• Title/Summary/Keyword: interface property

검색결과 569건 처리시간 0.028초

액중건조법으로 제조한 Retinol 함유 마이크로캡슐의 방출 거동 (Controlled Release of Retinol Containing Microcapsules Prepared by Solvent Evaporation Method)

  • 김세라;신영재;이천일;표형배;신재섭
    • 접착 및 계면
    • /
    • 제9권2호
    • /
    • pp.1-7
    • /
    • 2008
  • 생분해성이 있는 polycaprolactone을 사용하여 용액 상태에서 건조시키는 방법으로 마이크로 캡슐을 제조하였다. 심물질로는 화장품 분야에서 중요한 성분으로 쓰이는 retinol을 선택하였으며 안정제로는 poly(vinyl alcohol)을 사용하였다. 제조 조건에 따른 마이크로캡슐의 형태 변화와 물성 변화를 scanning electron microscope와 differential scanning calorimeter를 이용하여 측정하였으며 심물질의 방출 속도에 미치는 영향들을 UV를 이용하여 측정하였다. 사용한 벽재 물질 용액의 농도, 교반속도, 안정제의 농도 등을 변화 시켜 가면서 마이크로캡슐을 제조하여 보았으며, 최적 조건에서 지름이 5~6 um인 구형 모양의 균일한 크기를 갖는 마이크로캡슐들이 형성되었음을 확인하였다.

  • PDF

Ink Binder용 UV 경화형 조성물의 제조 및 특성 (Preparation and Properties of UV Curable Urethane Acrylates for Ink Binder)

  • 박현주;한창덕;오상택
    • 접착 및 계면
    • /
    • 제14권4호
    • /
    • pp.167-174
    • /
    • 2013
  • 본 연구에서는 ink binder용으로 isophorone diisocyanate (IPDI)/polyether polyol/2-hydroxyethyl acrylate (HEA)계 UV 경화형 우레탄 아크릴레이트를 중합하였다. HEA/PETA 혼합 비율을 달리한 조성물의 UV 조사 시간에 따른 광경화거동을 FT-IR spectrophotometer, probe tack tester 및 Photo-DSC로 확인하였다. UV 조사 시간이 증가함에 따라 전환률 및 gel content는 증가하였으며 probe tack은 감소하였다. 반응성 희석제로 사용한 PETA 함량이 증가함에 따라 저장탄성률, 인장강도 및 초기분해 온도가 증가하였다. HEA/PETA 비율이 30/70인 경우 UV 경화 후 PMMA sheet에 대한 부착특성이 가장 우수하였다.

일방향응고시킨 Al-Co 합금의 특성에 관한 연구 (Characteristics of the Unidirectionally Solidified Al-Co Alloy)

  • 박수정;전현용;이현규
    • 한국주조공학회지
    • /
    • 제25권1호
    • /
    • pp.30-35
    • /
    • 2005
  • The structures and mechanical property of the unidirectionally solidified Al-Co eutectic alloy were investigated. Al-Co eutectic alloy was unidirectionally solidified with growth rates(R) between I cm/hr and 10 cm/hr in the induction furnace maintaining the thermal gradient (G) at solid-liquid interface, $32^{\circ}C$/cm. The eutectic microstructure was varied with the growth condition(G/R ratio). When the G/R ratio was larger than $8.5{\times}10^{3}^{\circ}C/cm^{2}/sec$, a lamellar structure was formed, But the G/R ratio was smaller than $8.5{\times}10^{3}^{\circ}C/cm^{2}/sec$, a colony structure was formed. It was found that the interlamellar spacing(${\lambda}$) was dependent on the growth rate(R) with the relationship, ${\lambda}^{2}{\cdot}R=constant$. The microhardness of this eutectic alloy increased with increase in the growth rate.

