• 제목/요약/키워드: low band gap

검색결과 305건 처리시간 0.027초

CBD법을 이용한 Cd1-xZnxS 박막의 광학적 특성분석 (The analysis on the optical properties of $Cd_1-_xZn_xS$ films deposited by CBD method)

  • 송우창;이재형;김정호;문중섭;박용관;양계준
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 C
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    • pp.1649-1651
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    • 2000
  • Optical properties of $Cd_{1-x}Zn_{x}S$ films deposited by :chemical bath deposition(CBD), which is a very attractive method for low-cost and large-area solar cells, are presented, Especially, in order to control more effectively the zinc component of the films, zinc acetate, which used as the zinc source, mixed in reaction solution after preheating and the pH of the reaction solution decreased with increasing the concentration of zinc acetate. The films prepared after preheating and pH control had larger zinc component and higher optical band gap. As the more zinc substituted for Cd in the films, the optical transmittance improved, while the absorption edge shifts to a shorter wavelength and the optical band gap increased. The photo conductivity of the films was larger than the dark conductivity, while the ratio of those increased with increasing the mole ratio of zinc acetate.

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Effects of Growth Temperature on the Properties of ZnO Thin Films Grown by Radio-frequency Magnetron Sputtering

  • Cho, Shin-Ho
    • Transactions on Electrical and Electronic Materials
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    • 제10권6호
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    • pp.185-188
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    • 2009
  • The effects of the growth temperature on the properties of ZnO thin films were investigated by using X-ray diffraction, scanning electron microscopy, ultraviolet-visible spectrophotometry, and Hall measurements. The ZnO films were deposited by rf magnetron sputtering at various growth temperatures in the range of 100-$400{^{\circ}C}$. A strong c-axis preferred orientation is observed for all of the samples. As the growth temperature increases, the crystalline orientation of the ZnO (002) plane is not changed, but the full width at half maximum gets smaller. The dependence of the electron concentration, mobility, and resistivity on the growth temperature exhibits that the ZnO films have a higher electron concentration at higher temperatures, thus giving them a low resistivity. The optical transmittance and band gap energy, calculated from the spectra of optical absorbance, show a significant dependence on the growth temperature. As for the sample grown at $100{^{\circ}C}$, the average transmittance is about 90% in the visible wavelength range and the band gap is estimated to be 3.13 eV.

Enhancement of NOx photo-oxidation by Fe-doped TiO2 nanoparticles

  • Martinez-Oviedo, Adriana;Ray, Schindra Kumar;Gyawali, Gobinda;Rodriguez-Gonzalez, Vicente;Lee, Soo Wohn
    • Journal of Ceramic Processing Research
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    • 제20권3호
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    • pp.222-230
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    • 2019
  • Microwave hydrothermal-assisted sol-gel method was employed to synthesize the Fe doped TiO2 photocatalyst. The morphological analysis suggests anatase phase nanoparticles of ~20 nm with an SBET area of 283.99 ㎡/g. The doping of Fe ions in TiO2 created oxygen vacancies and Ti3+ species as revealed through the XPS analysis. The reduction of the band gap (3.1 to 2.8 eV) is occurred by doping effect. The as-prepared photocatalyst was applied for removal of NOx under solar light irradiation. The doping of Fe in TiO2 facilitates 75 % of NOx oxidation efficiency which is more than two-fold enhancement than the TiO2 photocatalyst. The possible reason of enhancement is associated with high surface area, oxygen vacancy, and reduction of the band gap. Also, the low production of toxic intermediates, NO2 gas, is further confirmed by Combustion Ion Chromatography. The mechanism related NOx oxidation by the doped photocatalyst is explained in this study.

Recent Progress in Blue Perovskite LEDs

  • Joonyun, Kim;Jinu, Park;Byungha, Shin
    • 한국재료학회지
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    • 제32권11호
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    • pp.449-457
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    • 2022
  • Halide perovskites are emerging materials for next-generation display applications, thanks to their narrow emission linewidth and band gap tunability, capable of covering the entire range of visible light. Despite their short period of research, perovskite light emitting diodes (PeLEDs) have shown rapid progress in device external quantum efficiency (EQE) in the near-infrared (NIR), red, and green emission wavelengths, and the record EQE has exceeded over 20 %. However there has been limited progress with blue emission compared to the red and green counterparts. In this review, the current status and challenges of blue PeLEDs are introduced, and strategies to produce spectrally stable blue PeLEDs are discussed. The strategies include 1) a mixed halide system in the form of 3-dimensional (3D) perovskites, 2) colloidal perovskite nanocrystals and 3) low dimensional perovskites, known as quasi-2D perovskites. In the mixed halide system, previous reports based on the compositional engineering of 3D perovskites to reduce spectral instability (i.e., halide segregation) will be discussed. Since spectral instability issue originate from the mixed halide composition in perovskites, the two other strategies are based on enlarging the band gap with a single halide composition. Finally, the prospects for each strategy are discussed, for further improvement in spectrally stable blue PeLEDs.

