• Title/Summary/Keyword: light spectra

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Determination of optical constants for organic light emitting material of Alq3 using Forouhi-Bloomer dispersion relations (포로히-블루머(Forouhi-Bloomer) 분산식을 이용한 유기발광물질 Alq3의 광학 상수 결정)

  • 정부영;우석훈;이석목;황보창권
    • Korean Journal of Optics and Photonics
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    • v.14 no.1
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    • pp.1-7
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    • 2003
  • We determined the optical constants of organic light emitting material of Alq$_3$ in a spectral range between 1.5 and 6 eV using the physical model introduced by Forouhi and Bloomer[Phys. Rev. B 34, pp. 7018-7026, 1986.]. The initial parameters of $A_i,\;B_i,\;C_i$ of Forouhi-Bloomer dispersion relations were determined from the absorption peaks and widths of absorption spectra of the Alq$_3$ film. The refractive index of substrate, a fused silica, is derived from the Sellmeier equation with the measured transmittance and reflectance spectra. Then, the complex refractive index and thickness of the Alq$_3$ film were calculated by use of a nonlinear least square fitting program with the Forouhi-Bloomer dispersion relation and the measured transmittance and reflectance spectra.

Photoadaptation of Green Sulfur Photosynthetic Bacteria Chlorobium phaeobacteroides

  • Hirabayashi, Hiroki;Ohmura, Satoshi;Ishii, Takasada;Takaichi, Shinichi;Uehara, Kaku
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.364-366
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    • 2002
  • Photoadaptation of Chlorobium (Cb.) phaeobacteroides was investigated under dim and strong light intensity. Absorption spectra of these whole cellIs were different each other. The Soret band intensity and the Qy bandwidth of BChl e in c디l grown under dim light intensity were smaller and more broadened than those under strong light intensity. From HPLC analysis of the pigments, total carotenoid (Car) / bacterochorolphyll (BChl) e ratio of cell increased wi1h increase of light intensities. But camposition of BChl e hamologs almost unchanged. Cb. phaeobacteroides contains 11 kinds of Car including isorenieratene and beta-isorenieratene as major Car. The campositions of Car were different for cells grown under dim and strong light intensities. In conclusion, Cb. phaeobacteroides changes total amount and canposition of Car to adapt various light intensities, while homolog canposition of BChle unchange.

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Effect of Interface Reaction between ZnO:Al and Amorphous Silicon on Silicon Heterojunction Solar Cells (실리콘 이종 접합 태양 전지 특성에 대한 ZnO:Al과 비정질 실리콘 계면 반응의 영향)

  • Kang, Min-Gu;Tark, Sung-Ju;Lee, Jong-Han;Kim, Chan-Seok;Jung, Dae-Young;Lee, Jung-Chul;Yoon, Kyung-Hoon;Kim, Dong-Hwan
    • Korean Journal of Materials Research
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    • v.21 no.2
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    • pp.120-124
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    • 2011
  • Silicon heterojunction solar cells have been studied by many research groups. In this work, silicon heterojunction solar cells having a simple structure of Ag/ZnO:Al/n type a-Si:H/p type c-Si/Al were fabricated. Samples were fabricated to investigate the effect of transparent conductive oxide growth conditions on the interface between ZnO:Al layer and a-Si:H layer. One sample was deposited by ZnO:Al at low working pressure. The other sample was deposited by ZnO:Al at alternating high working pressure and low working pressure. Electrical properties and chemical properties were investigated by light I-V characteristics and AES method, respectively. The light I-V characteristics showed better efficiency on sample deposited by ZnO:Al by alternating high working pressure and low working pressure. Atomic concentrations and relative oxidation states of Si, O, and Zn were analyzed by AES method. For poor efficiency samples, Si was diffused into ZnO:Al layer and O was diffused at the interface of ZnO:Al and Si. Differentiated O KLL spectra, Zn LMM spectra, and Si KLL spectra were used for interface reaction and oxidation state. According to AES spectra, sample deposited by high working pressure was effective at reducing the interface reaction and the Si diffusion. Consequently, the efficiency was improved by suppressing the SiOx formation at the interface.