Mechanistic Analysis of Geogrid Base Reinforcement in Flexible Pavements Considering Unbound Aggregate Quality

  • Kwon Jay-Hyun;Tutumluer Erol;Kim Min-Kwan
    • 한국도로학회논문집
    • /
    • 제8권2호
    • /
    • pp.37-47
    • /
    • 2006
  • The structural response and performance of a flexible pavement can be improved through the use of geogrids as base course reinforcement. Current ongoing research at the University of illinois has focused on the development of a geogrid base reinforcement mechanistic model for the analysis of reinforced pavements. This model is based on the finite element methodology and considers not only the nonlinear stress-dependent pavement foundation but also the isotropic and anisotropic behavior of base/subbase aggregates for predicting pavement critical responses. An axisymmetric finite element model was developed to employ a three-noded axisymmetric membrane element for modeling geogrid reinforcement. The soil/aggregate-geogrid interface was modeled by the three-noded membrane element and the neighboring six-noded no thickness interface elements. To validate the developed mechanistic model, the commercial finite element program $ABAQUS^{TM}$ was used to generate pavement responses as analysis results for simple cases with similar linear elastic material input properties. More sophisticated cases were then analyzed using the mechanistic model considering the nonlinear and anisotropic modulus property inputs in the base/subbase granular layers. This paper will describe the details of the developed mechanistic model and the effectiveness of geogrid reinforcement when used in different quality unbound aggregate base/subbase layers.

  • PDF

SM45C 중실축의 마찰용접 기계적 특성에 관한 연구 (A Study on the Mechanical Properties of the Friction Welding with Solid Shaft of SM45C)

  • 구건섭
    • 한국생산제조학회지
    • /
    • 제21권6호
    • /
    • pp.932-937
    • /
    • 2012
  • In the presented study, SM45C carbon steel parts were joined by friction welding. The welding process was carried out under optimized conditions using statistical approach. The study of SM45C is conducted with various combinations of process parameters. Parameter optimization, microstructure and mechanical property correlation are the major contribution of the study. The welded joints were produced by varying spindle revolution speed, friction pressure, upset pressure and burn-off length. Tension tests were applied to welded parts to obtain the strength of the joints. Fracturs properties were additionally obtained experimentally under fluctuated tensile loads. Microstructures using microphotographs were examined in the weld interface and weld region and heat affected zone and base metal and flash zone of welded parts. Finally, Hardness variations in welding zone and base metal were also obtained. Through these tests, the optimum conditions of parameters for ${\phi}20$ SM45C in friction welding were obtained when the friction spindle revolution was 1,950 rpm, the friction pressures was 30 MPs, upset pressures was 50 MPs.

광학모델을 이용한 자외선 접촉조 최적 설계에 관한 연구 (A Study on Optimal Design of UV Contactor using an Optical Radiation Model)

  • 최영균;김두일;김성홍
    • 한국물환경학회지
    • /
    • 제25권4호
    • /
    • pp.547-552
    • /
    • 2009
  • Because of refractory property of light, the travel path of UV light becomes longer than the straight line and shorter solely in water as UV light passes sequentially through air, quartz and water. Note that water significantly absorbs UV light. Hence, UV intensity shall be estimated to be lower when refraction is neglected than it is considered. Reflection is also critical for the design of UV radiation system. While the reflection at the interface of air and quartz is low enough to ignore, it is too high to be ignored at the interface of quartz and water. Assuming constant power, smaller length to width ratio of UV reactor is beneficial and single-lamp system is preferred to multi-lamps. Under the given cross section, optimal lamp positions could be decided. For example of an elliptical reactor with dual lamps, the optimal lamp locations shall be the 1/3 and 2/3 position of the longer axis.

Low Dissipative AUSM-type 수치기법 개발 (Development of Low Dissipative AUSM-type Scheme)

  • 김규홍
    • 한국항공우주학회지
    • /
    • 제32권9호
    • /
    • pp.12-26
    • /
    • 2004
  • 수치점성을 효과적으로 줄이기 위한 새로운 AUSM-type 수치기법을 개발하였다. TVD 제한자 분석을 통하여 제어면에서의 불성치를 보다 정확하게 예측할 수 있는 기준을 찾아내고 이를 이용하여 제어면의 물성치를 적절히 정의하는 M-AUSMPW+를 개발하였다. M-AUSMPW+의 장점은 다차원 유동을 해석하는데 있어 분명히 나타난다. M-AUSMPW+ 는 유동과 격자계가 일치하지 않는 격자계에서 수치점성을 효과적으로 제거할 수 있기 때문에 다차원 유동을 계산하는데 있어 기존의 어떠한 수치기법보다 정확하고 효과적인 계산이 가능하다. 접촉불연속면, 와류 유동, 충격파 경계층 상호작용, 정성 충격파관 문제를 통해 이를 확인하였다.

