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http://dx.doi.org/10.5229/JKES.2019.22.3.104

Recent Research Progress on Eco-Friendly Perovskite Solar Cells  

You, Hyung Ryul (Energy Science and Engineering, DGIST)
Choi, Jongmin (Energy Science and Engineering, DGIST)
Publication Information
Journal of the Korean Electrochemical Society / v.22, no.3, 2019 , pp. 104-111 More about this Journal
Abstract
Metal halide perovskite materials are considered as promising semiconducting materials for next-generation solar cells due to their unique electrical and optical properties. Intensive progress in perovskite solar cell yielded a certified power conversion efficiency over 24%. However, most of highly efficient perovskite solar cells required Pb-based perovskite materials, which is a critical obstacle for their commercialization, and development of Pb-free perovskite materials is one of recent urgent issues in this field. In this paper, we will introduce recent research progress on Pb-free perovskite solar cells.
Keywords
Perovskite; Quantum Dot; Solar Cell; Lead-Free;
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1 P. C. Harikesh, H. K. Mulmudi, B. Ghosh, T. W. Goh, Y. T. Teng, K. Thirumal, M. Lockrey, K. Weber, T. M. Koh, S. Li, S. Mhaisalkar and N. Mathews, 'Rb as an Alternative Cation for Templating Inorganic Lead-Free Perovskites for Solution Processed Photovoltaics', Chem. Mater., 28, 7496 (2016).   DOI
2 F. Jiang, D. Yang, Y. Jiang, T. Liu, X. Zhao, Y. Ming, B. Luo, F. Qin, J. Fan, H. Han, L. Zhang and Y. Zhou, 'Chlorine-Incorporation-Induced Formation of the Layered Phase for Antimony-Based Lead-Free Perovskite Solar Cells', J. Am. Chem. Soc., 140, 1019 (2018).   DOI
3 A. H. Slavney, T. Hu, A. M. Lindenberg and H. I. Karunadasa, 'A Bismuth-Halide Double Perovskite with Long Carrier Recombination Lifetime for Photovoltaic Applications', J. Am. Chem. Soc., 138, 2138 (2016).   DOI
4 https://www.nrel.gov/pv/cell-efficiency.html
5 A. K. Jena, A. Kulkarni and T. Miyasaka, 'Halide Perovskite Photovoltaics: Background, Status, and Future Prospects', Chem. Rev., 119, 3036 (2019).   DOI
6 S. Ruhle, 'Tabulated values of the Shockley-Queisser Limit for Single Junction Solar Cells', Solar Energy, 130, 139 (2016).   DOI
7 S. D. Stranks, G. E. Eperon, G. Grancini, C. Menelaou, M. J. Alcocer, T. Leijtens, L. M. Herz, A. Petrozza and H. J. Snaith, 'Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber', Science, 342, 341 (2013).   DOI
8 W.-J. Yin, T. Shi and Y. Yan. 'Unique Properties of Halide Perovskites as Possible Origins of the Superior Solar Cell Performance', Adv. Mater., 26, 4653 (2014).   DOI
9 C. C. Stoumpos, C. D. Malliakas and M. G. Kanatzidis, 'Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties' Inorg. Chem., 52, 9019 (2013).   DOI
10 Z. Chen, J. J. Wang, Y. Ren, C. Yu and K. Shum, 'Schottky Solar Cells based on $CsSnI_3$ Thin-Films', Appl. Phys. Lett., 101, 093901 (2012).   DOI
11 B.-W. Park, B. Philippe, X. Zhang, H. Rensmo, G. Boschloo and E. M. J. Johansson, 'Bismuth based Hybrid Perovskites $A_3Bi_2I_9$(A:methylammonium or cesium) for Solar Cell Application', Adv. Mater., 27, 6806 (2015).   DOI
12 N. K. Noel, S. D. Stranks, A. Abate, C. Wehrenfennig, S. Guarnera, A.-A. Haghighirad, A. Sadhanala, G. E. Eperon, S. K. Pathak, M. B. Johnston, A. Petrozza, L. M. Herz and H. J. Snaith, 'Lead-Free Organic-Inorganic Tin Halide Perovskites for Photovoltaic Applications', Energy Environ. Sci., 7, 3061 (2014).   DOI
