• Title/Summary/Keyword: limiting process

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Fabrication of Organic-Inorganic Superlattice Films Toward Potential Use For Gas Diffusion Barrier

  • Yun, Gwan-Hyeok;Muduli, Subas Kumar;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.394-394
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    • 2012
  • We fabricated organic-inorganic superlattice films using molecular layer deposition (MLD) and atomic layer deposition (ALD). The MLD is a gas phase process in the vacuum like to atomic layer deposition (ALD) and also relies on a self-terminating surface reaction of organic precursor which results in the formation of a monolayer in each sequence. In the MLD process, 'Alucone' is very famous organic thin film fabricated using MLD. Alucone layers were grown by repeated sequential surface reactions of trimethylaluminum and ethylene glycol at substrate temperature of $80^{\circ}C$. In addition, we developed UV-assisted $Al_2O_3$ with gas diffusion barrier property better than typical $Al_2O_3$. The UV light was very effective to obtain defect-free, high quality $Al_2O_3$ thin film which is determined by water vapor transmission rate (WVTR). Ellipsometry analysis showed a self-limiting surface reaction process and linear growth of each organic, inorganic film. Composition of the organic films was confirmed by infrared (IR) spectroscopy. Ultra-violet (UV) spectroscopy was employed to measure transparency of the organic-inorganic superlattice films. WVTR is calculated by Ca test. Organic-inorganic superlattice films using UV-assisted $Al_2O_3$ and alucone have possible use in gas diffusion barrier for OLED.

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Parameter Optimization for Cost Reduction of Microbubble Generation by Electrolysis

  • Lucero, Arpon Jr;Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.26 no.3
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    • pp.269-280
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    • 2017
  • To lower the operational cost of microbubble generation by electrolysis, optimization of parameters limiting the process must be carried out for the process to be fully adopted in environmental and industrial settings. In this study, four test electrodes were used namely aluminum, iron, stainless steel, and Dimensionally Sable Anode (DSA). We identified the effects and optimized each operational parameter including NaCl concentration, current density, pH, and electrode distance to reduce the operational cost of microbubble generation. The experimental results showed that was directly related to the rate and cost of microbubble generation. Adding NaCl and narrowing the distance between electrodes caused no substantial changes to the generation rate but greatly decreased the power requirement of the process, thus reducing operational cost. Moreover, comparison among the four electrodes operating under optimum conditions revealed that aluminum was the most efficient electrode in terms of generation rate and operational cost. This study therefore presents significant data on performing costefficient microbubble generation, which can be used in various environmental and industrial applications.

Dissolution of Mo/Al Bilayers in Phosphoric Acid

  • Kim, In-Sung;Chon, Seung-Whan;Kim, Ky-Sub;Jeon, Il-Cheol
    • Bulletin of the Korean Chemical Society
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    • v.24 no.11
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    • pp.1613-1617
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    • 2003
  • In the phosphoric acid based etchant, the dissolution rates of Mo films were measured by microgravimetry and the corrosion potentials of Mo and Al were estimated by Tafel plot method with various concentrations of nitric acid. Dissolution rate of Mo increased with the nitric acid concentration and reached a limiting value at high concentration of nitric acid in ambient condition. Corrosion potentials of Mo and Al shifted to positive direction and the difference between potentials of both metals was about 1,100 mV and 1,200 mV with 1% and above 4% of $HNO_3$, respectively. For a Mo/Al bilayers, the dissolution rate inversion is the main reason for good taper angle in shower etching process. Taper angles are observed by scanning electron microscope (SEM) after wet etching process for Mo/Al layered films with different concentrations of $HNO_3$. In the etch side profile, it was found that Al corroded faster than Mo below 4% of $HNO_3$ in dip etching process, however, Mo corroded faster above 4%. Trend for variation of taper angle of etched side of Mo/Al layered film can be explained by considering the effect corrosion rates of both metals with various concentrations of $HNO_3$.

An Optical-Density-Based Feedback Feeding Method for Ammonium Concentration Control in Spirulina platensis Cultivation

  • Bao, Yilu;Wen, Shumei;Cong, Wei;Wu, Xia;Ning, Zhengxiang
    • Journal of Microbiology and Biotechnology
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    • v.22 no.7
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    • pp.967-974
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    • 2012
  • Cultivation of Spirulina platensis using ammonium salts or wastewater containing ammonium as alternative nitrogen sources is considered as a commercial way to reduce the production cost. In this research, by analyzing the relationship between biomass production and ammonium-N consumption in the fed-batch culture of Spirulina platensis using ammonium bicarbonate as a nitrogen nutrient source, an online adaptive control strategy based on optical density (OD) measurements for controlling ammonium feeding was presented. The ammonium concentration was successfully controlled between the cell growth inhibitory and limiting concentrations using this OD-based feedback feeding method. As a result, the maximum biomass concentration (2.98 g/l), productivity (0.237 g/l d), nitrogen-to-cell conversion factor (7.32 gX/gN), and contents of protein (64.1%) and chlorophyll (13.4mg/g) obtained by using the OD-based feedback feeding method were higher than those using the constant and variable feeding methods. The OD-based feedback feeding method could be recognized as an applicable way to control ammonium feeding and a benefit for Spirulina platensis cultivations.

