We investigated the effects of a long term application of soil amendments such as lime, silicate, compost, or combinations of these materials on the contents of Cu and Zn in paddy soil and brown rice. The results obtained from a sequential extraction of Cu and Zn in paddy soils and brown rice, using $H_2O$, $KNO_3$, $Na_2$-EDTA and $HNO_3$ and showed that the most of Cu and Zn were NaOH-extractable (organically bound form) and $HNO_3$-extractable (sulfide and residual form). Cu contents of NaOH and EDTA extractable increased with the long term application of compost while the contents of Zn extracted by $KNO_3$ was decreased even though $HNO_3$ extractable-Zn was prominent chemical form in paddy soils. The percentage and contents of Zn, extracted by $KNO_3$ for each combination treatment of soil amendments, was decreased but the contents of Cu was not affected. The content of NaOH extractable-Cu was proportionally increased with increase in organic matter content irrespective of the extractants used in this experiment. The contents of Zn and exchangeable K were also increased with increase in organic matter content. However, we could not find any relationship between the extractable forms of Cu and Zn, and CEC, OM. while increase in CEC, contents of cations, and organic matter decreased the content of Cu in brown rice.
Kim, Sun-Joo;Yoon, Chun-Gyeong;Kim, Hyung-Joong;Yang, Yong-Suck
Korean Journal of Environmental Agriculture
/
v.19
no.3
/
pp.234-241
/
2000
For the recycling of sludge as soil conditioner, the firing technology in pottery industry was applied to the sludge treatment, and produced artificial media with many voids. To produce artificial media using sludge, chabazite and lime were used as additives, and the mixture of sludge and additives was thermally treated in the firing kiln at about $800{\sim}1,100^{\circ}C$ for about ten minutes. The effect of mixed artificial media into upland soil was investigated through the crop growth experiment and the physical & chemical characteristics of the mixed soils were analysed. The pH of artificial media was higher than that of the control soils. After the plant growth experiment, artificial media plots almost contained more CEC, OM, TN, TP and $AV.P_2O_5$ than upland soil plots. From the growth analysis, growth of soybean and corn in the artificial media plots was better than that in the original upland soil plots. The yield of soybean and corn in the artificial media plots were about 46kg/10a, 194kg/10a, respectively, which is higher than that in the control. Heavy metals in the artificial media plots were lower than the standard regulation. Therefore, the artificial media produced from sludge can be mixed into farmland, and crop production can be increased additionally.
A large amount of oyster-shell waste has been illegally disposed at oyster farm sites along the southern coast of Korea, which already created serious environmental problems. Therefore, the study was undertaken to increase the consumption of oyster shell meal as a soil amendment. The effects of oyster shell meal on dynamics of heavy metals and uptake of heavy metals by spring Chinese cabbage were evaluated in silt loam soil (in Gyeongsang National University, Jinju, Gyeongnam-do, Korea), where 0, 4, 8, 12 and 16 Mg $ha^{-1}$ oyster-shell meal fertilizer were added. Lime treatment (2 Mg $ha^{-1}$) was selected as a control. In the results of this study, cabbage yields were increased by increasing levels of oyster-shell meal fertilizer. With increasing levels of oyster-shell meal fertilizer, total heavy metals concentrations were not significant among treatments. However, 0.1N HCl extractable heavy metals concentration was significantly reduced due to increasing of soil pH. A lot of portion (ca. $80{\sim}90%$) heavy metals fraction of all fractions was residual phase in soil after harvesting. The contents of Cu, Mo, Zn in cabbage were slightly increased by increasing levels of oyster shell meal fertilizer. However, there were no toxic symptoms of heavy metals during cultivation. Conclusively, it was estimated that oyster shell fertilizer could be a good amendment to increase productivity of crop and reduce uptake of heavy metals by crop and mobility of heavy metals in soil.