Acid Group이 도입된 TPV (Thermoplastic Vulcanizate)계 열가소성 탄성체의 기계적 물성에 관한 연구 (Studies on Mechanical Properties of Thermoplastic Vulcanizate Containing Acid Group)

  • 김동호;김구니
    • 접착 및 계면
    • /
    • 제16권2호
    • /
    • pp.63-68
    • /
    • 2015
  • 본 연구에서는 carboxylic acid group이 도입된 열가소성 폴리우레탄(thermoplastic polyurethane, TPU)과 동적 가교형 TPV (thermoplastic vulcanizate)계 열가소성 탄성체를 제조하였으며, 탄성체 분자구조 내 acid group의 도입에 따른 기계적 물성, 그립성, 데브리스, 접촉각 및 접착특성 변화에 대해서 평가하였다. 연구결과 acid group이 도입된 경우 수소결합의 증가로 인해 기계적 물성과 wet slip 특성이 향상되었으며, 카르복시산에 의해 표면 극성이 증가되었기 때문에 접착력 또한 향상되었다. 그리고 acid group이 도입된 TPU를 사용해서 TPV를 제조한 결과 TPU 자체에 비해 감성특성과 데브리스(debris) 특성이 향상되었다.

Seed 중합을 이용한 고고형분 수용성 점착제의 합성과 물성 (Property and Polymerization of Hi-solid PSA's using Seeded Polymerization)

  • 정영식;민성기;설수덕
    • 접착 및 계면
    • /
    • 제10권4호
    • /
    • pp.174-181
    • /
    • 2009
  • 고 고형분 점착제의 점도 개선을 위해 seed 중합을 이용하여 수용성 저점도 점착제를 중합하였다. Seed 바인더 중합 중 최적 중합 조건을 산출하고, 점착제 중합 시 seed 바인더와 acrylic acid의 함량을 변화시켜 점도변화와 피착면에 대한 점착박리강도를 측정하여 다음과 같은 결과를 얻었다. 점착제 중합에서 seed 바인더의 함량이 7 wt%/monomer일 때 60%의 고형분에서 2,100 cps의 낮은 점도를 나타내고 평활한 점착제 필름을 제조할 수 있었다. Acrylic acid함량 변화에 따른 기계적 물성 측정에서는 4 wt%/monomer의 acrylic acid를 사용 했을 때 우수한 점착박리강도와 유지력을 나타내었다.

  • PDF

고온 프레스법에 의한 TiNi/Al2024 복합재료의 제조 및 기계적 특성평가 (Fabrication and Mechanical Properties of TiNi/Al2024 Composites by Hot-Press Method)

  • 손용규;배동수;박영철;이규창
    • 소성∙가공
    • /
    • 제18권1호
    • /
    • pp.45-51
    • /
    • 2009
  • Shape memory alloy has been used to improve the tensile strength of composite by the occurrence of compressive residual stress in matrix using its shape memory effect. In order to fabricate shape memory alloy composite, TiNi alloy fiber and Al2024 sheets were used as reinforcing material and matrix, respectively. In this study, TiNi/Al2024 shape memory alloy composite was made by using hot press method. In order to investigate bonding condition between TiNi reinforcement and Al matrix, the micro-structure of interface was observed by using optical microscope and diffusion layer of interface was measured by using Electron Probe Micro Analyser. And the mechanical properties of composite with three parameters(volume fraction of fiber, cold rolling amount and test temperature) were obtained by tensile test. The most optimum bonding condition for fabrication the TiNi/Al2024 composite material was obtained as holding for 30min. under the pressure of 60MPa at 793K. The strength of composite material increased considerably with the volume fraction of fiber up to 7.0%. And the tensile strength of this composite increased with the reduction ratio and it also depends on the volume fraction of fiber.