Mass transfer kinetics using two-site interface model for removal of Cr(VI) from aqueous solution with cassava peel and rubber tree bark as adsorbents

  • Vasudevan, M.;Ajithkumar, P.S.;Singh, R.P.;Natarajan, N.
    • Environmental Engineering Research
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    • v.21 no.2
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    • pp.152-163
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    • 2016
  • Present study investigates the potential of cassava peel and rubber tree bark for the removal of Cr (VI) from aqueous solution. Removal efficiency of more than 99% was obtained during the kinetic adsorption experiments with dosage of 3.5 g/L for cassava peel and 8 g/L for rubber tree bark. By comparing popular isotherm models and kinetic models for evaluating the kinetics of mass transfer, it was observed that Redlich-Peterson model and Langmuir model fitted well ($R^2$ > 0.99) resulting in maximum adsorption capacity as 79.37 mg/g and 43.86 mg/g for cassava peel and rubber tree bark respectively. Validation of pseudo-second order model and Elovich model indicated the possibility of chemisorption being the rate limiting step. The multi-linearity in the diffusion model was further addressed using multi-sites models (two-site series interface (TSSI) and two-site parallel interface (TSPI) models). Considering the influence of interface properties on the kinetic nature of sorption, TSSI model resulted in low mass transfer rate (5% for cassava peel and 10% for rubber tree bark) compared to TSPI model. The study highlights the employability of two-site sorption model for simultaneous representation of different stages of kinetic sorption for finding the rate-limiting process, compared to the separate equilibrium and kinetic modeling attempts.

Formulation and Evaluation of Tablets Containing Unsaponifiable Fraction of Zea mays (Zea mays 불검화추출물을 함유하는 정제의 제제설계 및 평가)

  • Han, Yong-Hae;Chung, Youn-Bok;Han, Kun;Chung, Suk-Jae;Park, Man-Ki;Shim, Chang-Koo
    • YAKHAK HOEJI
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    • v.44 no.6
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    • pp.578-587
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    • 2000
  • The purpose of the present study was to design and prepare the optimum formulation for the oral administration of titrated extract of the unsaponifiable fraction of Zea mays L. (ETIZM). For this purpose, we simulated the blood concentration of ETIZM after its oral administration, changing the dissolution rate constants $(0.05{\sim}20\;hr^{-1})$. In vivo parameters, such as absorption rate constant $(k_a)$, elimination rate constant (k) and volume of distribution (Vd), were incorporated in the simulation on the basis of the experiments and literatures. When the dissolution rate constant $(k_r)$ is over $5\;hr^{-1}$, the absorption process appears to be the rate limiting step for the transport of ETIZM from the G.I. ract to the blood circulation. While less than $5\;hr^{-1}$, the dissolution rate considered to be the rate limiting step. Moreover, the optimum blood concentration was shown in the range from 1 to $5\;hr^{-1}$ of $k_r$ in the simulation. To design and prepare the tablets on the basis of the above results, 7 formula containing HPMC, PEG 4000 and PEG 6000 (1-5%, respectively) were prepared and evaluated. The tablets containing PEG 4000 (1%), PEG 6000 (1%) or PEG 4000 (5%) satisfy the optimum $k_r$ range ($1-5\;hr^{-1}$). These formulations, therefore, will be able to show the more effective blood concentration, compared with the commercial products after the oral administration.

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A $120-dB{\Omega}$ 8-Gb/s CMOS Optical Receiver Using Analog Adaptive Equalizer (아날로그 어댑티브 이퀄라이저를 이용한 $120-dB{\Omega}$ 8-Gb/s CMOS 광 수신기)

  • Lee, Dong-Myung;Choi, Boo-Young;Han, Jung-Won;Han, Gun-Hee;Park, Sung-Min
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.45 no.6
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    • pp.119-124
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    • 2008
  • Transimpedance amplifier(TIA) is the most significant element to determine the performance of the optical receiver, and thus the TIA must satisfy tile design requirements of high gain and wide bandwidth. In f)is paper, we propose a novel single chip optical receiver that exploits an analog adaptive equalizer and a limiting amplifier to enhance the gain and bandwidth performance, respectively. The proposed optical receiver is designed by using a $0.13{\mu}m$ CMOS process and its post-layout simulations show $120dB{\Omgea}$ transimpedance gain and 5.88GHz bandwidth. The chip core occupies the area of $0.088mm^2$, due to utilizing the negative impedance converter circuit rather than using on-chip passive inductors.

