• 제목/요약/키워드: loss modulus

검색결과 372건 처리시간 0.024초

황기(黃芪)추출물의 항산화 효능과 에멀션 점탄성도에 미치는 영향에 관한 연구 (Study on Effects of Anti-oxidant and Viscoelastic on Emulsion by the Extract of Astragalus membranaceus)

  • 박찬익
    • 대한본초학회지
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    • 제27권2호
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    • pp.93-97
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    • 2012
  • Objectives : The Astragalus membranaceus has been used to diuretic, tonic, anti-viral, anti-oxidant activities in oriental herb medicine, and in each experiment, proved in this effects. Root of A. membranaceus includes according to flavonoid, saponin, polysaccharide, thus it has been studied for anti-oxidant, anti-inflammatory, anti-cancer activities. However, previous researches have been performed with being limited mainly to food industry. The present study was conducted anti-oxidative activity of A. membranaceus extracts. In addition, The objective of the present study was to determine the possibility for the application of emulsions in the development of A. membranaceus for cosmetics. Methods : In this study, aimed SOD like activity of A. membranaceus extract, effects of A. membranaceus extract on viscoelastic properties of emulsion was measured using rheometer. Results : In the results, 1, 3-butylene glycol extract of A. membranaceus efficiently reduce the active oxygen, SOD like activity of more than 40% decrement depend on concentration. And A. membranaceus extract increase the modulus of elasticity of emulsion, therefore A. membranaceus extract have not influence on stability loss. As such, the A. membranaceus extracts will remain stable when applied to emulsions or skin products. Conclusions : In consequence of this study, A. membranaceus extract can be effectively used in cosmetic emulsions when the relation between natural product extracts and formulation of cosmetics is elucidated. It is highly recommended that rheology be applied to determine the optimal extract concentration for cosmetic formulations.

Manufacturing and characteristics of PAN-based composite carbon fibers containing cellulose particles

  • Yang, Jee-Woo;Jin, Da Young;Lee, Ji Eun;Lee, Seung Goo;Park, Won Ho
    • Carbon letters
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    • 제16권3호
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    • pp.203-210
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    • 2015
  • This study fabricated low thermal conductive polyacrylonitrile (PAN)-based carbon fibers containing cellulose particles while maintaining their mechanical properties. The high thermal conductivity of carbon fibers limits their application as a high temperature insulator in various systems such as an insulator for propulsion parts in aerospace or missile systems. By controlling process parameters such as the heat treatment temperature of the cellulose particles and the amount of cellulose added, the thermal and mechanical properties of the PAN-based carbon fibers were investigated. The results show that it is possible to manufacture composite carbon fibers with low thermal conductivity. That is, thermal conductivities were reduced by the cellulose particles in the PAN based carbon fibers while at the same time, the tensile strength loss was minimized, and the tensile modulus increased.

실리카흄을 혼합한 고강도콘크리트의 강도향상을 위한 실험적 연구 (An Experimental Study for Improving the Strength of High Strength Concrete with Silica Fume)

  • 문한영;문대중;신승호
    • 대한토목학회논문집
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    • 제14권5호
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    • pp.1069-1080
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    • 1994
  • 콘크리트의 고강도화 요구에 부응하기 위하여 단위시멘트량을 크게 증가시키고 고성능감수제를 사용하여 물-시멘트비를 대폭 감소시킨 고강도콘크리트가 제조되고 있다. 본 연구에서는 콘크리트의 강도를 더욱 향상시키기 위한 목적으로 실리카흄과 석고를 사용하여 콘크리트를 제조하므로써 재령 28 일과 91일의 압축강도가 각각 $1,058kg/cm^2$, $1,170kg/cm^2$되는 고강도를 얻었다. 그러나 인장강도와 탄성계수는 압축강도의 증가에 비하여 크게 향상되지 않았다. 그리고 굳지 않은 고강도콘크리트의 경과시간에 따른 슬럼프 손실과 콘크리트의 내부 온도상승이 기존의 콘크리트보다 큰 점 등이 해결되야 할 문제점이라 생각되었다.

