 세라믹의 마이크로파 유전특성)

  • Yoon, Sang-Ok;Yun, Jong-Hun;Kim, Dae-Min;Hong, Sang-Heung;Kang, Ki-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.642-645
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    • 2002
  • Microwave dielectric properties of $ZnWO_4$ ceramic were investigated with calcination and sintering temperatures. The dielectric properties required for such application are high dielectric constant$(\varepsilon_r)$, high $Q{\times}f_o$ value and low temperature coefficient of resonant frequency$(\tau_f)$. These requirement correspond to necessities for size reduction, excellent frequency selectivity, good temperature stability of devices. $ZnWO_4$ ceramics could be sintered at low $1075^{\circ}C$, which was comparatively low temperature for microwave dielectrics. As a result, $ZnWO_4$ showed the dielectric constant of 13, quality factor($Q{\times}f_o$ value) of 22000 and 'temperature coefficient of resonant frequency$(\tau_f)$ of $-65{\pm}5ppm/^{\circ}C$.

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Field Application of the Mass Concrete Utilizing Combined Method for Temperature Crack Reduction (온도균열 저감공법을 복합사용한 매스콘크리트의 현장적용)

  • Han, Sang-Yoon;Lee, Chung-Sub;Baek, Dae-Hyun;Jang, Duk-Bae;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2010.05a
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    • pp.37-39
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    • 2010
  • In this study, with new office construction site of S Construction company as subject, to solve all the problems according to reduced hydration heat and temperature crack of mass concrete used mat foundation and placing time difference, low heat combination of coarse particle cement and fly-ash and setting time difference applied AE water reducing agent, and to prevent the early frost damage caused by low outdoor temperature, a heat insulation method using double bubble sheet was conducted. As a result, it was found that hydration heat and setting time difference was reduced by applying a low heat combination and setting time difference construction method, and that the high insulation capability of the double bubble sheet was able to not only prevent the early frost damage but also reduce temperature difference between the central part and the upper part of mass concrete.

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Expansion of Operating Range and Reduction of BSFC in Low Temperature Diesel Combustion with Boosting (과급을 이용한 저온 디젤 연소의 운전영역 확장 및 연료소비율 저감)

  • Shim, Eui-Joon;Han, Sang-Wook;Jang, Jin-Young;Park, Jung-Seo;Bae, Choong-Sik
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3013-3018
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    • 2008
  • Supercharging system was adopted to investigate the influence of boost pressure on operating range, brake specific fuel consumption (BSFC) and exhaust emissions by using a supercharger at low temperature diesel combustion (LTC) condition in a 5-cylinder 2.7 L direct injection diesel engine. The experimental parameters such as injection quantity, injection timing, injection pressure and exhaust gas recirculation (EGR) rate were varied to find maximum operating range. The result showed that operating range with boost was expanded up to 41.9% compared to naturally aspirated LTC condition due to increased mixing intensity. The boosted LTC engine showed low BSFC value and dramatically reduced soot emission under all operating range compared with high speed direct injection (HSDI) mode. Finally, this paper presents the boosted LTC map of emission and the strategy of improved engine operating range.

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A Study on the exhaust gas characteristics of the vehicle gasoline according to the ambient temperature (대기온도에 따른 휘발유 자동차의 배출가스 특성에 관한 연구)

  • Lim, Jae-Hyuk;Kim, Ki-Ho;Kim, Sung-Woo;Lee, Min-Ho;Oh, Sang-Gi
    • Journal of Power System Engineering
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    • v.19 no.6
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    • pp.47-53
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    • 2015
  • Korea is the geographic location during the summer, the temperature rising to $35^{\circ}C$ and winter temperature is $-15^{\circ}C$ to reduce the air temperature changes, such as relatively large compared to other countries. This increase or decrease of the harmful exhaust gas discharged from automobile substantially inconvenience a significant impact on the active side of the car engine temperature and exhaust gas reducing device receives a large impact on the atmospheric temperature is regulation to be different. However, domestic vehicle emissions test temperature of $20{\sim}30^{\circ}C$ is it does not reflect this situation the actual test temperature to accurately measure the exhaust gas volume of the vehicle is difficult. In this study, domestic automobile exhaust gas test conditions of a test temperature $20{\sim}30^{\circ}C$ various temperatures, including (35, 25, 0, -7, -15, $-25^{\circ}C$) under the two vehicles (2.0L MPI, 2.4 L GDI) as was discussed with respect to the exhaust gas characteristics of the vehicle according to the ambient temperature gas. As a result, domestic emissions test temperature of $25^{\circ}C$ than average conditions were temperature decreases greenhouse gas emissions and increase overall increased by up to 15 times higher. Air temperature and the engine exhaust gas inconvenience a direct effect on the activation temperature required in the reduction unit is determined to be an increase of emissions and greenhouse gases, and also an increase in the variety of lubricants based lubricating and viscosity reduction, such as the engine oil due to the low temperature of these result It is considered that shows the.