• Title/Summary/Keyword: leaching experiment

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Leaching Characteristic Analysis of Cement Solidified Radioactive Waste Attached by Yellow Sand Rain (황사빗물의 영향에 의한 방사성 폐기물 시멘트 고화체의 침출특성 분석)

  • 김혜진;이수홍;황주호;이재민
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.244-250
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    • 2003
  • With a recent public concern rising on the radioactive waste, it is disclosed that the problem is more serious than expected. This research has been conducted to find effects of yellow sandy rainwaters on the solidified cement of mid-and-low level radioactive waste. The ANS 16.1 standard test method was chosen for this leaching experiment. Make a cement solidified radioactive waste that contains Co nuclide, and fabricate it for over 28 days. Then, decide on the volume of leaching water and the concentration of ion and metal in leachate from the mass concentration of yellow sands in atmosphere. In this paper, we have taken a short look at characteristics of yellow sand. Before going into the leaching experiment, we decided experimental conditions first. Then, it was evaluated and analyzed how sandy rainfalls have impact on the cement solidified radioactive waste based on data from 90 days of leaching experiment.

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Application of Microwave-HClO Leaching for On-board Recovery of Au in Hydrothermal Minerals (열수광물내 Au의 선상회수를 위한 마이크로웨이브-차아염소산 용출 적용성)

  • Kim, Hyun Soo;Myung, Eun Ji;Kim, Min Sung;Lee, Sung-Jae;Park, Cheon-young
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.3
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    • pp.243-250
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    • 2020
  • The purpose of this study is to find out the possibility of applying microwave-hypochlorous acid leaching to effectively leaching Au in hydrothermal minerals on board. The comparative leaching experiment were confirmed that the leaching rate of Au with(T1)/with out(T2) of microwave nitric acid leaching. In addition, the leaching rate of Au on the conventional leaching by mechanical agitation(T3) and microwave leaching was compared. The result of microwave nitric acid leaching(solid-liquid ratio; 10%, leaching temperature; 90 ℃, leaching time; 20 min) confined that the metal leaching rate was high in the order of As>Pb>Cu>Fe>Zn, and the content of Au in the leaching residue was increased from 33.77 g/ton to 60.02 g/ton. As a result of the comparative leaching experiment using a chloride solvent, the dissolution rate of Au was high in the order of T1(61.10%)>T3(53.30%)>T2(17.30%). Therefore, chloride, which can be manufactured using seawater and that can be recycled by collecting chlorine gas generated in the leaching process, is expected to be an optimal solvent for Au leaching. In addition, the application of microwaves is believed to be effective in terms of time, efficiency and energy.

Nutrient Leaching from Leaf Litter of Emergent Macrophyte(Zizania latifolia) and the Effects of Water Temperature on the Leaching Process

  • Park, Sangkyu;Cho, Kang-Hyun
    • Animal cells and systems
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    • v.7 no.4
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    • pp.289-294
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    • 2003
  • To quantify nutrient loading from emergent macrophytes through leaching in the littoral zones of Paldang Reservoir, we conducted incubation experiments using leaf litter of the emergent macrophyte, Zizaniz latifolia. To separate the leaching process from microbial decay, we used $HgCl_2$ to suppress microbial activity during the experiment. We measured electric conductivity, absorbance at 280nm, total nitrogen and dissolved inorganic nitrogen, total phosphorus and soluble reactive phosphorus, Na, K, Mg and Ca amounts in leaf litter and in water. In addition, we examined the effects of water temperature and ion concentrations of ambient water on the leaching process. A total of 6% of the initial ash-free dry mass of leaf litter was lost due to leaching during incubation (four days). Electric conductivity and A280 continued to increase and saturate during the incubation. To compare reaching rates of different nutrients, we fitted leaching dynamics with a hyperbolic saturation function [Y=AㆍX/(B+X)]. From these fittings, we found that ratios of leaching amounts to nutrient concentration in the litter were in the order of K > Na > Mg > P > Ca > N. Leaching from leaf litter of Z. latifolia was dependent on water temperature while it was not related with ion concentrations in the ambient water. Our results suggest that the leaching process of nutrients, especially phosphorus, from aquatic macrophytes provides considerable contribution to the eutrophication of the Paldang Reservoir ecosystem.