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간헐적인 층간접착 을 이용한 Graphite/Epoxy 복합재료 의 파괴인성 개선 (Fracture Toughness Improvement of Graphite/Epoxy Composite by Intermittent Interlaminar Bonding)

  • 임승규;홍창선
    • 대한기계학회논문집
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    • 제8권5호
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    • pp.425-434
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    • 1984
  • 본 연구에서는 [0˚/90˚]$_{2s}$, Gr/Gp 복합 적층판에 대해서 접착면의 비율과 폴리에스테르 필름의 구멍의 형상이 적층판의 인장 성질과 파괴인성에 미치는 영향에 대한 실험적인 결과를 얻고자 한다.다.

Development and mechanical properties of bagasse fiber reinforced composites

  • Cao, Yong;Goda, Koichi;Shibata, Shinichi
    • Advanced Composite Materials
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    • 제16권4호
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    • pp.283-298
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    • 2007
  • Environment-friendly composites reinforced with bagasse fiber (BF), a kind of natural fiber as the remains from squeezed sugarcane, were fabricated by injection molding and press molding. As appropriate matrices for injection molding and press molding, polypropylene (PP) and polycaprolactone-cornstarch (PCL-C) were selected, as a typical recyclable resin and biodegradable resin, respectively. The mechanical properties of BF/PP composites were investigated in view of fiber mass fraction and injection molding conditions. And the mechanical properties and the biodegradation of BF/PCL composites were also evaluated. In the case of injection molding, the flexural modulus increased with an increase in fiber mass fraction, and the mechanical properties decreased with an increase in cylinder temperature due to the thermal degradation of BF. The optimum conditions increasing the flexural properties and the impact strength were $90^{\circ}C$ mold temperature, 30 s injection interval, and in the range of 165 to $185^{\circ}C$ cylinder temperature. On the other hand, as to BF/PCL-C fully-green composites, both the flexural properties and the impact strength increased with an increase in fiber mass fraction. It is considered that the BF compressed during preparation could result in the enhancement in mechanical properties. The results of the biodegradability test showed the addition of BF caused the acceleration of weight loss, which increased further with increasing fiber content. This reveals that the addition and the quantities of BF could promote the biodegradation of fully-green composites.

Multi-dimensional seismic response control of offshore platform structures with viscoelastic dampers (II-Experimental study)

  • He, Xiao-Yu;Zhao, Tie-Wei;Li, Hong-Nan;Zhang, Jun
    • Structural Monitoring and Maintenance
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    • 제3권2호
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    • pp.175-194
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    • 2016
  • Based on the change of traditional viscoelastic damper structure, a brand-new damper is designed to control simultaneously the translational vibration and the rotational vibration for platforms. Experimental study has been carried out on the mechanical properties of viscoelastic material and on its multi-dimensional seismic response control effect of viscoelastic damper. Three types of viscoelastic dampers with different shapes of viscoelastic material are designed to test the influence of excited frequency, strain amplitude and ambient temperature on the mechanical property parameters such as circular dissipation per unit, equivalent stiffness, loss factor and storage shear modulus. Then, shaking table tests are done on a group of single-storey platform systems containing one symmetric platform and three asymmetric platforms with different eccentric forms. Experimental results show that the simulation precision of the restoring force model is rather good for the shear deformation of viscoelastic damper and is also satisfied for the torsion deformation and combined deformations of viscoelastic damper. The shaking table tests have verified that the new-type viscoelastic damper is capable of mitigating the multi-dimensional seismic response of offshore platform.

Structure-property relations for polymer melts: comparison of linear low-density polyethylene and isotactic polypropylene

  • Drozdov, A.D.;Al-Mulla, A.;Gupta, R.K.
    • Advances in materials Research
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    • 제1권4호
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    • pp.245-268
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    • 2012
  • Results of isothermal torsional oscillation tests are reported on melts of linear low density polyethylene and isotactic polypropylene. Prior to rheological tests, specimens were annealed at various temperatures ranging from $T_a$ = 180 to $310^{\circ}C$ for various amounts of time (from 30 to 120 min). Thermal treatment induced degradation of the melts and caused pronounced decreases in their molecular weights. With reference to the concept of transient networks, constitutive equations are developed for the viscoelastic response of polymer melts. A melt is treated as an equivalent network of strands bridged by junctions (entanglements and physical cross-links). The time-dependent response of the network is modelled as separation of active strands from and merging of dangling strands with temporary nodes. The stress-strain relations involve three adjustable parameters (the instantaneous shear modulus, the average activation energy for detachment of active strands, and the standard deviation of activation energies) that are determined by matching the dependencies of storage and loss moduli on frequency of oscillations. Good agreement is demonstrated between the experimental data and the results of numerical simulation. The study focuses on the effect of molecular weight of polymer melts on the material constants in the constitutive equations.

