• Title/Summary/Keyword: light scattering

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Enhancement of Dye-Sensitized Solar Cell Efficiency by Spherical Voids in Nanocrystalline ZnO Electrodes

  • Hieu, Hoang Nhat;Dao, Van-Duong;Vuong, Nguyen Minh;Kim, Dojin;Choi, Ho-Suk
    • Korean Journal of Materials Research
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    • v.24 no.9
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    • pp.458-464
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    • 2014
  • Light scattering enhancement is widely used to enhance the optical absorption efficiency of dye-sensitized solar cells. In this work, we systematically analyzed the effects of spherical voids distributed as light-scattering centers in photoanode films made of an assembly of zinc oxide nanoparticles. Spherical voids in electrode films were formed using a sacrificial template of polystyrene (PS) spheres. The diameter and volume concentration of these spheres was varied to optimize the efficiency of dye-sensitized solar cells. The effects of film thickness on this efficiency was also examined. Electrochemical impedance spectroscopy was performed to study electron transport in the electrodes. The highest power conversion efficiency of 4.07 % was observed with $12{\mu}m$ film thickness. This relatively low optimum thickness of the electrode film is due to the enhanced light absorption caused by the light scattering centers of voids distributed in the film.

A Study on the Measurements of Optical Parameters in Photosensitizer by Light Scattering (농도가 진한 매질에서 광증감제에 의한 광학적 파라미터측정에 관한 연구)

  • Kim, Ki-Jun;Lee, Jou-Joub
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.1
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    • pp.102-108
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    • 2011
  • The study of wave propagation and scattering in biological media has become increasingly important in recent years. The propagation of light within tissues is an important problem that confronts the dosimetry of therapeutic laser delivery and the development of diagnostic spectroscopy. In the clinical application of photodynamic therapy(PDT) and in photobiology, the photon deposition within a tissue determines the spatial distribution of photochemical reactions. Scattered light is measured as a function of the distance (r) between the axis of the incident beam and the detection spot. Consequently, knowledge of the photosensitizer(Chlorophyll-a) function that characterizes a phantom is measured. To obtain the results of scattering coefficients(${\mu}s$) of a turbid material from diffusion described by experimental approach. It was measured the energy fluency of photon radiation at the position of penetration depth. From fluorescence experimental method obtained the analytical expression for the scattered light as the values of $(I/I_o)_{wavelength}$ vs the distance between the center of the incident beam and optical fiber in terms of the condition of "in situ spectroscopy(optically thick)" and real time by fluorometric measurements. The result was compromised with transport of intensities though a random distribution of scatters.

The study of phase inversion of polymer solutions using small angle light scattering (SALS): The effect of addition of alcohol (C1-C4) on phase separation behavior and hydraulic permeation (SALS를 이용한 고분자용액의 상전환 기구에 관한 연구 : C1-C4 알콜의 첨가에 따른 상분리 거동에 미치는 효과와 투과 특성)

  • Kang, Jong-Seok;Lee, Young-Moo
    • Proceedings of the Membrane Society of Korea Conference
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    • 2002.05a
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    • pp.81-85
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    • 2002
  • Small angle light scattering and field emission scanning electron microscope have been used to quantify the kinetics of liquid-liquid separation behavior during water vapor(RH52%[$\pm$3%] at 27$^{\circ}C$) quenching (non-solvent induced phase separation, NIPS) of polysulfone/NMP/Alcohol and CPVC/THF/Alcohol, respectively. Time dependence of the position of the light scattering maximum was observed at polysufone dope solutions, confirming spinodal secomposition (SD). while CPVC dope solutions showed a decreased scattered light intensity with a increased q-valuel, indicating nucleation & growth (NG). For the each system, domain growth rate in the intermediate and late stage of phase separation decreased with increasing the number of carbon of alcohol used as additive (non-solvent). Also, in the early stage for SD, the scattering intensity with time was in accordance with Cahns linear theory of spinodal decomposition,[1-3] regardless of types of non-solvent additive.

