• Journal of Power Electronics
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• v.14 no.5
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• pp.1038-1046
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• 2014

Lithium-ion batteries are widely used in hybrid and pure electric vehicles. State-of-charge (SOC) estimation is a fundamental issue in vehicle power train control and battery management systems. This study proposes a novel model-based SOC estimation method that applies closed-loop state observer theory and a comprehensive battery model. The state-space model of lithium-ion battery is developed based on a three-order resistor-capacitor equivalent circuit model. The least square algorithm is used to identify model parameters. A multi-state closed-loop state observer is designed to predict the open-circuit voltage (OCV) of a battery based on the battery state-space model. Battery SOC can then be estimated based on the corresponding relationship between battery OCV and SOC. Finally, practical driving tests that use two types of typical driving cycle are performed to verify the proposed SOC estimation method. Test results prove that the proposed estimation method is reasonably accurate and exhibits accuracy in estimating SOC within 2% under different driving cycles.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.20 no.4
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• pp.57-65
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• 2021

This paper explains a DMFC-Lithium Battery hybrid system applied to a forklift. A conventional Lead Acid battery forklift has several problems: long charging times, short operation times, and frequent battery replacements. As a result, hydrogen-powered forklifts are replacing Lead acid battery-powered forklifts due to their shorter refueling time and longer operation times. However, in doing so, we are confronted with the problem of a high hydrogen refueling infrastructure. A Direct Methanol Fuel Cell (DMFC), on the other hand, is an eco-friendly generator that directly converts the chemical energy of methanol into electricity. In general, DMFC is regarded as a small power generator under kW power. In this paper, a DMFC-Battery hybrid system is applied to a 1.5 ton forklift by increasing the power output of the DMFC stack and utilizing the high charge-discharge characteristics of a lithium battery.

• The Transactions of the Korean Institute of Power Electronics
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• v.17 no.3
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• pp.222-229
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• 2012

The SOC estimation method based on Kalman Filter(KF) requires the accurate battery model to express the electrical characteristics of the battery. However, the performance of KF SOC estimator can hardly be improved because of the nonlinear characteristic of the battery. This paper proposes the new KF SOC estimator of Lithium-Polymer Battery(LiPB), which considers the variation of parameters based on the hysteresis effect, the magnitude of SOC, the charging/discharging mode and the on/off load conditions. The proposed SOC estimation method is verified with the PSIM simulation combined the experimental data of the LiPB.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.32 no.1
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• pp.58-63
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• 2019

Lithium-ion batteries used for IT, automobiles, and industrial energy-storage devices have battery management systems (BMS) to protect the battery from abnormal voltage, current, and temperature environments, as well as safety devices like, current interruption device (CID), fuse, and vent to obtain positive temperature coefficient (PTC). Nonetheless, there are harmful to human health and property and damage the brand image of the manufacturer because of smoke, fire, and explosion of lithium battery packs. In this paper, we propose a systematic protection algorithm combining battery temperature, over-current, and interconnection between protection elements to prevent copper deposition, internal short circuit, and separator shrinkage due to frequent and instantaneous over-current discharges. The parameters of the proposed algorithm are suggested to utilize the experimental data in consideration of battery pack operating conditions and malicious conditions.

• Journal of Electrochemical Science and Technology
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• v.15 no.3
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• pp.414-420
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• 2024

Lithium-ion batteries are widely used in many applications due to their high energy density, high efficiency, and excellent cycle ability. Once an unknown Li-ion battery is reusable, it is important to measure its lifetime and state of health. The most favorable measurement method is the cycle test, which is accurate but time- and capacity-consuming. In this study, instead of a cycle test, we present an empirical model based on the C-rate test to understand the state of health of the battery in a short time. As a result, we show that the partially accelerated charge/discharge condition of the Li-ion battery is highly effective for the degradation of battery capacity, even when half of the charge/discharge conditions are the same. This observation provides a measurable method for predicting battery reuse and future capacity degradation.

• Electronics and Telecommunications Trends
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• v.38 no.5
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• pp.90-99
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• 2023

Recently, with the trend of information technology convergence and electrification, batteries are being widely used in fields such as industry, transportation, and specific applications. By 2030, the secondary battery market is expected to grow explosively by more than eight times compared with 2020 to $351.7 billion owing to the expanding adoption of electric vehicles. Depending on the electrochemical reactions in the electrode, a primary battery can only discharge through an irreversible reaction, while a secondary battery can be repeatedly charged and discharged using reversible reactions. According to the type of charge carrier ions, secondary batteries may be classified into those made of lithium, sodium, potassium, magnesium, and aluminum ions. We analyze the current status and technological issues of lithium-ion batteries, lithium-sulfur batteries, and solid-state batteries, which are representative examples of lithium secondary batteries. In addition, research trends in lithium secondary batteries are discussed.