Kim, Myung-Sook;Kim, Yoo-Hak;Kang, Seong-Soo;Yun, Hong-Bae;Hyun, Byung-Keun
Korean Journal of Soil Science and Fertilizer
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v.45
no.6
/
pp.1108-1113
/
2012
The changes of soil organic carbon (SOC) content in paddy soils (sandy loam) were assessed from data of the 59 years fertilization plots in which the continuous rice cropping experiment started in 1954. The treatments were no fertilization(no fert.), NPK fertilization (N, NPK), NPK plus rice straw compost (NPK+C), and NPK plus rice straw compost, silicate fertilizer and lime (NPK+CLS). After 41 years, SOC content in NPK+C and NPK+CLS treatment in surface soils (0~15 cm) reached at the highest, followed by maintaining a plateau level for 8 years. After 51 years, they showed a tendency to decrease. Peak concentrations of soil organic carbon were $20.1g\;kg^{-1}$ in NPK+CLS, $19.1g\;kg^{-1}$ in NPK+C, $13.3g\;kg^{-1}$ in NPK, $11.9g\;kg^{-1}$ in N, and $11.6g\;kg^{-1}$ in control. Dissolved organic carbon(DOC) contents in surface soil solution were about 2.3 times higher in NPK+C than that in NPK+CLS. Therefore, SOC in subsurface soil(15~30 cm) was greater in NPK+C than the other treatments. These results indicate that continuous application of rice straw compost and silicate fertilizer affected significantly on the level of SOC in surface soils, subsurface soils, and soil solutions. Thus, the combined applications of NPK fertilizers with organic compost and silicate as a soil amendment are recommended as the best fertilization practice for soil carbon accumulation, environment conservation, and enhancement of soil fertility status in the continuous rice cropping system.
Kang, San Ha;Lee, Ju Mok;Lee, Gyu Hye;Kim, Sa Duk;Lee, Chan Hee
Journal of Conservation Science
/
v.34
no.3
/
pp.211-225
/
2018
The Stupa of the State Preceptor Jigwang from the Beopcheonsaji temple site in Wonju (National Treasure No. 101) was built in the Goryeo Period (around the 11th century), with very excellent style and techniques. It was returned to the Korea after being taken to Osaka of Japan without notice in 1912, and was severely damaged during the Korean War. Subsequently, the Stupa was restored using restoration materials like mortar, and relocated to the National Palace Museum of Korea. Surface contaminants in the Stupa primarily existed around the restoration materials. Black discoloration, which indicates a high discoloration grade, signified a high possession rate in the north and inner regions of the Stupa, which may be related to the relative moisture maintenance time. Most surface contaminants were calcite and gypsum; the black discoloration area underwent secondary discoloration due to air pollution. Moreover, the stone properties exhibited a relatively low discoloration grade, exhibiting crystallized contaminants that partly covered the rock-forming minerals. Overall, the Stupa deteriorated due to discoloration and being covered by lime materials, which were dissolved as the mortar degraded. Hence, it required contaminants removal, surface cleaning and desalination during conservation treatment, in order to control the rate of physicochemical deterioration by contaminants.
Lee Yong-Hwan;Lee Sang-Min;Sung Jwa-Kyung;Choi Du-Hoi;Kim Han-Myeng;Ryu Gab-Hee
Korean Journal of Organic Agriculture
/
v.14
no.2
/
pp.205-217
/
2006
This research was carried out to investigate the effects of some organic materials such as rice straw, compost, hairy vetch, phosphate rock, magnesium lime powder and ash in the organic paddy fields, and also to develope the new technique for better soil management using described materials. The results are as follows; Height and tiller of rice plants were higher in chemical fertilizer than rice straw or compost, however, those of rice plants in hairy vetch-rice cropping system reached to chemical fertilizer. The Eh value of soil has decreased consecutively since on 30th, May because of the rising of soil temperature by an increase in the activity of microbes. As a result of measuring yield and yield components, there is not significant difference between treatment. The application of organic materials enriched the contents of available phosphorus, exchangible potassium and calcium in soil, and, also improved the physical properties such as pore space rates and bulk density. From the viewpoint of soil management technology in organic paddy fields, the application of rice straw or organic compost might cause the decrease of yield compared with conventional cultivation system, chemical fertilizer, however, the application of hairy vetch residues of soil compensated for growth and yield as well as improved the physicochemical property. Therefore, it is assumed that the cultivation of hairy vetch for winter season can be one of the useful methods for organic farming system.
To elucidate the effects of calcium carbonate applied under upland and flooded conditions on the changes of soil pH, an incubation study of a soil was carried out. The experiment was conducted under the conditions with and without ground rice straw application. The results of the experiment are summarized as follows: 1. The incubation under the upland moisture condition after the application of calcium carbonate raised soil pH as high as calcium hydroxide did, whereas incubation with calos treatment under the flooded condition showed a low pH. 2. Reduction of a soil brought about by the application of ground rice straw has a significant effect on the rise of soil pH. The high pH of a soil thus brought about or raised by the use of lime is gradually reduced as the accumulation of bicarbonate ions and carbon dioxide increases in the soil solution. It may, however, be possible to keep the high pH of a flooded soil by practicing intermittent drainage or cultivation which reduces the content of bicarbonate and $CO_2$ pressure in soil solution. 3. Carbonate and bicarbonate salts which may be produced in flooded and reduced soil increases the buffering capacity of the soil.
