• Journal of the Korean Ceramic Society
• /
• v.49 no.2
• /
• pp.155-160
• /
• 2012

This paper reported a simple deposition-precipitation method, introducing the metal (Ni, Ag and Sn) and $Na_2S{\cdot}5H_2O$ to preparedispersion metal sulfide nanoparticles on the surface of the Multi-walled carbon nanotube for synthesis of CNT-$M_xS_y$ ($NiS_2$, $Ag_2S$, SnS) composite photocatalysts. The characterization of the prepared CNT-$M_xS_y$ ($NiS_2$, $Ag_2S$, SnS) composites was performed by X-ray diffraction, scanning electron microscopy with energy dispersive X-ray analysis and BET analysis. Furthermore, the MB degradation rate constant for CNT-SnS composite was $5.68{\times}10^{-3}$ under visible light irradiation, which was much higher than the corresponding values for other samples. The detailed formation and photocatalytic mechanism are also provided here.

• Asian Journal of Atmospheric Environment
• /
• v.8 no.4
• /
• pp.202-211
• /
• 2014

In this study, long-term rainfall data with irregular spatial distribution in Seoul, Korea, were separated into individual precipitation events by the inter-event time definition of 6 hours. Precipitation washout of $PM_{10}$ and $NO_2$ concentrations in the air considering various complex factors were analyzed quantitatively. Concentrations of $PM_{10}$ and $NO_2$ in the atmosphere were lower under condition of rainfall compared to that of non-precipitation, and a noticeable difference in average $PM_{10}$ concentrations was observed. The reduction of concentrations of $PM_{10}$ and $NO_2$ by rainfall monitored at road-side air monitoring sites was also lower than that of urban air monitoring sites due to continuous pollutant emissions by transportation sources. Meanwhile, a relatively smaller reduction of average $PM_{10}$ concentration in the atmosphere was observed under conditions of light rainfall below 1 mm, presumably because the impact of pollutant emission was higher than that of precipitation scavenging effect, whereas an obvious reduction of pollutants was shown under conditions of rainfall greater than 1 mm. A log-shaped regression equation was most suitable for the expression of pollutant reduction by precipitation amount. In urban areas, a lower correlation between precipitation and reduction of $NO_2$ concentration was also observed due to the mobile emission effect.

• Journal of the Korean Society for Heat Treatment
• /
• v.18 no.1
• /
• pp.18-23
• /
• 2005

Effect of cold rolling on microstructural changes has been investigated for a Zn-15%Al alloy to elucidate the reason for its work softening behavior. Fully annealed microstructure of the Zn-15%Al alloy is characterized by ${\eta}$ grains and (${\eta}+{\alpha}$) lamellar colonies, where ${\eta}$ and ${\alpha}$ are Zn-rich HCP and Al-rich FCC phases, respectively. The hardness decreases continuously with increasing cold rolling degree, exhibiting work softening behavior. It is revealed that during the cold rolling, (${\eta}+{\alpha}$) lamellar colonies gradually change into equiaxed ${\eta}$ and ${\alpha}$ grains due to dynamic recrystallization at room temperature, while pre-existing ${\eta}$ grains are only deformed without recrystallization. Furthermore, cold rolling causes the precipitation of dissolved Al solutes in ${\eta}$ grains. In view of these results, change of (${\eta}+{\alpha}$) phases from lamellar to equiaxed morphology, which results in structural softness and increase in equiaxed ${\eta}/{\alpha}$ grain boundaries with higher mobility, and deterioration of solution hardening by precipitation of Al solutes from ${\eta}$ grains, are thought to contribute to the work softening of Zn-15%Al alloy.

• Journal of Korean Society for Atmospheric Environment
• /
• v.28 no.6
• /
• pp.615-631
• /
• 2012

This study provides an evaluation for capability of Integrated Climate and Air quality Modeling System (ICAMS) on future regional scale climate projection. Temperature and precipitation are compared between ground-level observation data and results of regional models (MM5) for the past 30 years over the Korean peninsula. The ICAMS successfully simulates the local-scale spatial/seasonal variation of the temperature and precipitation. The probability distribution of simulated daily mean and minimum temperature agree well with the observed patterns and trends, although mean temperature shows a little cold bias about $1^{\circ}C$ compared to observations. It seems that a systematic cold bias is mostly due to an underestimation of maximum temperature. In the case of precipitation, the rainfall in winter and light rainfall are remarkably simulated well, but summer precipitation is underestimated in the heavy rainfall phenomena of exceeding 20 mm/day. The ICAMS shows a tendency to overestimate the number of washout days about 7%. Those results of this study indicate that the performance of ICAMS is reasonable regarding to air quality predication over the Korean peninsula.

• Clean Technology
• /
• v.23 no.2
• /
• pp.196-204
• /
• 2017

CdZnS/ZnO composite was prepared through low-temperature precipitation and drying method. The property of CdZnS/ZnO as a recyclable photocatalyst for the degradation of rhodamine B (RhB) under visible light irradiation was examined. The sample was characterized by XRD, FE-SEM, XPS, UV-vis DRS and photoluminescence techniques before and after repeated reaction to investigate the change of properties during the photocatalytic reaction. During repeated reaction, the CdZnS/ZnO showed an improved photocatalytic activity and recycle stability. Among two feasible reaction pathways for photocatalytic degradation of RhB, the cleavage of conjugated chromophore was found to predominate over N-dealkylation of chromophore skeleton in the present work. The results indicate that the CdZnS/ZnO, prepared by a simple precipitation method, can be used as a visible-light driven photocatalyst with enhanced cycle stability and activity.