• KIEE International Transactions on Electrophysics and Applications
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• v.3C no.5
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• pp.189-193
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• 2003

Initial irreversible capacity (IIC) can be defined by means of the initial intercalation Ah efficiency (IIE) and the initial irreversible specific capacity at the surface (IICs) with the linear-fit range of the intercalation so as to precisely express the irreversibility of an electrode-electrolyte system. Their relationship was IIC = Qc - Q$_{D}$ = (IIE$^{-1}$ - 1) Q$_{D}$ + IICs in the linear-fit range of IIE. Here, Qc and Qd signify charge and discharge capacity, respectively, based on a complete lithium ion battery cell. Charge indicates lithium insertion to carbon anode. Two terms of IIE and IICs depended on the types of active materials and compositions of the electrode and electrolyte but did not change with charging state. In an ideal electrode-electrolyte system, IIE and IICs would be 100%, 0 mAh/g for the electrode and mAh for the cell, respectively. These properties can be easily obtained by the Gradual Increasing of State of Charge (GISOC).OC).

• Journal of Power Electronics
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• v.19 no.4
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• pp.858-868
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• 2019

With the widespread use of modern clean energy, lithium-ion batteries have become essential as a more reliable energy storage component in the energy Internet. However, due to the difference in monomers, some of the battery over-charge or over-discharge in battery packs restrict their use. Therefore, a novel multiphase interleaved converter for reducing the inconsistencies of the individual cells in a battery pack is proposed in this paper. Based on the multiphase converter branches connected to each lithium battery, this circuit realizes energy transferred from any cell(s) to any other cell(s) complementarily. This flexible interlaced converter is composed of an improved bi-directional Buck-Boost circuit that is presented with its own available control method. A simulation model based on the PNGV model of fundamental equalization is built with four cells in PSIM. Simulation and experimental results demonstrate that converter and its control achieve simple and fast equalization. Furthermore, a comparison of traditional methods and the HNFABC equalization is provided to show the performance of the converter and the control of lithium-based battery stacks.

• Carbon letters
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• v.1 no.1
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• pp.36-40
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• 2000

The initial irreversible capacity (IIC) of a hard carbon during the charge/discharge reaction is strongly affected by both the initial irreversible capacity on the carbon surface $(IIC_S)$ and the initial irreversible lithium insertion into carbon $(IIC_B)$. The initial coulombic efficiency of the insertion and the desertion of lithium (IIE) can be used as a performance to classify $IIC_B$ of the carbon. The $IIC_B$ was proportional to the specific discharge capacity with a slope, $IIE^{-1}$ - 1. The IIE of hard carbon had four regions. $IIE_A$ for the region of 0~95 mAh/g of $Q_{D1}$ was 60.2%. $IIE_B$ and $IIE_C$ for the regions of 95~172 mAh/g and 172~308 mAh/g had 84.9% and 91.5%, respectively. $IIE_D$ was appeared above 308 mAh/g. But, the $IIE_D$ was reduced to 82.1% compared with $IIE_C$. These IIE might be corresponding to lithium desertion from carbon at the region of 0~172 mAh/g range, lithium desertion from the micropore of carbon at the region of 172~308 mAh/g range, and to the lithium stripping of the plated lithium for the region above 308 mAh/g, respectively.

• Membrane Journal
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• v.27 no.1
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• pp.92-103
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• 2017

In this study, electrochemical performance of the hydrophilized separator for the lithium ion battery is studied. The polyolefin based material used as the separator for the lithium ion battery is hydrophobic, and the electrolytic solution using a carbonate-based organic solvent is hydrophilic. Therefore, the polyolefin separator is hydrophilized using various hydrophilic polymers because lithium ion battery uses an aqueous electrolyte solution. In order to evaluate change of the coated separator, the performances of separator in terms of surface morphology, porosity and the wettability are investigated. Finally, the resistance and the ionic conductivity of separator coated with lithium ion are measured to evaluate the performance of lithium ion battery. Separator coated with PMVE shows good hydrophilicity and excellent ionic conductivity because the porosity of the separator is maintained. We can confirm that this property makes potential candidates for lithium ion battery.