• Title/Summary/Keyword: lead free

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Investigation of Surface Degradation in Silicone Rubber Due to Corona Exposure (코로나 방전에 노출된 고분자 애자용 실리콘 고무의 표면열화)

  • Hong, Joo-Il;Huh, Chang-Su;Lee, Ki-Taek;Hwang, Sun-Mook;Youn, Bok-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.10
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    • pp.1068-1078
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    • 2004
  • In this paper we investigated the characteristics of surface degradation in silicone rubber due to corona exposure and recovery mechanism. It was shown that surface free energy was 22.42 mJ/$m^2$ on initial sample but surface free energy was approximately increased to 71.14 mJ/$m^2$ after 45 minutes. However, surface free energy on silicone rubber after corona discharge treatment was completely recovered within a short time due to diffusion of low molecular weight(LMW) silicone fluid. It was shown that corona discharge insured the increase of diffusible LMW chains, which could lead to recover the surface hydrophobicity. 200~370 g/mol distribution of LMW silicone fluid which was extracted by solvent-extraction with gel permeation chromatography (GPC) was contributed to recovery. The surface degradation characteristics on silicone rubbers and the recovery mechanism based on our results were discussed.

Reactivity balance for a soluble boron-free small modular reactor

  • van der Merwe, Lezani;Hah, Chang Joo
    • Nuclear Engineering and Technology
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    • v.50 no.5
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    • pp.648-653
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    • 2018
  • Elimination of soluble boron from reactor design eliminates boron-induced reactivity accidents and leads to a more negative moderator temperature coefficient. However, a large negative moderator temperature coefficient can lead to large reactivity feedback that could allow the reactor to return to power when it cools down from hot full power to cold zero power. In soluble boron-free small modular reactor (SMR) design, only control rods are available to control such rapid core transient. The purpose of this study is to investigate whether an SMR would have enough control rod worth to compensate for large reactivity feedback. The investigation begins with classification of reactivity and completes an analysis of the reactivity balance in each reactor state for the SMR model. The control rod worth requirement obtained from the reactivity balance is a minimum control rod worth to maintain the reactor critical during the whole cycle. The minimum available rod worth must be larger than the control rod worth requirement to manipulate the reactor safely in each reactor state. It is found that the SMR does have enough control rod worth available during rapid transient to maintain the SMR at subcritical below k-effectives of 0.99 for both hot zero power and cold zero power.

A shark attack treated in a tertiary care centre: Case report and review of the literature

  • Roy, Melissa;Plant, Mathew A;Snell, Laura
    • Archives of Plastic Surgery
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    • v.45 no.1
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    • pp.80-84
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    • 2018
  • Although uncommon, shark attacks can lead to devastating outcomes for victims. Surgeons also face unique challenges during operative management such as exsanguination, shock, specific injury patterns and infections. This case report presents the management of a 39-year-old previously healthy female attacked by a shark while on vacation in Mexico. The patient sustained severe injuries to her left arm and her left thigh. She was transferred to a Canadian institution after ambiguous operative management in Mexico and presented with no clear antibiotic coverage and a Volkman's contracture of the left upper extremity. In total, the patient underwent four washouts of wounds, two split-thickness skin grafts, one free anterolateral thigh flap, and one free transverse rectus abdominus myocutaneous flap for the reconstruction and salvage of the left lower extremity. This article highlights the specifics of this case and describes important points in managing these devastating injuries.

Recent Research Progress on Eco-Friendly Perovskite Solar Cells (친환경 페로브스카이트 태양전지 최신 기술 동향)

  • You, Hyung Ryul;Choi, Jongmin
    • Journal of the Korean Electrochemical Society
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    • v.22 no.3
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    • pp.104-111
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    • 2019
  • Metal halide perovskite materials are considered as promising semiconducting materials for next-generation solar cells due to their unique electrical and optical properties. Intensive progress in perovskite solar cell yielded a certified power conversion efficiency over 24%. However, most of highly efficient perovskite solar cells required Pb-based perovskite materials, which is a critical obstacle for their commercialization, and development of Pb-free perovskite materials is one of recent urgent issues in this field. In this paper, we will introduce recent research progress on Pb-free perovskite solar cells.

