Browse > Article

A Study on Natural Dyeing (5) - Adsorption Properties of Berberine for Silk Fabrics -  

Kim, Hye In (부산대학교)
Park, Su Min (부산대학교)
Publication Information
Textile Coloration and Finishing / v.14, no.2, 2002 , pp. 85-85 More about this Journal
Abstract
The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, 80℃. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.
Keywords
silk; berberine; tannin; adsorption; hydrophobic interaction;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Aftertreatment of anionic dyes on nylon fibers /
[ J. Shore ] / J.S.D.C.
2 Plant phenolic compounds and the isolation of plant enzymes /
[ W. D. Loomis ] / Methods Enzymol
3 /
[ N. Hollen;J. Saddler;A. L. Langford;S. J. Kadolph ] / Textiles
4 Studies on the natural dyes(12) /
[ K. R. Cho;M. J. Kang ] / J. Kor. Soc. of Dyers and Finishers
5 Condensed tannin purification and characterization of tannin-associated proteins /
[ A. E. Hegerman;L. G. Butler ] / J. Agric. Food Chem.
6 A study on natural dyeing(3) /
[ H. I. Kim;S. I. Eom;S. M. Park ] / J. Kor. Soc. of Dyers and Finishers
7 /
[ J. P. Kim ] / 천연염색의 색상다양화 및 염색물의 견뢰도 향상 기술의 개발
8 Interaction between tannic acid antimony potassium tartrate /
[ S. Yoshikawa;E. Doi ] / Sen-i Gakkaishi
9 Adsorption of Direct Dyes on Cotton /
[ J. Chrastil ] / Tex. Res. J.
10 Thermodynamic analysis for the binding of metyl orange with nylons /
[ Y. J. Lim;N. S. Yoon;C. M. Lee ] / Journal of the Korean Society of Textile Engineers and Chemists
11 Dyeing of silk with cationic dyes /
[ T. Sone;Y. Nakai;T. Yamazaki;S. Ooya ] / Sen-i Gakkaishi
12 Polphenol-protein interactions /
[ E. Haslam ] / Biochem.J.
13 Plant Phenolics /
[ E. Haslam ] / Phytochem.   ScienceOn
14 Dyeing of silk with a basic dye /
[ M. Dohmyo;Y. Shimizu;M. Kimura ] / J. Seric. Sci. Jpn.
15 Dyeing of silk fabric with Amur cork tree /
[ K. S. Kim ] / 建國技術硏究論文志
16 The effect of hydrophobic interaction on the binding of methyl orange and its homologs with nylons /
[ Y. J. Lim;N. S. Yoon;S. H. Song ] / Journal of the Korean Society of Textile Engineers and Chemists
17 Dyeing of silk fabric with Amur cork tree /
[ B. H. Kim;S. S. Cho ] / J. Kor. Soc. of Dyers and Finishers
18 /
[ T. Takagishi;K. Takami;N. Kuroki ] / J. Poly. Chem. Ed.   ScienceOn
19 Loess dyeing on cotton fabrics using silane coupling agent /
[ H. I. Kim;S. I. Eom;S. M. Park ] / J. Kor. Soc. of Dyers and Finishers
20 /
[ M. L. Gulrajani ] / Chemical Processing of Silk
21 Thermodynamics of reactive dyes with different functional groups /
[ S. K. Dho ] / J. Kor. Soc. of Dyers and Finishers
22 /
[ S. M. Park ] / 천연염색의 색상다양화 및 염색물의 견뢰도 향상 기술의 개발
23 Kinetics of Dyeing from Finite Baths Based on New Information /
[ H. Zollinger ] / J.S.D.C.
24 /
[ S. W. Nam ] / Studies on modernization of dyeing method with traditonal natural dyes
25 Some aspects of the Light Fastness of Reactive Azo-Dyes on Cellulose under Wet Condition /
[ J. Komiyama;T. Iijima ] / J.S.D.C.
26 /
[ H. O. So ] / A study of extracting of the coloring matters and standardizing of the dyeing conditions about the vegetable natural dyestuffs
27 White wool, the growth of the ancient dye and an expanding color vocabulary /
[ G. J. Smith;I. J. Miller;V. Daniels;A. J. Smith ] / J.S.D.C.
28 The photodegradation of some naturally occurring polymers /
[ R. S. Davidson ] / Journal of Photochemistry and Photobiology B; Biology   ScienceOn