Variable-color Light-emitting Diodes Using GaN Microdonut Arrays

  • Tchoe, Youngbin;Jo, Janghyun;Kim, Miyoung;Heo, Jaehyuk;Yoo, Geonwook;Sone, Cheolsoo;Yi, Gyu-Chul
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.280-280
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    • 2014
  • We report the fabrication and electroluminescent characteristics of GaN/InxGa1-xN microdonut-shaped light-emitting diode (LED) microarrays as variable-color emitters. The diameter, width, height, and period of the GaN microdonuts were controlled by their growth parameters and the geometrical factors of the growth mask patterns. For the fabrication of microdonut LEDs, p-GaN/p-AlxGa1-xN/u-GaN/u-InxGa1-xN heteroepitaxial layers were coated on the entire surface of n-GaN microdonuts. The microdonut LED arrays showed strong light emission, which could be seen with the unaided eye under normal room illumination. Additionally, magnified optical images of microdonut LED arrays exhibited microdonut-shaped light emissions having spatially resolved blue and green colors. Their electroluminescence spectra had two dominant peaks at 460 and 560 nm. With increasing applied voltage, the intensity of the blue emission peak increased much faster than that of the green emission peak, indicating that the color of the LEDs is tunable. We also demonstrated that EL spectra of the devices could be controlled by changing the size of microdonut LEDs. What we want to emphasize here with the microdonut LEDs is that they have additional inner sidewall facets which did not exist for other typical three-dimensional structures including nanopyramids and nanorods, and that InxGa1-xN single quantum well formed on the inner sidewall facets had unique thickness and chemical composition, which generated additional EL color. The origin of the electroluminescence peaks was investigated by structural characterizations and chemical analyses.

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Studies on the Natural dyes( I ) -extraction and UV, VIS spectrum of coloring matter of gromwell- (천연염료에 관한 연구 ( I ) -자근색소의 추출 및 자외가시분광특성-)

  • Cho Kyung Rae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.11 no.3 s.25
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    • pp.25-32
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    • 1987
  • The purpose of this study is to investigate optical behaviour of coloring matter of gromwell -extracted by water, acetic acid/methanol, and the other solvents. The results were as following: UV, VIS spectra of the solution of coloring matter of gromwell extracted by water at below $80^{\circ}C$ did not reveal in the range of the visible light wavelength and coloring matter of gromwell decomposed to blue particle at $95^{\circ}C$. The solution extracted by acetic acid/methanol was tinged with reddish purple and its spectra shifted to the longer wavelength according to increase of the solvent temperature. The color of the solution extracted by water became extinct as time went by, but that extracted by acetic acid/methanol kept up original color. In case of dried gromwell, extraction by acetic acid/methanol was easier than by water, and variation of spectra did not appear but showed hypochromic shift.

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WEAK GRAVITATIONAL LENSING BY STOCHASTIC GRAVITATIONAL WAVE BACKGROUND (확률적 중력파동 배경에 의한 약한 중력렌즈)

  • Song, Doo-Jong
    • Publications of The Korean Astronomical Society
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    • v.22 no.4
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    • pp.103-111
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    • 2007
  • On the formulation frameworks of linearly perturbed spacetime and weak gravitational lensing(WGL) we studied the statistical properties of a bundle of light rays propagating through stochastic gravitational wave background(SGWB). For this we considered the SGWB as tensor perturbations of linearly perturbed Friedmann spacetime. Using the solution of null geodesic deviation equation(NGDE) we related the convergence, shear and rotation deformation spectra of WGL with the strain spectra of SGWB. Adopting the astrophysical and cosmological SGWB strain spectra which were already known we investigated the approximated spectral forms of convergence, shear and rotation of WGL.

