• Title/Summary/Keyword: ionic components

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Source Identification of PM2.5 at the Tokchok Island on the Yellow Sea (황해상 덕적도 PM2.5오염원의 확인)

  • 윤용석;배귀남;김동술;황인조;이승복;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.4
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    • pp.317-325
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    • 2002
  • An air pollution monitoring station has been operated at Tokchok Island since April 1999 to characterize the background atmosphere in the vicinity of the Yellow Sea. In this study, eight chemical species in PM$_{2.5}$ and three gaseous species were analyzed. A total of 53 samples were collected for the analysis of PM$_{2.5}$ and gaseous species from April, 1999 to April, 2001. The overall mean mass concentration of PM$_{2.5}$ was 20.8 $\mu\textrm{g}$/㎥ and the eight soluble ionic species accounted for about 46.8% of PM$_{2.5}$ mass. Approximately 80% of samples appeared to experience the chloride loss effect. Air pollutant sources of PM$_{2.5}$ measured at Tokchok Island were qualitatively identified by the principal component analysis. It was found that five principal components are secondary aerosol, soil, incineration, phase change of nitrate, and ocean.and ocean.

Fabrication and Straining Model of a CNT/EAP Composite Film (카본나노튜브/도전성폴리머(CNT/EAP) 복합재 필름의 제조 및 특성분석)

  • Zhang, Shuai;Kim, Cheol
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.117-120
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    • 2005
  • The relationship between strain and applied potential was derived for composite actuators consisting single-wall carbon nanotubes (SWNTs) and conductive polymers (CPs). During deriving the relationship, an electrochemical ionic approach is utilized to formulate the electromechanical actuation of the composite film actuator. The results show that the well-aligned SWNTs composite actuator can give good actuation responses and high actuating forces available. The actuation is found to be affected by both SWNTs and CPs components and the actuation of SWNTs component has two kinds of influences on that of the CPs component: reinforcement at the positive voltage and abatement at the negative voltage. CNT/EAP was fabricated successfully using the chemical polymerization method.

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Preparation of Radio-pharmaceuticals-IIl - An evaluation of the eluate from a $^{113}Sn-^{113m}In$ cow system - (방사성의약품 합성방식에 관한 연구 - 제 3 보 - $^{113}In$ cow eluate 검토실험)

  • Kim, You-Sun;Kim, Tae-Young
    • The Korean Journal of Nuclear Medicine
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    • v.3 no.1
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    • pp.69-72
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    • 1969
  • In 1968 total 94,660 mc of radioactive iodocompound were prepared and distributed to the urers. In order to obtain an effective liver scanning In-113 m colloidal of even particle size from a $^{113}Sn-^{113m}In$ cow, the eluate(pH; 1.5) was examined by a radio paper partition chromatography. It was found that the eluate was composed of two components, ionic form and colloidal form. The ionid form could be eliminated by cation exchange resine and the eluate from the ion exchange resine was of even particle size to give an excellent liver scanning result. Labelling of $^{113m}In$ to human serum albumine was attempted.

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Analysis of pH Change and an Automatic pH Control with A New Function:On-Line Estimation of Acetic Acid

  • Jung, Yoon-Keun;Hur, Won
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.2 no.2
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    • pp.69-72
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    • 1997
  • The pH of microbial culture medium was calculated from equations of equilibrium, meterial balances for ionic components and electro-neutrality theory. Ammonium ion consumption and Acetic acid production are found out to be the major contributors for the alteration of the pH as well as the buffer capacity of the medium. By measuring the buffer capacity on-line, levels of acetic acid were estimated by a software sensor using pH signal in a fermentation process of E.coli growing in a minimal medium. The measured values of acetic acid showed good correlation to those of estimated by the software sensor.

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A Study on Natural Dyeing (5) - Adsorption Properties of Berberine for Silk Fabrics - (천연염색에 관한 연구(5) - 황벽색소 베르베린의 견에 대한 염착특성 -)

  • Kim, Hye In;Park, Su Min
    • Textile Coloration and Finishing
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    • v.14 no.2
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    • pp.85-85
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    • 2002
  • The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, 80℃. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.

A Study on Natural Dyeing (5) - Adsorption Properties of Berberine for Silk Fabrics - (천연염색에 관한 연구(5) -황벽색소 베르베린의 견에 대한 염착특성 -)

  • 박수민;김혜인
    • Textile Coloration and Finishing
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    • v.14 no.2
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    • pp.9-17
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    • 2002
  • The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, $80^\circ{C}$. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.

