• 제목/요약/키워드: large diffusion

검색결과 665건 처리시간 0.035초

비정형 혼합재 이동성질의 변동 (Fluctuation of Transport Properties of Random Heterogeneous Media)

  • 김인찬
    • 대한기계학회논문집B
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    • 제20권9호
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    • pp.3015-3029
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    • 1996
  • The notion of effective transport property of a heterogeneous medium implies that the medium is large enough that the ergodic theorem holds and local fluctuation of the property can be neglected. In case that the medium is not large enough compared to its characteristic microstructure length scale, the effective property fluctuates and differs from the value of the medium being large enough. As a representative transport phenomenon, diffusion was considered and the fluctuation of varying effective diffusion property, diffusion coarseness $C_k$, was defined as a quantifying parameter. Scaled effective diffusion property, $^*$>/k$_1$ and $C_k$ were computed for the two phase random media consisting of matrix of diffusion coefficient k$_1$ and spheres of diffusion coefficient k$_2$. Numerical simulations were performed by use of the so-called first passage time technique and data were collected for existing microstructure models of hard spheres(HS), overlapping spheres(OS) and penetrable concentric shells(PCS).

자유 평면 제트유동 해석을 위한 간혈도 난류모델의 개발 (Development of the intermittency turbulence model for a plane jet flow)

  • 조지룡;정명균
    • 대한기계학회논문집
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    • 제11권3호
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    • pp.528-536
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    • 1987
  • 본 연구에서는 간헐적인 유동에 의거한 체적 대류 모델을 설정하고, 구배 확 산 모델에 유동장의 중심부와 외부에서 서로 다른 무게값을 부여하는 혼성 확산 모델 (hybrid diffusion model)을 제안하며, 이 모델을 검증하기 위한 첫 단계로서 평면 제 트 유동에 대하여 수치 계산을 수행하다. 여기에는 간헐도에 대한 난류 전달 방정식 이 필요한데 이 방정식의 생성항(production term)은 곧 외부의 비회전 유동이 난류성 유체로 유입되는 정도를 의미하게 된다.

QUALITATIVE ANALYSIS OF A DIFFUSIVE FOOD WEB CONSISTING OF A PREY AND TWO PREDATORS

  • Shi, Hong-Bo
    • 대한수학회보
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    • 제50권6호
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    • pp.1827-1840
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    • 2013
  • This paper is concerned with the positive steady states of a diffusive Holling type II predator-prey system, in which two predators and one prey are involved. Under homogeneous Neumann boundary conditions, the local and global asymptotic stability of the spatially homogeneous positive steady state are discussed. Moreover, the large diffusion of predator is considered by proving the nonexistence of non-constant positive steady states, which gives some descriptions of the effect of diffusion on the pattern formation.

Self-Diffusion of Hydrophobically End-Capped Polyethylene Oxide Urethane Resin by Using Pulsed-Gradient Spin Echo NMR Spetroscopy

  • Park, Jinwoo;Daewon Sohn;Lee, Youngil;Chaejoon Cheong
    • Macromolecular Research
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    • 제11권6호
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    • pp.444-450
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    • 2003
  • Hydrophobically End-capped polyethylene oxide Urethane Resin(HEUR)-associating polymers, HEUR 35(8), HEUR 35(12), and HEUR 35(18), comprise a polyethylene oxide (PEO) having a molecular weight of 35,000 that is end capped with two C$\_$8/H$\_$17/, C$\_$12/H$\_$25/, and C$\_$18/H$\_$37/ alkyl chains, respectively. These associating polymers were synthesized by condensation reactions with polyethylene oxides and alkyl isocyanates. The self-diffusion coefficients of HEUR-associating polymers were measured in aqueous solution by pulsed-gradient spin-echo (PGSE) nuclear magnetic resonance (NMR) spectroscopy. All polymers underwent a decrease in their mean diffusion coefficients as the concentration was increased. However, the dispersion of the diffusion coefficients, ${\beta}$, about the mean fluctuated with changes in concentration. The large dispersion at low concentrations of HEUR 35(8) and HEUR 35(12) is related to the interaction between hydrophobic end groups, and the large dispersion at high concentrations of HEUR 35(18) is correlated with transient network formation. These results are valuable for predicting the associating mechanism of the large aggregates before and after their critical micelle concentration.

시간에 따라 변화는 회전 각속도를 가지는 원통용기내의 스핀업 (Spin-up in a Cylinder with a Time-Dependent Rotation Rate)

  • 김경석;곽호상;현재민
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집E
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    • pp.456-462
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    • 2001
  • Comprehensive numerical computations are made of a homogenous spin-up in a cylindrical cavity with a time-dependent rotation rate. Numerical solutions are acquired to the governing axisymmetric cylindrical Navier-Stokes equation. A rotation rate formula is ${\Omega}_f={\Omega}_i+{\Delta}{\Omega}(1-{\exp}(-t/t_c))$. If $t_c$ is large, it implies that a rotation change rate is small. The Ekman number, E, is set to $10^{-4}$ and the aspect ratio, R/H, fixed to I. For a linear spin-up(${\epsilon}<<$), the major contributor to spin-up in the interior is not viscous-diffusion term but inviscid term, especially Coriolis term, though $t_c$ is very large. The viscous-diffusion term only works near sidewall. But for spin-up from rest, when $t_c$ is very large, viscous-diffusion term affects interior area as well as sidewall, initially. So azimuthal velocity of interior for large $t_c$ appears faster than that of interior for relatively small $t_c$. However, the viscous-diffusion term of interior decreases as time increases. Instead, inviscid term appears in the interior.

