• 자원환경지질
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• 제52권2호
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• pp.141-158
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• 2019

경남에 소재하는 삼천포 및 하동 석탄 화력발전소 인근 농경지 토양을 대상으로 중금속 함량을 측정하였다. 삼천포지역 48개, 하동 지역 61개의 표토 및 심토를 대상으로 분석한 결과, Cu, Hg, Ni, Pb, Zn는 모두 토양오염 우려기준 미만으로 나타났으나 Cd는 삼천포 38개, 하동 13개 시료에서 우려기준을 초과하였다. 지질부하지수와 농축계수를 구한 결과 Cd는 높은 오염도를 보였으며 Cd와 Pb는 인위적 오염원에 의한 토양 내 농축인 것으로 보인다. 그러나 연속추출을 통해 중금속의 존재형태를 규명한 결과 Cd를 포함한 토양 내 중금속들은 대부분 용출 가능성이 매우 적은 형태로 존재하여 생물이용도가 낮게 나타났다. 이러한 결과는 석탄 화력발전소 인근 토양이 인위적인 요인으로 인해 Cd로 오염되었으나 인근 생태계로 유입될 가능성은 낮음을 의미한다.

• Membrane and Water Treatment
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• 제10권2호
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• pp.165-178
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• 2019

Mixed matrix membranes (MMMs) of poly (vinyl alcohol) (PVA) containing certain amounts of H-${\beta}$ zeolite for pervaporation were manufactured by using a solution casting protocol. These zeolite-embedded membranes were then characterized with scanning electron microscope (SEM), X-ray diffraction (XRD) and swelling tests. The membrane separation performance has been examined by means of isopropanol (IPA) dewatering from its highly concentrated aqueous solutions via response surface methodology (RSM). The results have demonstrated that the influences of feed IPA composition (85-95 wt.%), feed temperature ($50-70^{\circ}C$), zeolite loading (15-25 wt.%) and their interactive influences are all statistically significant on both pervaporation flux ($398-1228g/m^2{\cdot}h$) and water/isopropanol separation factor (617-2001). The quadratic models based on the RSM analysis have performed excellently to correlate experimental data with very high determination coefficients and very low relative standard deviations. The optimal pervaporation predictions given by using the RSM models demonstrate a total flux of $953g/m^2{\cdot}h$ and separation factor of 1458, and are excellently verified by experimental results. As reflected by these results, PVA MMMs embedded with hydrophilic $H-{\beta}$ zeolite entities have performed considerably better than its pure counterpart and indicated great potential for isopropanol dehydration applications.

• 대한조선학회논문집
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• 제56권4호
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• pp.335-342
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• 2019

The objective of this study is to analyze the mechanical properties of plywood used as a thermal insulating material for LNG CCS (Liquefied Natural Gas, Cargo Containment System). It is created by bonding an odd number of parallel and perpendicular direction for preventing contraction and expansion of wood. Also plywood is widely used as LNG CCS insulating material because of its durability, light weight and high stiffness. Since LNG CCS is loaded with liquid cargo, the impact load by sloshing during operation and the wide temperature range (room temperature, low temperature, cryogenic temperature) exposed during loading, unloading should be considered. The thickness of the plywood which is used for the membrane type MARKIII was selected as the thickness of the test specimen. In this present study, plywood is analyzed by the fracture behavior and mechanical properties of plywood by temperature and grain direction. In addition, it is necessary to analyze the fracture shape and predict the fracture strain by using regression model because the critical load may cause cracks inside the tank, which may affect the leakage of cryogenic liquid.

• Clinical and Experimental Pediatrics
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• 제62권9호
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• pp.344-352
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• 2019

Background: Ventilator dependency constitutes a major problem in the intensive care setting. Malnutrition is considered a major determinant of extubation failure, however, attention has been attracted to modulating carbon dioxide production through decreasing carbohydrate loading and increasing the percent of fat in enteral feeds. The detected interrelation between substrate oxidation and ventilation outcome became the base of several research to determine the appropriate composition of the nonprotein calories of diet in ventilated patients. Purpose: We aimed to assess the effect of high-fat dietary modification and nutritional status on ventilatory and final outcomes of pediatric intensive care. Methods: Fifty-one ventilated children (1 month to 12 years of age) with pulmonary disease who could be enterally fed, in the Cairo University Pediatric intensive care unit, were divided into 2 groups: group A included 25 patients who received isocaloric high-fat, low-carbohydrate diet; group B included 26 patients who received standard isocaloric diet. Comprehensive nutritional assessment was done for all patients. Results: Group A had a significant reduction in carbon dioxide tension, but no similar reduction in the duration or level of ventilatory support. Assisted minute ventilation was predicted by weight-for-age and caloric intake rather than the type of diet. Poor nutritional status was associated with higher mortality and lower extubation rates. Mild hypertriglyceridemia and some gastrointestinal intolerance were significant in group A, with no impact on the adequacy of energy or protein delivery. Conclusion: The high-fat enteral feeding protocol may contribute to reducing carbon dioxide tension, with mild hypertriglyceridemia and negligible gastrointestinal intolerance as potential adverse effects. Optimization of nutritional status rather than dietary modification may improve ventilatory and survival outcomes in critically ill-ventilated children.

