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A Study on Natural Dyeing (5) - Adsorption Properties of Berberine for Silk Fabrics -  

박수민 (부산대학교 섬유공학과)
김혜인 (부산대학교 섬유공학과)
Publication Information
Textile Coloration and Finishing / v.14, no.2, 2002 , pp. 9-17 More about this Journal
Abstract
The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, $80^\circ{C}$. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.
Keywords
silk; berberine; tannin; adsorption; hydrophobic interaction;
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1 S. M. Park, '천연염색의 색상다양화 및 염색물의 견뢰도 향상 기술의 개발', 산업자원부, 61(2000)
2 S. K. Dho, Thermodynamics of reactive dyes with different functional groups, J. Kor. Soc. of Dyers and Finishers, 10(3), 168-174(1998)
3 Y. J. Lim, N. S. Yoon, and S. H. Song, The effect of hydrophobic interaction on the binding of methyl orange and its hornologs with nylons, Journal of the Korean Society of Textile Engineers and Chemists, 26(1), 41-47(1989)
4 T. Sone, Y. Nakai, T. Yamazaki, and S. Ooya, Dyeing of silk with cationic dyes. Sen-i Gakkaishi, 41(4), T-164(1985)
5 A. E. Hagerman and L. G. Butler, Condensed tannin purification and Charac-tehzation of tannin-associated proteins, J. Asric. Food Chem, 28, 947-952(1980)
6 Y. J. Lim, N. S. Yoon, and C. M. Lee, Thermodynamic analysis for the binding of methyl orange with nylons, Journal of the Koreon Society of Textile Engineers and Chemists, 24(4), 318-323(1987)
7 J. Shore, Aftertreatment of anionic dyes on nylon fibers, J.S.D.C., January, 3-12(1974)
8 N. Hollen, J. Saddler, A. L. Langford, and S. J. Kadolph, 'Textiles', Macmillan Publishing Co., 62(1988)
9 H. I. Kim, S. I. Eom, and S. M. Park, Loess dyeine on cotton fabrics using silane coupling agent, J. Kor. Soc. of Dyers and Finishers, 13(5), 320-345(2001)
10 H. I. Kim, S. I. Eom, and S. M. Park, A syudy on natural dyeing(3), J. Kor. Soc. of Dyers and Finishers, 13(5), 289-297(2001)
11 J. Chrastil, Adsorption of Direct Dyes on Cotton, Tex. Res. J., 60, 413(1990)
12 M. Dohmyo, Y. Shimizu, and M. Kimura, Dyeing of silk with a basic dye, J. Seric. sci. Jpn, 60(30), 161-165(1991)
13 T. Takagishi, K. Takami, and N. Kuroki, J. Poly. Chem. Ed., 13, 437(1975)
14 E. Haslam, Plant Phenolics, Phytochem, 11, 3391-3393(1972)
15 W. D. Loomis, Plant phenolic compounds and the isolation of plant enzymes, Methods Enzymol, 31, 423-438(1974)
16 J. P. Kim, '천연염색의 색상다양화 및 염색물의 견뢰도 향상 기술의 개발', 산업자원부, 191(2000)
17 H. 0. So, 'A study of extracting of the coloring matters and standardizing of the dyeing conditions about the vegetable natural dyestuffs', Ministry of Science & Technology, 50(1995)
18 B. H. Kim and S. S. Cho, Dyeing of silk fabric with Amur cork tree, J. Kor. Soc. of Dyers and Finishers, 8(1), 26-33(1996)
19 E. Haslam, Po1ypheno1-protein interactions, Biochem. J., 139, 285-288(1974)
20 G. J. Smith, I. J. Miller, V. Daniels, and A. J. Smith, White wool, the growth of the ancient dye and an expanding color vocabulary. J.S.D.C., 113, 124-126(1997)
21 M. L. Gulrajani, 'Chemical Processing of Silk', Indian Institute of Technology, 97 (1993)
22 R. S. Davidson, The photodegradation of some naturally occurring polymers, journal of Photochemistry and Photobiology B ; Biology, 33, 3-25(1996)
23 S. W. Nam, 'Studies on modernization. of dyeing method with traditional natural dyes', Ministry of Science & Technology, 420(1995)
24 H. Zollinger, Kinetics of Dyeing from Finite Baths Based on New Information, J.S.D.C., 81, 345(1965)
25 S. Yoshikawa and E. Doi, Interaction between tannic acid and antimony potassium tartrate, Sen-i Gakkaishi, 31(10), T-191-193 (1975)
26 K. R. Cho and M. J. Kang, Studies on the natural dyes(12), J. Kor. Soc. of Dyers and Finishers, 12(4), 13-21(2000)
27 K. S. Kim, Dyeing of silk fabric with Amur cork tree, 建國技術硏究論文志, 24, 215-219 (1999)
28 J. Komiyama and T. Iijima, Some aspects of the Light Fastness of Reactive Azo-Dyes on Cellulose under Wet Condition. J.S.D.C., 93, 217(1977)