Attitudes, Perceptions, and Experiences toward End-of-Life Care Decision-Making among Intensive Care Unit Nurses in Korea: An Integrative Review (생애말 치료결정 과정에 대한 중환자실 간호사의 인식, 태도, 경험: 국내 연구논문의 통합적 고찰)

  • Choi, JiYeon;Son, Youn-Jung;Lee, Kyounghoon
    • Journal of Korean Critical Care Nursing
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    • v.13 no.1
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    • pp.27-43
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    • 2020
  • Purpose : This integrative review aimed to synthesize studies on intensive care unit (ICU) nurses' attitude, perceptions, and experiences toward end-of-life care decision-making. Methods : Using Whittermore and Knafl (2005)'s methods, we identified and synthesized research articles published in domestic journals between the years 2003 and 2019 and evaluated the quality of selected articles using the Mixed Methods Appraisal Tool. Results : In the 13 studies reviewed, 12 were published prior to enactment of the "The Act for Hospice and Palliative Care and Decision-Making about Life-Sustaining Treatment (2018)." All nine quantitative studies identified were based on cross-sectional descriptive survey. In four qualitative studies, content analysis (n=2) and phenomenology (n=2) were used. Overall, ICU nurses were well-aware of the necessity of communicating and limiting life-sustaining treatments. Many ICU nurses had positive attitude towards limiting life-sustaining treatments to promote patients' comfort and dignity. Although nurses were willing to take active roles, they also reported having experienced high stress in the process of decision-making and implementation. Conclusions : It is important to prepare ICU nurses with proper knowledge and attitude regarding the topic area. It is also equally important to develop systems to support nurses' emotional stress and moral distress during communication, decision-making, and implementation.

A Study on the Mathematical Model of Cell Growth by Carrot Cell Suspension Culture (당근세포의 현탁배양에 의한 세포성장 모델연구)

  • 채보희;허병기
    • KSBB Journal
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    • v.4 no.3
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    • pp.259-265
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    • 1989
  • In a batch fermentation process using carrot cell suspension culture, the effect of initial concentration of limiting nutrients(glucose and phosphate) on the specific growth rate and cell yield was investigated. The period of exponential growth is about 2 days and the consumption of glucose and phosphate in culture medium was very small when the initial concentrations of glucose and phosphate are 1.49g/1 ~ 3.01g/l and 0.08 ~ 0.32mM respectively. The specific growth rate of cells ranged from TEX>$0.15\;day^{-1}$ to $0.3\;day^{-1}$ irregularly. And the ratio of the initial concentration of glucose to phosphate did not affect the specific growth rate and the cell yield. The increase on cells had linear relationship with the consumption of limiting nutrients. Therefore, the increase of cells was found to be more influenced by the concentration of glucose than that of phosphate.

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Performance Enhancement of Anaerobic Treatment of Waste Sludge by Chemical Pretreatment (화학적 전처리를 통한 혐기성 슬러지 처리효율의 향상)

  • 허준무;박종안;손부순
    • Journal of environmental and Sanitary engineering
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    • v.13 no.1
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    • pp.16-25
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    • 1998
  • Laboratory-scale experiment using anaerobic fluidized bed reactor was carried out to investigate the prehydrolysis step with caustic soda on the treatment efficiency of anaerobic sludge treatment, since the overall rate-limiting step for the complete anaerobic digestion of sludge was the hydrolysis step by extracellular bacterial enzymes of insoluble polymeric molecules. Reactors received a sludge which had not been pretreated, a 50-50 mixture of pretreated and untreated sludge, and the fully pretreated sludge. Hydraulic retention time of 10, 5, 2.5 days and 1 day were applied with an respective equivalent organic loading rate of 1.17, 2.23, 4.17, 11.24 gCOD/L/d. Reactor with the untreated sludge did not archieve adequate digestion even at the HRT of 5 days, and reactor, which received the 50-50 mixture, operated well at the HRT of 5 days, but began to show signs of unstable digestion at the HRT of 2.5 days. While, reactor, which was fed the hydrolyzed sludge, operated reasonably well at the 2.5 days, but was showing somewhat decrease in removal efficiencies. Results, therefore, have substantiated that the limiting reaction in the anaerobic treatment process is hydrolysis. The soluble COD did not significantly accumulate in the reactor as organic acid form, even when they were highly stressed. It was believed that this resistance to a build-up of organic acids and soluble COD behavior was mainly due to the maintenance of the methane bacteria in the fixed-film system which prevents washout as the organic loading increased. The anaerobic fluidized bed reactor was therefore effective for the digestion of waste activated sludge at short HRT.

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