• Macromolecular Research
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• v.9 no.2
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• pp.122-128
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• 2001

Monodisperse composite latex particles with size of ca. 300 nm, which consist ofn-butyl acrylate as a soft phase and methyl methacrylate as a hard phase with different morphology, were synthesized by seeded multi-stage emulsion polymerization. Three types of composite latex particles including random-, core/shell-, and gradient-type particles were obtained by using different monomer feeding methods during semi-batch emulsion polymerization. Effect of poly(butyl acrylate)-poly(methyl methacrylate) rubber particle morphology on the mechanical and rheological properties of rubber toughened poly(methyl methacrylate) was investigated. Among three different rubber particles, the gradient-type rubber particle showed better toughening effect than others. No significant variation of rheological property of poly(methyl methacrylate)/rubber blends was observed for the different rubber particle morphology.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.769-772
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• 2004

Very-Early-Strength Latex-Modified Concrete(VESLMC) provides the repairing material with short curing time as well as excellent bond strength, flexural strength and impermeability against water and chloride. In 2001, VESLMC introduced in Korea and improved superior material through research and development on material properties and durability. In 2003, the field test progressed for study problems of VESLMC field application. This paper introduced equipment improvement for bridge deck repair save both repair time and labor, while producing quality VESLMC structures.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.1
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• pp.26-34
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• 2010

Effects of drying condition (IR radiation) on the optical properties and the printability of coated paper were elucidated at various latex sizes and low and high coating color concentrations. It was found that the smaller latex provided better rheology and higher dry and wet pick strength than the larger one. The high solids coating resulted in higher paper gloss and smaller roughness than the low solids coating, even though the clay addition was reduced by 20 parts in the high solids coating. Increasing IR radiation prohibited binder migration into the base paper. Thus it improved binder distribution and decreased pores in the coated layer, resulting in the increased dry and wet pick strength and the improved printing gloss. On the other hand, the color trapping and ink set-off was impaired with increasing IR radiation. Print mottle index passed through a maximum with increasing IR radiation.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.43 no.1
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• pp.17-22
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• 2011

The conventional coated paper has many functional problems for printed RFID tag. This study was carried out in order to evaluate the effect of coating color components on conductivity of printed coated paper. It has been well known that the efficiency of printed RFID tag is influenced by surface properties of substrate. The required properties for suitable substrate of printed RFID tag are high smoothness and waterproof property. In this study high grammage base paper surface sized with PVA was used. Coated paper was manufactured with five different formulations. Types of coating pigments and dosage of latex were varied. It was obtained high smoothness and also less binder demand with clay than GCC. On the other hand, suitable surface resistance and smoothness of coated paper for RFID tag was obtained with 20% of latex. Besides it shows the possibility of using coated paper for printed RFID tag.

• Macromolecular Research
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• v.17 no.10
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• pp.776-784
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• 2009

N,N-dimethyldodecylamine (tertiary amine)-modified MMT (DDA-MMT) was prepared as an organically modified layered silicate (OLS), after which styrene-butadiene rubber (SBR) nanocomposites reinforced with the OLS were manufactured via the latex method. The layer distance of the OLS and the morphology of the nanocomposites were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). By increasing the amount of N,N-dimethyldodecylamine (DDA) up to 2.5 g, the maximum values of torque, tensile strength and wear resistance of the SBR nanocomposites were increased due to the increased dispersion of the silicate layers in the rubber matrix and the increased crosslinking of the SBR nanocomposites by DDA itself. When SBR nanocomposites were manufactured by using the ternary filler system (carbon black/silica/OLS) to improve their dynamic properties as a tire tread compound, the tan $\delta$(at $0^{\circ}C$ and $60^{\circ}C$) property of the compounds was improved by using metal stearates instead of stearic acid. The mechanical properties and wear resistance were increased by direct substitution of calcium stearate for stearic acid because the filler-rubber interaction was increased by the strong ionic effect between the calcium cation and silicates with anionic surface. However, as the amount of calcium stearate was further increased above 0.5 phr, the mechanical properties and wear resistance were degraded due to the lubrication effect of the excessive amount of calcium stearate. Consequently, the SBR/organoclay nanocomposites that used carbon black, silica, and organoclay as their ternary filler system showed excellent dynamic properties, mechanical properties and wear resistance as a tire tread compound for passenger cars when 0.5 phr of calcium stearate was substituted for the conventionally used stearic acid.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.3
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• pp.246-252
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• 2021

The basic properties and volume stability of the ultra-rapid setting cement mortar containing low-quality recycled aggregate with a higher water absorption and lower specific gravity than relavent Korea Standard were experimentally confirmed. The mix proportion without recycled aggregate followed that of the general repair mortar used in the fields. 15% and 30% of the fine aggregate was substituted by the recycled aggregate in the mixtures with and without latex emulsion, and properties and characteristics of the mortar including mortar flow, setting time, compressive and flexural strength, and linear deformation under sealed and unsealed conditions were evaluated. It was confirmed that when low-quality recycled aggregate was used by 30%, there were risks of decrease in the early-age strength by up to 50% within 24h and increases in drying shrinkage by up to 2 times for 2 weeks compared to the the mixtures without the recycled aggregate.