• 한국표면공학회지
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• 제52권1호
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• pp.16-22
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• 2019

The structural change of DLC coatings during long-term wear test and dicing test under the low loading condition was investigated. DLC coatings were applied for the precision injection molds of a modified SNCM steel for the extension of life and the micro-diamond blades for the high cutting efficiency and the increase in life. A ball-on-disc wear tests in the mold steel and a dicing tests in the micro-diamond blades were conducted to understand degradation of DLC coatings. The degradation of DLC coatings for the injection mold steel and the micro-diamond blades during the wear and dicing tests were studied with Raman Spectroscopy. Raman peaks were divided two bands(D band and G band) to study the degradation process of DLC structure. By the wear test, polished condition of wear marks were observed to be maintained until 10 hrs of wear test period is given, but small striation marks appeared in 20 hours wear test. It was observed that $I_D/I_G$ ratios changed as the degradation of DLC coatings is proceeded during the wear tests and the dicing tests. It is suggested that the change in $I_D/I_G$ value possibly reflected from the composition of $sp^2$ and $sp^3$ bondings in DLC layers relevant to the change in mechanical and physical property.

• Korean Chemical Engineering Research
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• 제57권3호
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• pp.425-431
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• 2019

As rechargeable metal-air batteries will be ideal energy storage devices in the future, an active cathode electrocatalyst is required with bi-functionality on both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) during discharge and charge, respectively. Here, a class of perovskite cathode catalyst with a micro-tubular structure has been developed by controlling bi-functionality from different Ru and Ni dopant ratios. A micro-tubular structure is achieved by the activated carbon fiber (ACF) templating method, which provides uniform size and shape. At the perovskite formula of $LaCrO_3$, the dual dopant system is successfully synthesized with a perfect incorporation into the single perovskite structure. The chemical oxidation states for each Ni and Ru also confirm the partial substitution to B-site of Cr without any changes in the major perovskite structure. From the electrochemical measurements, the micro-tubular feature reveals much more efficient catalytic activity on ORR and OER, comparing to the grain catalyst with same perovskite composition. By changing the Ru and Ni ratio, the $LaCr_{0.8}Ru_{0.1}Ni_{0.1}O_3$ micro-tubular catalyst exhibits great bi-functionality, especially on ORR, with low metal loading, which is comparable to the commercial catalyst of Pt and Ir. This advanced catalytic property on the micro-tubular structure and Ru/Ni synergy effect at the perovskite material may provide a new direction for the next-generation cathode catalyst in metal-air battery system.

• Earthquakes and Structures
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• 제20권2호
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• pp.149-160
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• 2021

Buildings made using the locally available clay materials are amongst the least expensive forms of construction in many developing countries, and therefore, widely popular in remote areas. It is despite the fact that these low-strength masonry structures are vulnerable to seismic forces. Since transporting imported materials like cement and steel in areas inaccessible by motorable roads is challenging and financially unviable. This paper presents, and experimentally investigates, adobe masonry structures that utilize the abundantly available local clay materials with moderate use of imported materials like cement, aggregates, and steel. Shake-table tests were performed on two 1:3 reduce-scaled adobe masonry models for experimental seismic testing and verification. The model AM1 was confined with vertical lightly reinforced concrete columns provided at all corners and reinforced concrete horizontal bands (i.e., tie beams) provided at sill, lintel, and eave levels. The model AM2 was confined only with the horizontal bands provided at sill, lintel, and eave levels. The models were subjected to sinusoidal base motions for studying the damage evolution and response of the model under dynamic lateral loading. The lateral forcedeformation capacity curves for both models were developed and bi-linearized to compute the seismic response parameters: stiffness, strength, ductility, and response modification factor R. Seismic performance levels, story-drift, base shear coefficient, and the expected structural damages, were defined for both the models. Seismic performance assessment of the selected models was carried out using the lateral seismic force procedure to evaluate their safety in different seismic zones. The use of vertical columns in AM1 has shown a considerable increase in the lateral strength of the model in comparison to AM2. Although an R factor equal to 2.0 is recommended for both the models, AM1 has exhibited better seismic performance in all seismic zones due to its relatively high lateral strength in comparison to AM2.

