• 한국마이크로전자및패키징학회:학술대회논문집
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• 한국마이크로전자및패키징학회 2003년도 기술심포지움 논문집
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• pp.151-155
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• 2003

The requirements for harsh environment electronic controllers in automotive applications have been steadily becoming more and more stringent. Electronic substrate technologists have been responding to this challenge effectively in an effort to meet the performance, reliability and cost requirements. An effect of the plasma cleaning at the alumina substrate and the IMC layer between $Sn-37wt\%Pb$ solder and Ag-Pd thick film conductor after reflow soldering has been studied. Organic residual carbon layer was removed by the substrate plasma cleaning. So the interfacial adhesive strength was enhanced. As a result of AFM measurement, Ag-Pd conductor pad roughness were increased from 304nm to 330nm. $Cu_6Sn_5$ formed during initial ref]ow process at the interface between TiWN/Cu UBM and solder grew by the succeeding reflow process so the grains had a large diameter and dense interval. A cellular-shaped $Ag_3Sn$ was observed at the interface between Ag-Pd conductor pad and solder. The diameters of the $Ag_3Sn$ grains ranged from about $0.1\~0.6{\mu}m$. And a needle-shaped $Ag_3Sn$ was also observed at the inside of the solder.

• 한국세라믹학회지
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• 제23권5호
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• pp.67-74
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• 1986

To investigate the effects of unreacted silicon on the $\alpha$/$\beta$transfornation variation of morphology and mechanical strength of Sintered Reaction Bonded Silicon Nitride the mixtures of $\alpha$-$Si_3N_4$ and Si powder and Reaction Bonded Silicon Nitride were heat treated. The heat-treatments were performed in Ar atmosphere in order to inhibit the nitridation of silicon. In the mixtures heat-trated at 1$700^{\circ}C$ the amount of $\beta$-TEX>$Si_3N_4$transformed from $\alpha$-TEX>$Si_3N_4$was sigmoidally increased and the equiaxed $\alpha$-TEX>$Si_3N_4$grains elongated with the amount of silicon and heat treating time. And large $\beta$-TEX>$Si_3N_4$grains grown into silicon were observed. On the other hand there was no change in the heat-treatment of pure $\alpha$-TEX>$Si_3N_4$In case of the heat-treatment of RBSN the same phenomena due to the silicon appearing from the decomposition of $\alpha$-Smatte and needle were observed. From the three point bending test the strength of the sintered specimens with the and without 5wt% silicon addition had 53Kg/$mm^2$ and 73Kg/$mm^2$ respectively.

• 한국세라믹학회지
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• 제48권6호
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• pp.641-647
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• 2011

The present study aims to identify the effect of sintering atmosphere [$O_2$, 75$N_2$-25 $H_2$ (mol%) and $H_2$] on microstructural evolution at the relatively low sintering temperature of 1040$^{\circ}C$. Samples sintered in $O_2$ showed a bimodal microstructure consisting of fine matrix grains and large abnormal grains. Sintering in 75 $N_2$ - 25 $H_2$ (mol %) and $H_2$ caused the extent of abnormal grain growth to increase. These changes in grain growth behaviour are explained by the effect of the change in step free energy with sintering atmosphere on the critical driving force necessary for rapid grain growth. The results show the possibility of fabricating $(K_{0.5}Na_{0.5})NbO_3$ at low temperature with various microstructures via proper control of sintering atmosphere.

• 한국세라믹학회지
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• 제50권3호
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• pp.180-185
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• 2013

We investigated the characteristics of hot-pressed pure yttria ceramics, and annealed them in an oxidation atmosphere. Regardless of the heat treatment in the oxidation atmosphere, XRD analysis showed that all the samples had a $Y_2O_3$ phase without structural change. Even though the color variation of the hot-pressed $Y_2O_3$ ceramics was due to the sintering temperatures, the oxidation process turned the color of the $Y_2O_3$ ceramics into white. The color change during oxidation treatment appears to be related to oxygen defects. In addition, oxygen defects also affected the weight change and microstructure of the $Y_2O_3$ ceramics. The $Y_2O_3$ ceramic sintered at $1600^{\circ}C$ had a $5.03g/cm^3$ density, which is close to the theoretical density of $Y_2O_3$. As the sintering temperature increased, small homogeneous grains grew to large grains which affected the Vickers hardness. $Y_2O_3$ ceramics hot-pressed at $1600^{\circ}C$ and annealed at $1200^{\circ}C$ had a flexural strength of 140MPa.

• Journal of Photoscience
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• 제5권1호
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• pp.11-15
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• 1998

The texture change of non-linear optical molecules at the air/water interface was investigated as a function of surface pressure with Brewster angle microscopy. The texture change resulted from the aggregation of dye molecules is important to understand the film uniformity and grain formation process. The 4-Octadecylhydroxy-4'-nitrostilbene (OHNS) generated the small spots of size around 1$\mu$m. The spots exhibit high contrast with other film area and do not show angle dependent reflectivity change. It is interesting to observe that the size of the domain stays the same as the film pressure increases. At high surface pressure, the contrast ratio of domains becomes high, which means dense packing of OHNS. And, the size of domain grows. In the middle of domain, highly contrasted domains are formed. The first and the second order transitions of OHNS observed from surface pressure-area isotherm result from the two types of grains. The N,N-Dihexadecylcyanoaniline (DHCA) formed highly contrasted gains over entire region, and the grains are the double layers. The difference in Langmuir film of OHNS and DHCA at the air/water interface is consistent with the small tilt angle from the surface normal for OHNS and the large tilt angle for DHCA in the Langmuir-Blodgett films.