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Diffusion of Probe Molecule in Small Liquid n-Alkanes: A Molecular Dynamics Simulation Study

  • Yoo, Choong-Do;Kim, Soon-Chul;Lee, Song-Hi
    • Bulletin of the Korean Chemical Society
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    • 제29권8호
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    • pp.1554-1560
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    • 2008
  • The probe diffusion and friction constants of methyl yellow (MY) in liquid n-alkanes of increasing chain length were calculated by equilibrium molecular dynamics (MD) simulations at temperatures of 318, 418, 518 and 618 K. Lennard-Jones particles with masses of 225 and 114 g/mol are modeled for MY. We observed that the diffusion constant of the probe molecule follows a power law dependence on the molecular weight of nalkanes, DMY${\sim}M^{-\gamma}$ well. As the molecular weight of n-alkanes increases, the exponent $\gamma$ shows sharp transitions near n-dotriacontane ($C_{32}$) for the large probe molecule (MY2) at low temperatures of 318 and 418 K. For the small probe molecule (MY1) $D_{MY1}$ in $C_{12}$ to C80 at all the temperatures are always larger than Dself of n-alkanes and longer chain n-alkanes offer a reduced friction relative to the shorter chain n-alkanes, but this reduction in the microscopic friction for MY1 is not large enough to cause a transition in the power law exponent in the log-log plot of DMY1 vs M of n-alkane. For the large probe molecule (MY2) at high temperatures, the situation is very similar to that for MY1. At low temperatures and at low molecular weights of n-alkanes, $D_{MY2}$ are smaller than $D_{self}$ of n-alkanes due to the relatively large molecular size of MY2, and MY2 experiences the full shear viscosity of the medium. As the molecular weight of n-alkane increases, $D_{self}$ of n-alkanes decreases much faster than $D_{MY2}$ and at the higher molecular weights of n-alkane, MY2 diffuses faster than the solvent fluctuations. Therefore there is a large reduction of friction in longer chains compared to the shorter chains, which enhances the diffusion of MY2. The calculated friction constants of MY1 and MY2 in liquid n-alkanes supported these observations. We deem that this is the origin of the so-called“solventoligomer”transition.

GLOBAL EXISTENCE OF SOLUTIONS TO THE PREY-PREDATOR SYSTEM WITH A SINGLE CROSS-DIFFUSION

  • Shim, Seong-A
    • 대한수학회보
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    • 제43권2호
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    • pp.443-459
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    • 2006
  • The prey-predator system with a single cross-diffusion pressure is known to possess a local solution with the maximal existence time $T\;{\leq}\;{\infty}$. By obtaining the bounds of $W\array_2^1$-norms of the local solution independent of T we establish the global existence of the solution. And the long-time behaviors of the global solution are analyzed when the diffusion rates $d_1\;and\;d_2$ are sufficiently large.

직접메탄올 연료전지에서 전지 성능에 대한 확산층의 영향 (Effect of Diffusion Layer for Cell Performance in DMFC)

  • 권부길;박경원;최종호;성영은
    • 한국전기화학회:학술대회논문집
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    • 한국전기화학회 2001년도 연료전지심포지움 2001논문집
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    • pp.179-184
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    • 2001
  • The diffusion layer within MEA(membrane electrode assembly) has been evaluated important factor for improvement of cell performance in DMFC. The diffusion layer in MEA structure leads to the reduction of catalyst loss in active catalysts layer as well as prevention of water-flooding in cathode. Cell performance is directly affected by interior properties of diffusion layer materials. Acetylene Black and $RuO_2$ with large pore size and low porosity compared to Vulcan XC-72R gave better performance caused by vigorous methanol diffusion and water removal. And $RuO_2$ as diffusion layer materials showed different behavior in anode and cathode compartment, that is, diffusion layers in anode and cathode side make methanol diffusion and water removal facilitate, respectively.

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다기능 경피 확산 테스트 시스템 설계 및 제작 (Multifunctional Transdermal Diffusion Test System)

  • 고멍얀;김호;박상범
    • 한국기계가공학회지
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    • 제19권10호
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    • pp.8-15
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    • 2020
  • The diffusion cell method is the main technique employed for the in vitro diffusion test of transdermal drug delivery preparations. Most existing transdermal diffusion devices use a water bath heating structure and direct current motor magnetic stirrer. However, these devices are confronted with problems, such as large volume, incompatible vertical and horizontal diffusion cells, few diffusion cell sets, and poor reliability. To overcome these deficiencies, the system adopts a dry heating method and uses a rotating magnetic field generated by the electromagnetic stirrer to drive the magnetic stirrer. Accordingly, the resulting device is characterized by a simple structure and small volume, convenient operation, compatible vertical and horizontal diffusion cells, and numerous diffusion cell sets. The reliability and practicability of the system is verified by the in vitro percutaneous permeability test of the bisoprolol patch.