• Korean Journal of Chemical Engineering
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• 제35권11호
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• pp.2256-2268
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• 2018

Hydrophilic and hydrophobic polyethersulfone (PES)-zinc oxide (ZnO) sublayers were prepared by loading of ZnO nanoparticles into PES matrix. Both porosity and hydrophilicity of the hydrophilic sublayer were increased upon addition of hydrophilic ZnO, while these were decreased for the hydrophobic sublayer. In addition, the results demonstrated that the hydrophilic membrane exhibited smaller structural parameter (S value or S parameter or S), which is beneficial for improving pure water permeability and decreasing mass transfer resistance. In contrast, a higher S parameter was obtained for the hydrophobic membrane. With a 2 M NaCl as DS and DI water as FS, the pure water flux of hydrophilic TFN0.5 membrane was increased from $21.02L/m^2h$ to $30.06L/m^2h$ and decreased for hydrophobic TFN0.5 membrane to $14.98L/m^2h$, while the salt flux of hydrophilic membrane increased from $10.12g/m^2h$ to $17.31g/m^2h$ and decreased for hydrophobic TFN0.5 membrane to $3.12g/m^2h$. The increment in pure water permeability can be ascribed to reduction in S parameter, which resulted in reduced internal concentration polarization (ICP). The current study provides a feasible and low cost procedure to decrease the ICP in FO processes.

• 정보보호학회논문지
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• 제19권5호
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• pp.105-118
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• 2009

현대사회는 IT 기술의 급속한 발달과 초고속망을 통한 인터넷 및 컴퓨터의 보급으로 인해 정보사회라는 새로운 문화적 변환기를 맞이하고 있으며, 다양한 서비스 및 디바이스의 발전을 가져오고 있다. 그러나 보안 측면에서 고려해야 할 요구사항은 더욱 복잡해지고 다양화되고 있으며, 기존의 매체나 프로토콜이 갖고 있는 보안 취약성을 그대로 내포하게 된다. 유비쿼터스 오피스 네트워크 환경에서 이동성을 제공하는 디바이스는 상대적으로 컴퓨팅 능력이 낮아 기존에 개발된 보안 기능의 탑재가 어려우므로 단말 해킹, 바이러스 공격, 정보유출 등 다양한 공격이 시도될 가능성이 높다고 할 수 있다. 이에 대한 대책으로 제안된 PKI 인증 기술은 유비쿼터스 오피스 네트워크 서비스 제공 구조인 멀티도메인 환경에 적용하기에 적합하지 않으며, 변형된 인증체계 개발이 필요하다. 따라서 본 논문에서는 아이디 기반 공개키 방식 및 인가 티켓을 이용하여 안전하고 효율적인 로밍과 Main 디바이스 인증/인가 기술 및 Sub 디바이스 티켓을 이용한 인증/인가 기술에 관한 연구를 통하여 안전성과 효율성을 제공할 수 있다.

• 한국전산구조공학회논문집
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• 제34권2호
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• pp.93-100
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• 2021

현재 우리나라에서 설계 및 시공되는 대부분의 철근콘크리트 벽식구조 공동주택은 상부벽체-하부골조 시스템으로 구성되어 있으며 서로 다른 상하부 구조시스템의 결합을 위해 전이보를 이용한다. 상부의 하중을 하부의 기둥 부재에 효율적으로 전달하기 위해 전이보가 큰 강성을 지녀야 하고 이로 인해 부재의 춤이 커져 많은 물량의 투입되고 전반적인 경제성이 떨어지게 된다. 이러한 문제점을 해결하기 위해 기둥을 벽체요소로 대체하고 일반적인 콘크리트 전이보에 비해 규모가 작은 경계보를 수평 구조요소로 활용한 새로운 경계보-벽체 시스템을 제안한다. 제안된 시스템의 축하중에 대한 성능 평가를 위해 3차원 비선형 유한요소해석을 수행하였다. 주요 설계변수로 상하부벽체 길이비, 경계보 부재의 전단보강근 간격, 하부벽체로 연속되는 상부벽체 수직근의 꺾임 비율, 슬래브 길이를 설정하고 제안된 시스템의 성능에 얼마나 기여하는지 분석하였다.