• 한국재료학회지
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• 제30권2호
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• pp.57-60
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• 2020

Titanium aluminides have attracted special interest as light-weight/high-temperature materials for structural applications. The major problem limiting practical use of these compounds is their poor ductility and formability. The powder metallurgy processing route has been an attractive alternative for such materials. A mixture of Ti and Al elemental powders was fabricated to a mechanical alloying process. The processed powder was hot pressed in a vacuum, and a fully densified compact with ultra-fine grain structure consisting of Ti₃Al intermetallic compound was obtained. During the compressive deformation of the compact at 1173 K, typical dynamic recrystallization (DR), which introduces a certain extent of grain refinement, was observed. The compact had high density and consisted of an ultra-fine equiaxial grain structure. Average grain diameter was 1.5 ㎛. Typical TEM micrographs depicting the internal structure of the specimen deformed to 0.09 true strain are provided, in which it can be seen that many small recrystallized grains having no apparent dislocation structure are generated at grain boundaries where well-developed dislocations with high density are observed in the neighboring grains. The compact showed a large m-value such as 0.44 at 1173 K. Moreover, the grain structure remained equiaxed during deformation at this temperature. Therefore, the compressive deformation of the compact was presumed to progress by superplastic flow, primarily controlled by DR.

• Plant Resources
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• 제6권3호
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• pp.178-182
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• 2003

This study was conducted to investigate the relationship between yearly variations of climatic elements and yearly variations of productivity in perilla. In addition, correlation coefficients among yield and yield components were estimated. The data of yield and yield components were investigated for 10 years from 1991 to 2000. The meteorological data gathered at the Yeosu Weather Station for the same period were used to find out the relationships between climatic elements and productivity. Yearly variation of the amount of precipitation in September was large with coefficients of variation(c. v.) of 11.1%, but the coefficient of variance(c. v.) in July and August were relative small with 1.8, 2.1%, respectively. Number of cluster per hill and weight of 1,000 grains were greatly with c. v. of 76.1, 79.3%, respectively, but the coefficients of variance(c. v.) of plant height and seed yield were more less with 9.58, 10.60%, respectively. Correlation coefficients between precipitation of September and seed yield were positively significant correlation at the level of 5.1%, respectively, but the duration of sunshine in September and seed yield were negatively significant at the level of 5.1%, respectively. Correlation coefficients of these, the plant height, number of branches per plant, cluster length, number of cluster per hill, weight of 1,000 grains and seed yield were positively significant at the level of 5.1% respectively.

• 한국재료학회지
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• 제27권1호
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• pp.53-61
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• 2017

Magnesium alloys are of emerging interest in the automotive, aerospace and electronic industries due to their light weight, high specific strength, damping capacity, etc. However, practical applications are limited because magnesium alloys have poor formability at room temperature due to the lack of slip systems and the formation of basal texture, both of which characteristics are attributed to the hcp crystal structure. Fortunately, many magnesium alloys, even commercialized AZ or ZK series alloys, exhibit superplastic behavior and show very large tensile ductility, which means that these materials have potential application to superplastic forming (SPF) of magnesium alloy sheets. The SPF technique offers many advantages such as near net shaping, design flexibility, simple process and low die cost. Superplasticity occurs in materials having very small grain sizes of less than $10{\mu}m$ and these small grains in magnesium alloys can be achieved by thermomechanical treatment in conventional rolling or extrusion processes. Moreover, some coarse-grained magnesium alloys are reported to have superplasticity when grain refinement occurs through recrystallization during deformation in the initial stage. This report reviews the characteristics of superplastic magnesium alloys with high-strain rate and coarse grains. Finally, some examples of SPF application are suggested.

• Journal of Welding and Joining
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• 제26권4호
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• pp.73-78
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• 2008

In this paper, research was the variation of microstructure and mechanical properties of clad(A4045/A3003) Al alloy sheet by gas tungsten arc welding. Tensile properties of the gas tungsten arc welding joint decreased because of the softened heat affected zone(HAZ). The hardness of HAZ was lower than that of base metal, because relieved the work hardening effect of the welding heat. Hardness distribution of the weld zone with the base metal appears similarly, but the hardness of HAZ decreased remarkably. The microstructure in the weld zone of A4045 clad layer was formed a coarse columner grains of Si-rich. In the case of large weld heat input, the Si of the A4045 were diffused and until A3003 weld zone they decreased the strength.

• 한국분말재료학회지
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• 제25권4호
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• pp.331-335
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• 2018

This study investigates the directional recrystallization behavior of Ni based oxide dispersion strengthened (ODS) alloy according to the zone annealing velocity. The zone annealing temperature is set as $1390^{\circ}C$, while the zone velocities are set as 2.5, 4, 6, and 10 cm/h, respectively. The initial microstructure observation of the as-extruded sample shows equiaxed grains of random orientation, with an average grain size of 530 nm. On the other hand, the zone annealed samples show a large deviation in grain size depending on the zone velocities. In particular, grains with a size of several millimeters are observed at 2.5-cm/h zone velocity. It is also found that the preferred orientation varies with the zone annealing velocity. On the basis of these results, this study discusses the role of zone velocities in the directional recrystallization of Ni base ODS alloy.