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An Experimental Study of Silica Particle Growth in a Coflow Diffusion Flame Utilizing Light Scattering and Local Sampling Technique (II) - Effects of Diffusion - (광산란과 입자포집을 이용한 동축류 확산화염 내의 실리카 입자의 성장 측정(II) - 확산의 영향 -)

  • Cho, Jaegeol;Lee, Jeonghoon;Kim, Hyun Woo;Choi, Mansoo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.9
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    • pp.1151-1162
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    • 1999
  • The effects of radial heat and $H_2O$ diffusion on the evolution of silica particles in coflow diffusion flames have been studied experimentally. The evolution of silica aggregate particles in coflow diffusion flames has been measured experimentally using light scattering and thermophoretic sampling techniques. The measurements of scattering cross section from $90^{\circ}$ light scattering have been utilized to calculate the aggregate number density and volume fraction using with combination of measuring the particle size and morphology through the localized sampling and a TEM image analysis. Aggregate or particle number densities and volume fractions were calculated using Rayleigh-Debye-Gans and Mie theory for fractal aggregates and spherical particles, respectively. Flame temperatures and volumetric differential scattering cross sections have been measured for different flame conditions such as inert gas species, $H_2$ flow rates, and burner injection configurations to examine the relation between the formation of particles and radial $H_2O$ diffusion. The comparisons of oxidation and flame hydrolysis have also been made for various $H_2$ flow rates using $N_2$ or $O_2$ as a carrier gas. Results indicate that the role of oxidation becomes dominant as both carrier gas($O_2$) and $H_2$ flow rates increases since the radial heat diffusion precedes $H_2O$ diffusion in coflow flames used in this study. The effect of carrier gas flow rates on the evolution of silica particles have also been studied. When using $N_2$ as a carrier gas, the particle volume fraction has a maximum at a certain carrier gas flow rate and as the flow rate is further increased, the hydrolysis reaction Is delayed and the spherical particles finally evolves into fractal aggregates due to decreased flame temperature and residence time.

Measurement and Analysis of Light Scattering of Au Pads on PCB Surface to Extract Scattering Parameters (인쇄회로기판용 Au 패드의 산란 특성 측정 및 분석에 의한 산란 인자 추출)

  • Ko, Nak-Hoon;Park, Dae-Seo;Kim, Young-Seok;O, Beom-Hoan;Park, Se-Geun;Lee, El-Hang;Lee, Seung-Gol;Choi, Tae-Il
    • Korean Journal of Optics and Photonics
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    • v.20 no.2
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    • pp.134-140
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    • 2009
  • In this study, the influence of surface roughness on light scattering from Au pads on a PCB surface was investigated. Angular distributions of light scattered from Au pads with different surface roughness were measured for several incident angles. Diffusely-scattered light could be separated by using the fact that the amount of specularly-scattered light was directly related to surface roughness. The separated diffuse term was curve-fitted with a physics-based model, and then the related scattering parameters were extracted and compared with measured parameters.

Depth-resolved Stokes parameters of light backscattered from turbid media with polarization-sensitive optical coherence tomography system and successive phase-shifting algorithm (위상천이원리 와 PS-OCT시스템을 적용한 역산란광의 매질 깊이별 스톡스변수 추출)

  • Oh, Jung-Taek;Kim, Seung-Woo
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.02a
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    • pp.286-287
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    • 2003
  • Polarization-sensitive optical coherence tomography (PS-OCT) was developed to image highly scattering tissues with accounting for polarization effects in the sample. These polarization-sensitive images can provide additional information on the structure of the tissue because of a polarization state of the light is changed at its interaction with biological tissues. The scattering and birefringence are two phenomena, which change the polarization state of light passing through medium. (omitted)

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A new method for mapping visible-near infrared light levels in Fruit