수열합성법을 이용한 Cu2O 입자의 합성 (Synthesis of Cu2O Particles Using the Hydrothermal Method)

  • 신성민;김경환;홍정수
    • 한국전기전자재료학회논문지
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    • 제37권1호
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    • pp.63-67
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    • 2024
  • In this study, we successfully synthesized copper oxide (Cu2O) particles through a hydrothermal method at a relatively low temperature (150℃). The synthesis involved the precise control of molar concentrations of NaOH. Notably, Cu2O particles were effectively synthesized when NaOH concentrations of 0.15 M and 0.20 M were utilized. While attempts were made at different molar concentrations, the synthesis of pure Cu2O particles was only achieved at concentrations of 0.15 M and 0.20 M. In this experimental investigation, Cu2O synthesized under these specific conditions exhibited absorption characteristics within the wavelength range of 640 to 570 nm, consistently exhibiting a band gap energy of 1.9 eV. These Cu2O particles, characterized by their small band gap energy and straightforward synthetic method, hold significant promise for various applications including semiconductors and solar cells.

Low-voltage cathodoluminescent Characteristics of ZnGa$_2$O$_4$ : Mn phosphors

  • 조성희;유재수;이종덕;이중환
    • 한국표면공학회지
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    • 제30권1호
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    • pp.57-62
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    • 1997
  • Green-emitting $ZnGa_2O_4$ : Mn phosphors were synthesized by a thermal method and their low-voltage cathodoluminescent characteristics were examined for the field emitter display (FED) application. Low efficiency of $ZnGa_2O_4$ : Mn phosphors could be ascribed to the low penetration depth of into phosphors, which might results in charge accumulation on the phosphors screen. For increasing cathodoluminescent of $ZnGa_2O_4$ : Mn under low voltage excitation, wide band-gap oxide materials were added to the $ZnGa_2O_4$: Mn powder. It is found that the luminance can be increased by 20%. Measurement of leakage current on the phosphor screen shows that the enhancement of low-voltage cathodoluminescent by additive materials is mainly due to the consumption of surface charges on the phosphor.

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Ka대역 위성통신용 fly-away 터미널 안테나 & RF 시스템 설계 (An Antenna & RF System for Fly-away Satcom Terminal Application on Ka-band)

  • 박병준;김춘원;윤원상;이성재
    • 한국군사과학기술학회지
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    • 제17권4호
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    • pp.485-491
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    • 2014
  • An Antenna & RF system for a fly-away satcom terminal application on ka-band is presented in this paper. The Fly-away satellite terminal can be moved and operated by two person and adapt automatic satellite tracking system in order to decrease the tracking time. Additionally, for low-power consumption, compact size and light-weight, a dual reflector antenna is constructed using dual-offset gregorian antenna structure. For minimize weight, the reflector of the antenna is made of Magnesium. For low-power consumption and light-weight, the pHEMT MMIC compound devices is utilized. The Electronic Band-Gap(EBG) Low-Pass Filter(LPF) is designed for harmonic rejection. In the receiving part, Low-Noise Block converter(LNB) structure is designed for compact and lightweight. In this paper, fly-away satcom terminal with low-power consumption, compact size and light-weight is described with antenna system and RF system performances. Through the experimentation, fly-away terminal's EIRP is more than 50dBW, G/T is more than $17dB/^{\circ}K$.

A Novel Phase Noise Reduction In Oscillator Using PBG(Photonic Band Gap) Structure and Feedforward Circuit

  • Seo, Chul-Hun
    • Journal of electromagnetic engineering and science
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    • 제5권4호
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    • pp.204-207
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    • 2005
  • In this paper, PBG structure and feedforward circuit has been used to suppress the phase noise of the oscillator. Microstrip line resonator have low Q, but we can obtain high LO power by feedforward circuit and improve the resonator Q by the PBG, simultaneously. The proposed oscillator which uses PBG and feedforward circuit shows 0${\~}$20 dB phase noise reduction compared to the conventional oscillator. We have obtained -115.8 dBc of phase noise at 100 kHz offset from 2.4 GHz center.

CdS 박막의 제조 방법에 따른 물성 및 CdS/CdTe 이종접합의 전기적 특성 분석 (Characterization of CdS Thin Films and CdS/CdTe Heterojunction Prepared by Different Techniques)

  • 이재형
    • 한국전기전자재료학회논문지
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    • 제18권3호
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    • pp.199-205
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    • 2005
  • Polycrystalline cadmium sulfide(CdS) thin films were deposited on glass substrate by chemical bath deposition(CBD) and vacuum evaporation (VE) techniques. VE-CdS films consisted primarily of hexagonal phase, whereas CBD CdS films containing primarily the cubic form. VE-grown films were shown to have better crystallinity than CBD-grown films. The grain size of the CBD films is smaller than the ones of VE films. VE-CdS films exhibited relatively high transmittance in the above-gap region and band gap compared with CBD films. However, CdTe solar cells with these low quality CBD-CdS layers yield higher and more stable characteristics. Current-voltage-temperature measurements showed that the current transport for both cells was controlled by both tunneling and interface recombination but the cells with CBD-CdS displayed less tunneling.