Tunable Photonic Band Gap Materials and Their Applications

  • Gang, Yeong-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.261-261
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    • 2010
  • Photonic band gap (PBG) materials have been of great interest due to their potential applications in science and technology. Their applications can be further extended when PBG becomes tunable against various chemical and electrical stimuli. In recent, it was found that tunable photonic band gap materials can be achieved by incorporating stimuli-responsive smart gels into PBG materials. For example, the characteristic volume phase transition of gels in response to the various external stimuli including temperature, pH, ionic strength, solvent compositions and electric field were recently combined with the unique optical properties of photonic crystals to form unprecedented highly responsive optical components. Since these responsive photonic crystals are capable of reversibly converting chemical or electrical energy into characteristic optical signals, they have been considered as a good platform for label-free chemical or biological detection, actuators or optical switches as well as a model system for investigating gel swelling behavior. Herein, we report block copolymer photonic gels self-assembled from polystyrene-b-poly (2-vinyl pyridine) (PS-b-P2VP) block copolymers. In this talk, we are going to demonstrate that selective swelling of lamellar structure can be effectively utilized for fabricating PBG materials with extremely large tunability. Optical properties and their applications will be discussed.

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Investigation on the cold start characteristics of PEMFC using Axiomatic Design approach (Axiomatic Design 기법을 이용한 연료전지 냉시동 특성 개선에 관한 연구)

  • Suh, Jung-Do;Lee, Sung-Ho;Ahn, Byung-Ki;Lim, Tae-Won;Yu, Ha-Na;Lee, Dai-Gil
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.17-20
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    • 2008
  • Cold start of a fuel cell system is a major obstacle should be overcome as to commercialize it, especially for passenger vehicle applications. However, the cold start characteristics is so complicated since it involves various phenomenon such as ice-blocking in GDL, ionic conductivity in membrane affected by water activity with phase change, heat transfer through components such as bipolarplates or endplates, electro-chemical reactions affected by circumferential temperature and humidity as well. Axiomatic design provides a systematic method to investigate the complex phenomenon although it was developed as a methodology to establish logical design procedure by Nam P. Suh in 1990s. This paper presents a framework to approach the complex cold start problem using Axiomatic Design which features simplifying a problem through hierarchical decomposition and decoupling from the view of functional requirements and design parameters.

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Ion Gel Gate Dielectrics for Polymer Non-volatile Transistor Memories (이온젤 전해질 절연체 기반 고분자 비휘발성 메모리 트랜지스터)

  • Cho, Boeun;Kang, Moon Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.12
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    • pp.759-763
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    • 2016
  • We demonstrate the utilization of ion gel gate dielectrics for operating non-volatile transistor memory devices based on polymer semiconductor thin films. The gating process in typical electrolyte-gated polymer transistors occurs upon the penetration and escape of ionic components into the active channel layer, which dopes and dedopes the polymer film, respectively. Therefore, by controlling doping and dedoping processes, electrical current signals through the polymer film can be memorized and erased over a period of time, which constitutes the transistor-type memory devices. It was found that increasing the thickness of polymer films can enhance the memory performance of device including (i) the current signal ratio between its memorized state and erased state and (ii) the retention time of the signal.

A study on the Coating Structure and Printability of Coated Paper (I) - Effect of Ionic Monomer on Paper-coating Latex Properties - (도공층 구조 및 도공지의 인쇄적성에 관한 연구 (I) - 이온성 단량체가 도공용 라텍스의 물성에 미치는 영향 -)

  • Lee, Yong-Kyu
    • Journal of the Korean Wood Science and Technology
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    • v.25 no.3
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    • pp.75-82
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    • 1997
  • To improve the quality of coated paper, the continuous research to the coating components and development of alternative latices is required. Recently, amphoteric latex is getting a great concern due to their changable properties of surface charge through controlling pH and some methods have been tried to prepare amphoteric latices. This study was carried out to synthesize amphoteric latex using seeding polymerization method with low concentration emulsifier. Styrene was used as a main monomer in addition to acrylonitrile for a hydrophilic comonomer. acrylic acid for a anionic comonomer and N,N-dimethylaminoethyl methacrylate for a cationic comonomer. Particle size and viscosity of latex were greatly affected by addition of acrylic acid and ammonium persulfate as an initiator. Negative charge of latex in alkali condition was changed to zero to positive charge in around pH 4.

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