The Dissolution Efficiency of Gold Concentrate with Microwave-nitric Acid Leaching and the Recovery of Invisible Gold Using the Filter Paper (마이크로웨이브-질산용출에 의한 금 정광의 용해효율과 여과지를 이용한 비-가시성 금 회수)

  • Lee, Jong-Ju;Park, Cheon-Young
    • Economic and Environmental Geology
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    • v.52 no.6
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    • pp.595-604
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    • 2019
  • The purpose of this study was simply to obtain gold through a microwave-nitric acid experiment of invisible gold concentrate with the use of filter paper. For the purpose, this study conducted a microwave-nitric acid leaching experiment and examined nitric acid concentration. As a result of the experiment, this study discovered that Fe, Te and Ag were completely leached in the leaching solution whereas Au was not determined in all of the nitric acid conditions. The leaching solution was filtered with three filter papers and then these filter papers were analyzed with SEM/EDS. As a result of the EDS analysis, Au was detected in all of the surface and cross-section of the 1st, 2nd and 3rd filter papers. As the three filter papers containing solid-residue were analysed in the lead-fire assay, gold particles were found in all of the nitric acid conditions. In the lead-fire assay, maximum gold(452.50g/t) was recovered when nitric acid concentration was 6M and microwave leaching time was 12mins.

Leaching Characteristics on Arsenic Contaminated Soils after Stabilization Treatment (안정화 처리된 비소오염토양의 용출특성)

  • Yu, Chan;Park, Jin-Chul;Yoon, Sung-Wook;Baek, Seungh-Wan;Lee, Jung-Hun;Lim, Young-Cheol;Choi, Seung-Jin;Jang, Min
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.920-925
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    • 2008
  • In this presentation, a leaching experiment which is followed the pH changes(pH=4, pH=7) and the mixing rates(1%, 3%, 5%, 7%) was carried out to examine the arsenic reduction effects and the leaching characteristics on arsenic contaminated soil after stabilization treatment in which 5 materials were used as stabilization agencies, i.e. ZVI(zero valent iron), blast furnace slag, steel refining slag, quick lime, and oyster shell meal. Except for blast furnace slag, the arsenic removal rate increased as the mixing rate increases of stabilization agencies. Arsenic leaching concentration was indicated that pH=7 condition is higher than pH=4 condition. This result shows because arsenic immobilization reaction increases as pH decreases, and arsenic adsorption takes place as pH decreases.

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Sulfuric Acid Leaching of Valuable Metals from Spent Petrochemical Catalyst using Hydrogen Peroxide as a Reducing Agent

  • Park, Kyung-Ho;Sohn, Jeong-Soo;Kim, Jong-Seok
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.478-481
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    • 2001
  • The spent petrochemical catalyst used in the manufacturing process of terephthalic-acid contains valuable metals such as cobalt and manganese. To recover these metals, sulfuric acid leaching was performed with hydrogen peroxide as a reducing agent. Low extractions of Mn, Co and Fe were obtained by sulfuric acid leaching without reducing agent. With adding hydrogen peroxide as a reducing agent, the high extraction of these metals could be obtained. Different from general leaching experiment, the extraction rates of metal components were decreased with increasing reaction temperature in this case. Under the optimum condition, the extraction rates of Mn, Co and Fe were 93.0%, 87.0% and 100% respectively.

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Physicochemical Properties of Added Sugar Ratio on Gugija-Sugar Leaching by Using Gugija (Lycii fructus) Raw Fruit (구기자생과를 이용한 구기자청 제조시 당첨가량에 따른 이화학적 특성)