Properties of Poly(benzoxazole) Copolymer Films Containing Quinoxalinedioxy/Pyridinedioxy Unit

  • Park, A Ram;Lee, Eung Jae;Choi, Jae Kon
    • Elastomers and Composites
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    • 제52권2호
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    • pp.143-153
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    • 2017
  • Herein we studied the characterization of the PBO films formed via solution casting and thermal cyclization of poly(o-hyroxyamide)s(PHAs) that were synthesized by direct polycondensation of 3,3'-dihydroxybenzidine with 4,4'-(2,3-quinoxalinedioxy) dibenzoic acid and/or 4,4'-(2,3-pyridinedioxy) dibenzoic acid. All the PHAs exhibited inherent viscosities in the range of 0.55~0.84 dL/g in DMAc solution. The copolymers, CPH-2-5, were partially soluble in less polar solvents like pyridine and THF. However, all the PBOs were not soluble in polar solvents, but only partially soluble in sulfuric acid. The temperatures corresponding to 10% weight loss of the PBOs with increasing content of quinoxalinedioxy unit were higher than those of the PHAs, and the char yields at $900^{\circ}C$ in $N_2$, tensile strength, and initial modulus of the PBOs were 1.1~1.3 times, 1.2~1.8, and 1.6~3.3 times higher, respectively, than those of the PHAs. The LOI value of CPB-2 was 38.5%, while that of CPB-1 was the highest at 40.0%. The LOI test confirmed that excellent flame retardants were synthesized.

실리카흄을 혼합(混合)한 콘크리트의 고강도화(高强度化)에 관한 기초적(基礎的) 연구(研究) (A Fundamental Study on the High Strength Concrete Using Silica Fume)

  • 문한영;김진철
    • 대한토목학회논문집
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    • 제12권4_1호
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    • pp.33-41
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    • 1992
  • 콘크리트의 강도를 크게 향상시키기 위한 연구의 일환으로 이산화규소의 함유량이 90% 이상이며, 평균입경이 $0.2{\mu}m$ 정도되는 비정질의 실리카흄을 결합재의 일부로 대체하고 고성능감수제를 사용하여 물-결합재비를 대폭 감소시킨 모르터와 콘크리트를 제조하여 재령 28일에 압축강도의 최대값이 각각 $865kg/cm^2$$725kg/cm^2$의 고강도모르터 및 콘크리트를 얻었다. 그러나 굳지 않은 콘크리트의 믹싱후 경과시간에 따른 슬럼프 손실이 큰 점과 아울러 인장강도 및 탄성계수가 크게 향상되지 않은 점이 충분히 해결되지 않았다.

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방사선 열화에 따른 Polychloroprene의 산화특성 (Oxidation Properties of Polychloroprene by Irradiation Degradation)

  • 김기엽;강현구;류부형;이청;임기조
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
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    • pp.456-459
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    • 2003
  • Polychloroprene(CR) is well known as elastomer commonly utilized in the electrical. It is mainly used for cable jacket and insulator. The irradiation degradation property of polymer materials is very important to prevent unexpected accidents in the Nuclear Power Plant(NPP). The irradiation degradation is caused by the oxidation of polymer materials, and this oxidation is occurred by oxygen radical produced from air. In this study, we evaluate the oxidation properties of CR. CR is irradiated for 200, 400, 600, 1000 kGy radiation dose. The oxidation properties of irradiated CR are investigated by differential scanning calorimetry, dynamic mechanical properties and FT-IR/ATR. Glass transition temperature(Tg), decomposition onset temperature(DOT), loss modulus and mechanical tan $\delta$ values are compared together. The irradiation limit of CR in the NPP, is known for 500 kGy, and this is exactly matched with investigated results.

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