13 F. Hao, C. C. Stoumpos, D. H. Cao, R. P. H. Chang and M. G. Kanatzidis, 'Lead-Free Solid-State Organic-Inorganic Halide Perovskite Solar Cells', Nature Photon., 8, 489 (2014).   DOI
14 S. Shao, J. Liu, G. Portale, H.-H. Fang, G. R. Blake, G. H. ten Brink, L. J. A. Koster and M. A. Loi, 'Highly Reproducible Sn-Based Hybrid Perovskite Solar Cells with 9% Efficiency', Adv. Energy Mater., 8, 1702019 (2018).   DOI
15 C. C. Stoumpos, L. Fraser, D. J. Clark, Y. S. Kim, S. H. Rhim, A. J. Freeman, J. B. Ketterson, J. I. Jang and M. G. Kanatzidis, 'Hybrid Germanium Iodide Perovskite Semiconductors: Active Lone Pairs, Structural Distortions, Direct and Indirect Energy Gaps and Strong Nonlinear Optical Properties', J. Am. Chem. Soc., 137, 6804 (2015).   DOI
16 T. Krishnamoorthy, H. Ding, C. Yan, W. L. Leong, T. Baikie, Z. Zhang, M. Sherburne, S. Li, M. Asta, N. Mathews and S. G. Mhaisalkar, 'Lead-Free Germanium Iodide Perovskite Materials for Photovoltaic Applications', J. Mater. Chem. A, 3, 23829 (2015).   DOI
17 R. L. Z. Hoye, R. E. Brandt, A. Osherov, V. Stevanovic, S. D. Stranks, M. W. B. Wilson, H. Kim, A. J. Akey, J. D. Perkins, V. Bulovic, and T. Buonassisi, 'Methylammonium Bismuth Iodide as a Lead-free, Stable Hybrid Organic-Inorganic Solar Absorber', Chem. Eur. J., 22, 2605 (2016).   DOI
18 Z. Zhang, X. Li, X. Xia, Z. Wang, Z. Huang, B. Lei and Y. Gao, 'High-Quality (CH3NH3)3Bi2I9 Film-Based Solar Cells: Pushing Efficiency up to 1.64%', J. Phys. Chem. Lett., 8, 4300 (2017).   DOI
19 T. M. Koh, T. Krishnamoorthy, N. Yantara, C. Shi, W. L. Leong, P. P. Boix, A. C. Grimsdale, S. G. Mhaisalkar and N. Mathews, 'Formamidinium Tin-based Perovskite with Low Eg for Photovoltaic Applications', J. Mater. Chem. A, 3, 14996 (2015).   DOI
20 F. Hao, C. C. Stoumpos, P. Guo, N. Zhou, T. J. Marks, R. P. H. Chang and M. G. Kanatzidis, 'Solvent-Mediated Crystallization of $CH_3NH_3SnI_3$ Films for Heterojunction Depleted Perovskite Solar Cells', J. Am. Chem. Soc., 137, 11445 (2015).   DOI
21 S. J. Lee, S. S. Shin, Y. C. Kim, D. Kim, T. K. Ahn, J. H. Noh, J. Seo, and S. I. Seok, 'Fabrication of Efficient Formamidinium Tin Iodide Perovskite Solar Cells through $SnF_2$-Pyrazine Complex', J. Am. Chem. Soc., 138, 3974 (2016).   DOI
22 K. P. Marshall, M. Walker, R. I. Walton and R. A. Hatton, 'Enhanced Stability and Efficiency in Hole-Transport-Layer-Free $CsSnI_3$ Perovskite Photovoltaics', Nat. Energy, 1, 178 (2016).
23 T.-B. Song, T. Yokoyama, C. C. Stoumpos, J. Logsdon, D. H. Cao, M. R. Wasielewski, S. Aramaki and M. G. Kanatzidis, Importance of Reducing Vapor Atmosphere in the Fabrication of Tin-based Perovskite Solar Cells', J. Am. Chem. Soc., 139, 836 (2017).   DOI
24 D. H. Cao, C. C. Stoumpos, T. Yokoyama, J. L. Logsdon, T.-B. Song, O. K. Farha, M. R. Wasielewski, J. T. Hupp and M. G. Kanatzidis, 'Thin Films and Solar Cells Based on Semiconducting Two-Dimensional Ruddlesden-Popper $(CH_3(CH_2)_3NH_3)_2(CH_3NH_3)_{n-1}Sn_nI3_{n+1}$ Perovskites', ACS Energy Lett., 2, 982 (2017).   DOI
25 Y. Liao, H. Liu, W. Zhou, D. Yang, Y. Shang, Z. Shi, B. Li, X. Jiang, L. Zhang, L. N. Quan, R. Quintero-Bermudez, B. R. Sutherland, Q. Mi, E. H. Sargent and Z. Ning, 'Highly Oriented Low-Dimensional Tin Halide Perovskites with Enhanced Stability and Photovoltaic Performance', J. Am. Chem. Soc., 139, 6693 (2017).   DOI
26 B. Saparov, F. Hong, J.-P. Sun, H.-S. Duan, W. Meng, S. Cameron, I. G. Hill, Y. Yan and D. B. Mitzi, 'Thin-Film Preparation and Characterization of Cs3Sb2I9: A Lead-Free Layered Perovskite Semiconductor', Chem. Mater., 27, 5622 (2015).   DOI