  • Fraser, Daniel G.;Jordan, Robert B.;Kunnemeyer, Rainer;Mcglone, V. Andrew
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1128-1128
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    • 2001
  • We have developed a probe for measuring the light levels inside illuminated fruit. The probe has minimal effect on the light levels being measured and enables the sampling of the light flux at any point within the fruit. We present experimental light extinction rates within apple, nashi, kiwifruit, and mandarin fruit. Moving from the illuminated side to the far side of the fruit, the extinction level follows an initial power law decay as the light diffuses into the fruit then reduces to an exponential decay through the rest of the fruit. Significant variations in the rates of light extinction are found in the core, skin and differing flesh regions. Monte Carlo simulations of the light distribution in fruit, which use scattering and absorption coefficients for the diffusely scattering tissue, and boundary conditions for the skin effects, produce results that follow the experimental results closely.

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Development of An Optical Surface Roughness Sensor for On-the-Machine Measurement (기상 측정을 위한 광학적 표면 거칠기 측정 센서 개발)

  • Kim, Hyun-Soo;Hong, Seong-Wook
    • Journal of the Korean Society for Precision Engineering
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    • v.11 no.6
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    • pp.168-178
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    • 1994
  • This paper presents an optical surface roughness sensor developed for intermediate- process measurement on the machine. The light scattering method is adopted for the sensor, which is designed conpact and flexible enough to apply to 'on the machine' measurement of surface roughness. The developed sensor has special features such that it makes use, as the measurement parameter, of the ratio between fluxes of the incident light, and the specularly and partly diffusely reflected light, and that it can adjust the incident light angle. The experimental investigation reveals not only the sensor has good performance as a surface roughness sensor but the sensor is very robust so as to be useful in in-process measurement.

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Study on Analysis of Optical Deflection of Laser Scattering Based on Rayleigh Criterion for Crystalline Silicon Wafer in Solar Cell (태양전지용 결정질 실리콘 웨이퍼에서의 레일리기준 기반 레이저산란의 광편향 분석에 관한 연구)

  • Kim, Gyung-Bum
    • Journal of the Semiconductor & Display Technology
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    • v.9 no.4
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    • pp.31-37
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    • 2010
  • In this paper, optical deflection of laser scattering has been investigated based on Rayleigh criterion for crystalline silicon wafer in solar cell. A laser scattering mechanism is newly designed using light scattering properties in silicon wafer. Intensity distributions of laser scattering are different, depending on the incident angle of laser computed from Rayleigh criterion. In case of the incident angle satisfied with the criterion, they are asymmetric. Also, their specular reflection angle is shifted to unpredicted ones. These phenomena are in accordance with previous theories of laser scattering. The optical deflection of laser scattering is experimentally identified with the designed laser scattering mechanism. Its mathematical model is presented from the geometric relationship of laser scattering. It is shown that the optical deflection of laser scattering agree with the presented model, exclusive of grazing angles which is satisfied with Rayleigh criterion.

Methods to Improve Light Harvesting Efficiency in Dye-Sensitized Solar Cells

  • Park, Nam-Gyu
    • Journal of Electrochemical Science and Technology
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    • v.1 no.2
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    • pp.69-74
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    • 2010
  • Methodologies to improve photovoltaic performance of dye-sensitized solar cell (DSSC) are reviewed. DSSC is usually composed of a dye-adsorbed $TiO_2$ photoanode, a tri-iodide/iodide redox electrolyte and a Pt counter electrode. Among the photovoltaic parameters of short-circuit photocurrent density, open-circuit voltage and fill factor, short-circuit photocurrent density is the collective measure of light harvesting, charge separation and charge collection efficiencies. Internal quantum efficiency is known to reach almost 100%, which indicates that charge separation occurs without loss by recombination. Thus, light harvesting efficiency plays an important role in improvement of photocurrent. In this paper, technologies to improve light harvesting efficiency, including surface area improvement by nano-dispersion, size-dependent light scattering efficiency, bi-functional nano material, panchromatic absorption by selective positioning of three different dyes and transparent conductive oxide (TCO)-less DSSC, are introduced.