  • Lee, Ka-Soon;Kim, Gwan-Hou;Kim, Hyun-Ho;Lee, Hee-Chul;Paik, Seung-Woo;Lee, Sox-Su
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.6
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    • pp.744-751
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    • 2008
  • Physicochemical properties of Gugija-sugar leaching were investigated by adding sugar ratio on Gugija (Lycii fructus) raw fruit. Gugija were prepared by parboiling ($40{\sim}50$ sec at $85^{\circ}C$) and unparboiling. Gugija-sugar leaching were leached after preserving (5 months at $5^{\circ}C$) Gugija-sugar mixture (20, 40, 60, 80 and 100% sugar based on raw Gugija). The yield increased with UPRGSL-4 (Gugija-sugar leaching adding 80% sugar) having the highest yield at 77.5%; in contrast, total acidity decreased with increasing ratio of sugar. The main organic acids of raw Gugija are tartaric acid (0.63%), citric acid (0.57%), malic acid (0.54%) and succinic acid (0.3%). Citric acid and succinic acid decreased with increasing ratio of sugar but malic acid and tartaric acid increased on Gugija-sugar leaching. Polyphenolics and betaine content of unparboiling Gugija-sugar leaching decreased as increase ratio of sugar but in term of used Gugija amount, betaine content of each Gugija-sugar leaching was equal to raw Gugija. Also, parboiling Gugija-sugar leaching decreased quickly with increasing ratio of sugar, especially PRGSL-4 and PRGSL-5 (parboiling Gugija-80 and 100% sugar leaching, respectively) was not determined. 15 types of free amino acids were detected in raw Gugija; the total content was 601.6 mg/100 g and the highest amino acid among them was serine, 218.1 mg/100 g. In PRGSL-4 prepared by parboiling, 9 kinds of free amino acid were detected and the total content was 383.3 mg/100g. Also, in UPRGSL-4 (unparboiling Gugija-80% sugar leaching), all 17 kinds were detected and its total content was 705.7 mg/100 g.

Characteristics of Microwave Leaching for the Removal of Bi, As from the Sulfide Mineral Concentrate (황화광물정광으로부터 Bi, As 제거를 위한 마이크로웨이브 용출 특성)

  • On, Hyun-Sung;Togtokhmaa, B.;Park, Cheon-Young
    • Journal of the Mineralogical Society of Korea
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    • v.31 no.3
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    • pp.137-147
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    • 2018
  • The aim of this study was to leach penalty elements, such as Bi and As, effectively through microwave leaching of a gold concentrate sample containing penalty elements with nitric acid solution. For this purpose, the time effect of microwave leaching, nitric acid concentration effect, and sample addition effect in a microwave were examined. The experiment, demonstrated that the leaching rate of penalty elements increased as microwave leaching time and nitric acid concentration increased and concentration addition decreased. When a microwave heating experiment was carried out on the concentrate and ore minerals, Bi was removed by as much as 90%, and the phase of arsenopyrite was transformed in the order of arsenopyrite (FeAsS), pyrrhotite (FeS), and hematite ($Fe_2O_3$). When the X-ray diffraction (XRD) analysis was carried out with solid residue, elemental sulfur and anglesite were identified. The intensity of the XRD peaks of elemental sulfur and anglesite increased, and the peaks were sharper when the microwave leaching time was 12 min instead of 1 min, the nitric acid concentration was 4 M in rather than 0.5 M, and the concentration addition was 30 g rather than 5 g. This was probably because more elemental sulfur and anglesite were generated in the leaching solution as the leaching efficiency increased. Bi can be leached as valuable elements in the leaching solution through microwave leaching processes while they are released to the environment through a microwave heating processes.

The Effect of Cutting Frequency and Nitrogen Fertilizing Level on NO_3-N Leaching Losses In the Pasture (영년 혼파초지에 있어서 예취빈도와 질소시비수준이 NO$_3$-N의 유실에 미치는 영향)

  • 육완방
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.10 no.2
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    • pp.84-88
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    • 1990
  • This experiment was conducted to evaluate the effect of cutting frequency and nitrogen fertilization on $(NO_3$-N leaching losses under 12 years mixture permanent meadow, The results of this study were summarized as follows: 1. There was no difference in the $(NO_3$-N content of soil water within 1 m soil depth during the whole experimental period. It means that the content of $(NO_3$-N leaching losses was not influenced by botanical composition, cutting frequency and nitrogen fertilization in this experiment. 2. The level of $(NO_3$-N content during the whole experimental period was not in excess of 0.5 ppm level.

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