• Korean Journal of Food Science and Technology
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• v.12 no.3
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• pp.209-215
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• 1980

Proteases from papaya latex were partially purified by ammonium sulfate precipitation and separated into two fractions (Fraction I and II ) by carboxymethyl cellelose column chromatography. Each fraction, mixture of the two fractions, and crude extract of the papaya latex at pH 7.0 were inactivated at the range of $60{\sim}90^{\circ}C$ and thermal properties of the enzymes were investigated. In the thermal inactivation of fraction I, the enthalpy of activation was 89.5 kJ/mol; the entropy of activation, -44.0 J/mol K; the free energy of activation, 104.6 kJ/mol; z-value, $25^{\circ}C$. For fraction II, the enthalpy of activation was 96.5 kJ,/mol; the entropy of activation, -22.0 J/mol K; the free energy of activation, 104.0 kJ/mol; z-value, $23^{\circ}C$. For the mixture of fraction I and II, the enthalpy of activation was 90.9 kJ/mol; the entropy of activation, -38.8 J/mol·K; the free energy of activation, 104.2 kJ/mol; z-value, $24.6^{\circ}C$. For crude extract, the enthalpy of activation was 113.8 kJ/mol; the entropy of activation, 22.0 J/mol·K; the free energy of activation, 106.2 kJ/mol; z-value, $23.2^{\circ}C$. It was indicated that the fraction I was more heat-stable than the fraction II and this suggested that the thermal stability of the proteases in papaya latex is probably due to the fraction I.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.123-128
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• 2001

The Purpose of this study is to clarify the effect of the monomer ratio on properties of the polymer-modified mortars using methyl methacrylate-butyl acrylate latexes, and to obtain basic data necessary to develop appropriate latexes for cement modifiers. This paper deals with the effect of the monomer ratio on the typical properties of polymer-modified mortars with methyl methacrylate-butyl acrylate latexes. The polymer latex-modified mortars are prepared with 5, 10, IS and 20% of polymer cement ratio respectively, and properties of modified mortars such as water absorption, compressive and flexural strengths, chloride-ion penetration depth are tested. The test results indicate that the monomer ratio is very important factors to characterize the strength properties of polymer-modified mortars, but the water absorption and chloride-ion penetration depth are influenced by polymer-cement ratio rather than monomer ratios.

• International Journal of Highway Engineering
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• v.17 no.2
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• pp.39-46
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• 2015

PURPOSES: The objectives of this study were to develop a new polymer-modified emulsion for application to tack coats and to evaluate its properties by comparing it with other types of asphalt emulsions, with the goal of providing an enhanced tack coat material for use in construction. METHODS: Modified asphalt binders were developed from using SBS and SBR latex in the laboratory, and their fundamental properties, such as their penetration index and PG grade, were evaluated. Based on the properties, a new tack coat material was developed. To evaluate the newly developed asphalt emulsion, the bonding strength between the two layers of HMA was measured by applying a uniaxial tensile test and shear test. For the tests, a total of four different conditions were applied to the specimens, including the developed asphalt emulsion, latex modified asphalt emulsion, conventional asphalt emulsion, and non-tack coating. RESULTS AND CONCLUSIONS: Overall, the developed asphalt emulsion exhibits the best bonding strength behavior among all of the three types. Also, the two types of polymer-modified emulsions were found to be better for application for use as a tack coat than a conventional emulsion. Especially, at a high temperature ($50^{\circ}C$), the conventional asphalt emulsion no longer acts as a tack coating material. Therefore, the polymer-modified emulsion should be considered for application to tack coat construction during the summer.

• Polymer(Korea)
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• v.36 no.3
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• pp.364-371
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• 2012

Polystyrene/single-walled carbon nanotube (PS/SWCNT) nanocomposites were prepared by latex technology and the effect of surfactant (SDS) on nanotube dispersion, rheological and electrical properties was investigated. The nanocomposites were prepared through freeze-drying after mixing PS particles and aqueous SWCNT/SDS suspension. As the SDS content increased, the storage modulus and complex viscosity of the nanocomposites were increased due to enhanced dispersion of nanotubes, but if the content excessively increased, the modulus and viscosity began to decrease due to low molecular weight of SDS. The electrical conductivity sharply increased with the addition of SDS, and then did not show significant changes. This result is speculated to be the competition between the increased dispersion of nanotubes and the deterioration of electrical conductivity by SDS adsorption. An optimal ratio of SDS to SWCNT for improving electrical conductivity and end-use properties was 2. With this ratio, the electrical percolation threshold of SWCNT was less than 1 wt%.