Aging: Degradation of Permeability in Microporous Polymeric Membranes (물리적 노화로 인한 미세 다공성 중합체의 투과성 저하)

  • Kim, Kyunam;Koh, Dong-Yeun
    • Membrane Journal
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    • v.29 no.4
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    • pp.191-201
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    • 2019
  • Before the commercialization of polymeric membranes applicable for industrial application, the homework remains for the high-performance polymers to overcome the practical challenge: long-term stability for prolonged service time. Polymers of intrinsic microporosity (PIMs), exhibiting exceptionally high fractional free volume and high permeability, are susceptible to physical aging where the extra volume created by the inefficient ladder-type packing will lead them from the volumetric equilibrium and reduce the free volume/permeability over time. Here, we will re-examine the physical aging of polymers of intrinsic microporosity, and discuss some of the most prominent attempts to mitigate physical aging in PIMs.

Protective Effects of Auraptene against Free Radical-Induced Erythrocytes Damage

  • Khadijeh Jamialahmadi;Amir Hossein Amiri;Fatemeh Zahedipour;Fahimeh Faraji;Gholamreza Karimi
    • Journal of Pharmacopuncture
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    • v.25 no.4
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    • pp.344-353
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    • 2022
  • Objectives: Auraptene is the most abundant natural prenyloxycoumarin. Recent studies have shown that it has multiple biological and therapeutic properties, including antioxidant properties. Erythrocytes are constantly subjected to oxidative damage that can affect proteins and lipids within the erythrocyte membrane and lead to some hemoglobinopathies. Due to the lack of sufficient information about the antioxidant effects of auraptene on erythrocytes, this study intended to evaluate the potential of this compound in protecting radical-induced erythrocytes damages. Methods: The antioxidant activity of auraptene was measured based on DPPH and FRAP assays. Notably, oxidative hemolysis of human erythrocytes was used as a model to study the ability of auraptene to protect biological membranes from free radical-induced damage. Also, the effects of auraptene in different concentrations (25-400 µM) on AAPH-induced lipid/protein peroxidation, glutathione (GSH) content and morphological changes of erythrocytes were determined. Results: Oxidative hemolysis and lipid/protein peroxidation of erythrocytes were significantly suppressed by auraptene in a time and concentration-dependent manner. Auraptene prevented the depletion of the cytosolic antioxidant GSH in erythrocytes. Furthermore, it inhibited lipid and protein peroxidation in a time and concentration-dependent manner. Likewise, FESEM results demonstrated that auraptene reduced AAPH-induced morphological changes in erythrocytes. Conclusion: Auraptene efficiently protects human erythrocytes against free radicals. Therefore, it can be a potent candidate for treating oxidative stress-related diseases.

Effect of dietary fiber on lead absorption and metabolic changes in growing rats (식이내 섬유질의 종류가 성장기 흰쥐의 납 흡수 및 체내대사에 미치는 영향)

  • 김미경
    • Journal of Nutrition and Health
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    • v.22 no.6
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    • pp.485-496
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    • 1989
  • This study was performed to investigate nutritional effect of various dietary fibers on lead absorption and metabolism of protein and lipid in growing rats. Forty eight male rats of Sprague-Dawley strain weighing 75.7$\pm$0.7g were blocked into six groups according to body weight and fed six kinds of diet different with fiber source(non-fiber, cellulose, pectin) and lead level(0%, 1% ) for 4 weeks. Results are summerized as follows: 1) Food intake, weight gain, FER and PER were remarkably decreased in lead(Pb) added groups, and FER and PER in Pb-added pectin group were significantly lower than those in Pb-added non-fiber group. 2) Weight of liver, kidney and epididymal fat pad, bone weight and length, hematocrit, and hemoglobin content were decreased in Pb-added groups. 3) Total protein content in serum was tended to be decreased in Pb-added groups, but total lipid and cholesterol contents in serum were not different with dietary Pb level and fiber source. 4) Nitrogen, lipid and cholesterol content in liver were tended to be deceased in Pb-added groups, and especially those of the Pb-added pectin group were the lowest among groups. 5) Daily urinary and fecal excretions of nitrogen, lipid and cholesterol were decreased in Pb-added groups. Especially fecal excretions of nitrogen, lipid and cholesterol in Pb-free groups were significantly increased by dietary cellulose and pectin. 6) Pb content in blood was significantly increased in Pb-added pectin group. There was no significant decrease in Pb contents of liver, kidney and tibia, and increase in excretion of Pb by feeding dietary fibers. In conculsion, dietary fibers had no effect on the absorption of Pb, and dietary pectin seemed to increase Pb poisoning by decreasing bioavailibility of protein, lipid and other nutrients in the diet.