• Korean Journal of Ecology and Environment
• /
• v.42 no.2
• /
• pp.221-231
• /
• 2009

This study was carried out to comparatively identify characteristics of turbid water influence in Imha Reservoir, Soyang Reservoir, and Daecheong Reservoir in Korea. We used 3 years dataset from 2002 to 2004 and analyzed seasonal water quality characteristics, particular parameters in association with turbidity, and light transparency to figure out the trends. All parameters to be used in the study were total phosphate (TP), total nitrogen (TN), chlorophyll-${\alpha}$ (Chl), suspended solids (SS), Secchi depth (SD), conductivity, and verticallight extinction coefficienct($K_d$), euphotic zone ($Z_{eu}$), and critical depth ($Z_p$). All parameters depend on season and watershed. Suspended solids from Soyang Reservoir were usually caused by TP, mainly related to living wastes and agricultures in upper stream. Daecheong Reservoir was influenced by organic matters related to large phytoplankton biomass in summer and inorganic suspended solids by nutrients in the winter. However, in case of Imha Reservoir, turbid water, consisted in silt and clay through heavy precipitation remained in the waterbody to decrease water transparency along with TP and caused the light limitation in winter. Overall results suggest that it was necessary to establish various management programs because the reasons occurring turbidity were varied according to the reservoir circumstances.

• Korean Journal of Materials Research
• /
• v.10 no.6
• /
• pp.445-449
• /
• 2000

Nickel ferrite $(Ni_{0.75}Fe_{2.25}O_4$ was synthesized by co-precipitation method in order to investigate its behavior under conditions of the reactor coolant system in pressurized light water nuclear power plants. Ammonia or potassium carbonate was used as a solution pH control agent, and aqueous ammonia or potassium carbonate solution or secondary distilled water was used as a co-precipitate washing agent. The effects of the pH control agent and the co-precipitate washing agent on the production yield on the basis of the Ni/Fe molar ratio and the particle characteristics of final products were investigated by XRD, SEM, EDX and XPS. The production yield was almost congruent with that of the initial aqueous mixture in case of using potassium carbonate as a pH control agent, while in case of using ammonia, it was quite changed. The difference seemed to be due to the effects of $Ni^{2+}{\leftarrow}NH_3$complexation in the aqueous solution and of the pH of co-precipitate washing agent.

• Current Applied Physics
• /
• v.18 no.11
• /
• pp.1403-1409
• /
• 2018

In the present study, the $SrMoO_4:Eu^{3+}$ phosphors has been synthesized through hydro-thermal co-precipitation method, and single factor and orthogonal experiment method was adopted to find optimal synthesis condition. It is interesting to note that hydro-thermal temperature is a prominent effect on the luminescent intensity of $SrMoO_4:Eu^{3+}$ red phosphor, followed by co-precipitation temperature, calcining time, and the doping amount of $Eu^{3+}$. The optimal synthesis conditions were obtained: hydro-thermal temperature is $145^{\circ}C$, co-precipitation temperature is $35^{\circ}C$, the calcining time is 2.5 h, and the doping amount of activator $Eu^{3+}$ is 25%. Subsequently, the crystalline particle size, phase composition and morphology of the synthesized phosphors were evaluated by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The results show that these phosphors possess a scheelite-type tetragonal structure, and the particle size is about $0.2{\mu}m$. Spectroscopic investigations of the synthesized phosphors are carried out with the help of photo-luminescence excitation and emission analysis. The studies reveal that $SrMoO_4:Eu^{3+}$ phosphor efficiently convert radiation of 394 nm-592 and 616 nm for red light, and the luminescence intensity of $SrMoO_4:Eu^{3+}$ phosphors is improved. $SrMoO_4:Eu^{3+}$ phosphors may be a potential application for enhancing the efficiency of white LEDs.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2004.08a
• /
• pp.679-682
• /
• 2004

$SrGa_2S_4$:Eu green phosphor and SrS:Eu red phosphor have been synthesized by co-precipitation method, respectively. Two sulfide phosphors were influenced by oxygen defect in host materials. Excitation spectra of these phosphors have high efficiency at the long wavelength region. And emission efficiency is increased under the excitation wavelength of 465nm. The combination of thiogallate green phosphor and sulfide red phosphor based on blue light InGaN chip has made it possible to emit white light.

• Journal of the Korean Ceramic Society
• /
• v.54 no.5
• /
• pp.429-437
• /
• 2017

Micro hollow plate type silica with low refraction properties was synthesized and its hollow structure was applied as an optical structure to develop a light diffusion material that simultaneously satisfies the requirements of good light diffusibility, high transmissibility, and high luminance. The developed light diffusion material was applied to a light diffusion film and the film's optical properties were assessed. Hollow silica was synthesized by precipitation method using $Mg(OH)_2$ core particles, sodium silicate, and ammonium sulfate as the silica precursors. The concentration of the silica precursor was adjusted to control hollow silica shell thickness. The total light transmittance of the light diffusion film composed of the hollow silica was 94.55%, which was 4.57% higher than that of the PC film; new film's haze was 71.20%, which was 70.9% higher. Furthermore, the luminance increased by 5.34% compared to that of the light source. The reason for the results is not only that the micro plate type hollow silica, which has a low refractive property, played a role in reducing the difference in refractive index between the medium boundaries, but also that there was a light-concentrating effect due to the changing of light paths to the front direction inside the hollow structure. Optical simulation verified the enhanced optical properties when hollow silica was applied to the light diffusion film.