Wanapat, Metha;Anantasook, N.;Rowlinson, P.;Pilajun, R.;Gunun, P.
Asian-Australasian Journal of Animal Sciences
/
v.26
no.4
/
pp.529-536
/
2013
The objective of this study was to investigate the effect of levels of cottonseed meal with various carbohydrate sources in concentrate on feed intake, nutrient digestibility, rumen fermentation and microbial protein synthesis in dairy bulls. Four, 6 months old dairy bulls were randomly assigned to receive four dietary treatments according to a $2{\times}2$ factorial arrangement in a $4{\times}4$ Latin square design. Factor A was carbohydrate source; cassava chip (CC) and cassava chip+rice bran in the ratio of 3:1 (CR3:1), and factor B was cotton seed meal levels in the concentrate; 109 g CP/kg (LCM) and 328 g CP/kg (HCM) at similar overall CP levels (490 g CP/kg). Bulls received urea-lime treated rice straw ad libitum and were supplemented with 10 g of concentrate/kg BW. It was found that carbohydrate source and level of cotton seed meal did not have significant effects on ruminal pH, ammonia nitrogen concentration, microbial protein synthesis or feed intake. Animals which received CC showed significantly higher BUN concentration, ruminal propionic acid and butyric acid proportions, while dry matter, organic matter digestibility, populations of total viable bacteria and proteolytic bacteria were lower than those in the CR3:1 treatment. The concentration of total volatile fatty acids was higher in HCM than LCM treatments, while the concentration of butyric acid was higher in LCM than HCM treatments. The population of proteolytic bacteria with the LCM treatments was higher than the HCM treatments; however other bacteria groups were similar among the different levels of cotton seed meal. Bulls which received LCM had higher protein digestibility than those receiving HCM. Therefore, using high levels of cassava chip and cotton seed meal might positively impact on energy and nitrogen balance for the microbial population in the rumen of the young dairy bull.
Effects of lime and ameliolating materials on decreasing available soil cadmium were studied, applying the amendments to Cd pre-and post-treated soils. Soil sttreated with Cd were placed in pots and kept under field moisture condition, summer through winter in 1981. The results of soil analysis made 40 to 60 days after the Cd treatment are as follows ; 1. Greater amount of Cd was extracted by 0.1N-HCl or 2% Citric acid than N-AcNH4 solution. More Cd was dissoluted by 0.1-HCl than 2% Citric acid. No Cd was extracted by pure water. Showing a wide variance in the amount of extractable Cd among treatments (amendments), the $N-AcNH_4$ solution seemed to be the most effective extracting solution of available soil cadmium. 2. Calcium hydroxide was the most effective materials in reducing $N-AcNH_4$ extractable Cd, followed by calcium carbonate and calcium silicate. 3. Superphosphate is also effective in reducing exchangeable cadmium. The reduction seemed to be attributed to the precipitation of cadmium phosphate. 4. The exchangeable cadmium by $N-AcNH_4$ was large in the soil pH range of 6.0 and 6.5, and it decreased as the soil pH became far apart from these values. The decrese of exchangeable Cd at low pH seemed to be related to the increase of $Mn^{+{+}}$ and that at the high pH to the precipitation as Cd-hydroxide.
Aromatic hydrocarbons which are not easily degraded by microorganisms can be accumulated in the conlaminated environment for a long lime, producing toxic effects on wild lives and humans. However, the sublethal concentrations of the chemicals induce the synthesis of stress-shock proteins in the cells and increase the adaptability of the organisms to the environmental stresses. In this study, therefore, the cells of Psezido~nonus sp. DJ- 12 treated with catechol at various concentrations were inveshgated for their survival, biodegtadability of catechol, production of stress-shock proteins, and cytological changes. The organisms were capable of degrading catechol at the range of 0.5 to 1.0 mM concentration wilhin 6 hours incubation, but they were killed by $10^2$-10$^3$ celllinl at 3 mM or higel- concentration without any catechol degradation. These cells treated with catechol begm lo produce DnaK and GroEL at 1 mM and 0.5 mM. respectively. Pseudumonas sp. DJ-12 treated with 10 mM catechol for I hour exhihiled some punctuated pores on the cell wall and contortion of the rod shape. The cells treated with he sublethal concentration of catechol showed the increased tolerance for suvival when exposed to the lethal concentration, and such tolerant effects were functioned crossly among benzoate, 4-chlorobenzoate, 'and catechol.
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