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Occupational Exposure to Metals in Shooting Ranges: A Biomonitoring Study

  • Vandebroek, Eline;Haufroid, Vincent;Smolders, Erik;Hons, Luc;Nemery, Benoit
    • Safety and Health at Work
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    • v.10 no.1
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    • pp.87-94
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    • 2019
  • Background: Lead (Pb) exposure in shooting ranges has been reduced by various measures such as jacketed ammunition and lead-free primers. Nevertheless, this may lead to exposure to other metals, potentially resulting in adverse health effects. Methods: In a cross-sectional study, 35 subjects from seven different shooting ranges were studied: four shooting instructors, 10 police officers, 15 Special Forces, and six maintenance staff members. Metals and metalloids were determined in blood and urine by inductively coupled plasma-mass spectrometry. Results: The concentrations of most elements did not differ significantly between groups or compared to reference values, except for Sb and Pt in urine and Pb in blood. Mean values for Sb were considerably higher in urine from the Special Forces ($0.34{\mu}g/L$), the maintenance staff ($0.13{\mu}g/L$), and shooting instructors ($0.32{\mu}g/L$) compared to the police officers before shooting ($0.06{\mu}g/L$) and a Belgian reference value ($0.04{\mu}g/L$). For Pt, the Special Forces showed higher mean urinary concentrations ($0.078{\mu}g/L$) compared to a Belgian reference value (<$0.061{\mu}g/L$). Mean values for blood lead were markedly higher in the Special Forces ($3.9{\mu}g/dL$), maintenance staff ($5.7{\mu}g/dL$), and instructors ($11.7{\mu}g/dL$) compared to police officers ($1.4{\mu}g/dL$). One instructor exceeded the biological exposure index for blood Pb ($38.8{\mu}g/dL$). Conclusion: Since both Pb and Sb were found to be higher in shooting range employees, especially among frequent shooters, it is advisable to provide appropriate protective equipment, education, and medical follow-up for shooting range personnel in addition to careful choice of ammunition.

Enhancing X-ray radiation protection with novel liquid silicone rubber composites: A promising alternative to lead aprons

  • Wesam Abdullah;Ramzun M. Ramli;Thair Hussein Khazaalah;Nurul Zahirah Noor Azman;Tasnim M. Nawafleh;Farah Salem
    • Nuclear Engineering and Technology
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    • v.56 no.9
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    • pp.3608-3615
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    • 2024
  • This study introduces a lead-free alternative for enhanced radiation protection. While lead aprons effectively attenuate ionizing radiation, concerns regarding flexibility, weight, and environmental hazards persist. In response, the present research is focused on producing an innovative sheet shielding comprised of carefully selected dense metal oxide microparticles (DMOs-MPs) and liquid silicone rubber (LSR). To evaluate the efficacy of the LSR samples, the current study uses rigorous testing procedures, such as microstructure characterization using EDX and FESEM. Furthermore, the study investigated key attenuation parameters within the LSR samples. Radiation protection was greatly and effectively supplied using DMOs-MPs filler (Bi-1 to Bi-7) in LSR samples; this protection reached 99.9% in the X-ray energy range. Due to the unique characteristics of the Bi-7, the results demonstrated that the samples' shielding efficiency improved with the addition of high atomic number and high-density fillers. It had the greatest attenuation coefficient and density. At 60 keV, Bi-7's density was 2.980 gcm-3, and its LAC and MAC were 19.2621 cm-1 and 6.4638 cm2/g, respectively. It also had the lowest half-value layer values in the energy range of 60-120 keV. The LSR samples showed effective radiation absorption for different energy levels, indicating that LSR can enhance the flexibility and comfort of the apron while providing adequate radiation protection. The incorporation of the DMOs-MPs with LSR represents an effective contribution and a noteworthy stride to enhance the safety and well-being of medical professionals routinely exposed to ionizing radiation.

A Study on the Free-to-Play Model for Digital Games (디지털 게임의 부분유료화 모델에 관한 연구)

  • Lee, Dong-Eun;Lee, You-Ho
    • Journal of Korea Game Society
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    • v.15 no.6
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    • pp.107-120
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    • 2015
  • Free-to-Play of Digital Game became to be one of the largest profit business models because of its stable profit and ability to attract new players. However as the services that are provided gets diversified, some problem come up with mass imbalance in the gameplay experience. Therefore in this process to organize the concepts and features of the Free-to-Play and typing research depending on the acquisition method, durability, and function of revelation target. It was able to derive the three problems, which are inequality in the gameplay experience, economic imbalance in the game world, and player's breakaway. The goal of study is to explain by giving specific examples with these three problems and offer rational solutions. These kinds of study will give a lead on how the Free-to-Play model should be applied to the Korean game market.