Photocurrent Improvement by Incorporation of Single-Wall Carbon Nanotubes in TiO2 Film of Dye-Sensitized Solar Cells

  • Jung, Kyoung-Hwa;Jang, Song-Rim;Vittal, R.;Kim, Dong-Hwan;Kim, Kang-Jin
    • Bulletin of the Korean Chemical Society
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    • v.24 no.10
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    • pp.1501-1504
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    • 2003
  • Single-wall carbon nanotubes (SWCN) were integrated in $TiO_2$ film and the beneficial influence on the dyesensitized solar cells in terms of improved photocurrent was studied in the light of static J-V characteristics obtained both under illumination and in the dark, photocurrent transients, IPCE spectra and impedance spectra. Compared with a solar cell without SWCN, it is established that the photocurrent density of the modified cell increases at all applied potentials. The enhanced photocurrent density is correlated with the augmented concentration of electrons in the conduction band of $TiO_2$ and with increased electrical conductivity. Explanations are additionally corroborated with the help of SEM, Raman spectra and dye-desorption measurements.

Visible-light Photocatalytic Activity of BiOCl/Bi3O4Cl Nanocomposites

  • Gao, Bifen;Chakraborty, Ashok Kumar;Yang, Ji-Min;Lee, Wan-In
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1941-1944
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    • 2010
  • The heterojunction structures of BiOCl/$Bi_3O_4Cl$, exhibiting considerable visible-light photocatalytic efficiency, were prepared by a simple wet-chemical process at ambient condition. The prepared nanocomposites were characterized by XRD, TEM, and UV-visible diffuse reflectance spectra. Under visible light (${\lambda}\geq$420 nm) irradiation, BiOCl/$Bi_3O_4Cl$ exhibited an enhanced photocatalytic activity in decomposing 2-propanol (IP) in gas phase and salicylic acid (SA) in aqueous solution, whereas the bare BiOCl and $Bi_3O_4Cl$ showed negligible activities. It is deduced that the remarkable visible-light photocatalytic activity of the BiOCl/$Bi_3O_4Cl$ originates from the hole $(h^+)$ transfer between VB of the $Bi_3O_4Cl$ and BiOCl semiconductors.

Deterioration Mechanism of Paper According to Sizing and Beating (II) -Influences of Beating- (사이징과 고해에 따른 종이의 열화기구(제2보) -고해의 영향-)

  • 김봉용
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.2
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    • pp.58-63
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    • 1999
  • Three kinds of papers were prepared from different beating degree of pulps. Physical and optical properties were examined to elucidate the deterioration mechanism of paper according to beating degrees. Changes of double folds, elongation, water retention value, DP, K/S value and visible, UV region light absorption spectra of those papers treated by UV light were studied. Double folds and brightness were decreased more rapidly by UV treatment with increasing of beating degree. The light absorption rates of pulps in visible and UV region were also increased with change of beating level. The formation of new hydrogen bonds and higher light absorption rate of pulps according to beating induced to absorb and interact with much UV light. These phenomena maybe brought about to accelerate paper deteriortion by UV treatment both optical and physical properties.

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Exciplex emission in bilayer Light-emitting device

  • Liang, Yu-Jun;Zhang, Hong-Jie;Han, Sang-Do;Jung, Young-Ho;Taxak, Vinod Bala
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.762-765
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    • 2002
  • The bilayer organic light-emitting diode using Al (DBM) $_3$ (DBM=Dibenzoylmethane) as an emitting material and poly (N-vinylcarbazole) (PVK) as hole-transport material, emitted bright blue-green light instead of blue light. The blue-green emission is attributed to exciplex formation at the solid interface between Al (DBM) $_3$ and the hole-transport material. The exciplex formation was evidenced by the measurement of the photoluminescence spectra and lifetimes of Al (DBM) $_3$, PVK and an equimolar amount of mixture of Al (DBM) $_3$ and PVK.

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