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http://dx.doi.org/10.17702/jai.2013.14.4.167

Preparation and Properties of UV Curable Urethane Acrylates for Ink Binder  

Park, Hyun-Ju (Korea Institute of Footwear & Leather Technology)
Han, Chang-Duk (CNFK Co., Ltd.)
Oh, Sang-Taek (Korea Institute of Footwear & Leather Technology)
Publication Information
Journal of Adhesion and Interface / v.14, no.4, 2013 , pp. 167-174 More about this Journal
Abstract
In this study, Ultraviolet (UV) curable urethane acrylates for ink binder was prepared by reaction of IPDI, polyether polyol and HEA. The UV curing behavior of compositions with HEA/PETA ratio on UV irradiation time was investigated by FT-IR spectrophotometer, probe tack tester and Photo-DSC. Conversion % and gel content were increased with increasing UV irradiation time, but probe tack was decreased. Storage modulus, tensile strength and decomposition temperature were increased as PETA content increased. In case of HEA/PETA ratio was 30/70, adhesion property of UV-cured composition on PMMA sheet was excellent.
Keywords
ink binder; urethane acrylate; UV coating; PMMA;
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1 V. Jancovicova, M. Mikula, B. Havlinova, and Z. Jakubikova, Prog. Org. Coat., 76, 432 (2013).   DOI   ScienceOn
2 T. A. Speckhard, K. K. S. Hwang, S. B. Lin, S. Y. Tsay, M. Koshiba, Y. S. Ding, and S. L. Cooper, J. Appl. Polym. Sci., 30, 647 (1985).   DOI   ScienceOn
3 K. H. Hsieh, C. H. Kuo, C. A. Dai, W. C. Chen, T. C. Peng, and G. H. Ho, J. Appl. Polym. Sci., 91, 3162 (2004).   DOI   ScienceOn
4 C. Decker, Macromol. Rapid Commun., 23, 1067 (2002).   DOI   ScienceOn
5 J. N. Tey, A. M. Soutar, S. G. Mhaisalkar, H. Yu, and K. M. Hew, Thin Solid Films, 504, 384 (2006).   DOI   ScienceOn
6 A. Chiolerio, L. Vescovo, and M. Sangermano, Macromol. Chem. Phys., 211, 2008 (2010).   DOI   ScienceOn
7 F. Wang, J. Q. Hu, and W. P. Tu, Prog. Org. Coat., 62, 245 (2008).   DOI   ScienceOn
8 A. R Han, J. G. Kim, J. W. Hong, and H. K. Kim, J. adhes. interface, 13, 1 (2012).
9 E. S. Park, H. D Hwang, C. H Park, Y. H Lee, J. I Moon, and H. J. Kim, J. adhes. interface, 12, 2 (2011).
10 J. W. Yoo and D. S. Kim, Polymer (Korea), 23, 376 (1999).
11 D. Kunwong, N. Sumanochitraporn, and S. Kaewpirom, Songklanakarin J. Sci. Technol., 33, 2 (2011).
12 대한민국 특허, 10-2012-0056339.
13 K. M. I. Ali, M. A. Khan, M. M. Zaman, and M. A. Hossain, J. Appl. Polym. Sci., 54, 309 (1994).   DOI   ScienceOn
14 일본 특허, 2012158672.
15 일본 특허, 2012009364.
16 B. Nabeth, J. F. Gerard, and J. P. Pascault, J. Appl. Polym. Sci., 60, 2113 (1996).   DOI   ScienceOn
17 S. F. Thames and Z. A. He, J. Appl. Polym. Sci., 54, 951 (1994).   DOI   ScienceOn
18 M. A. Ali, M. A. Khan, and K. M. I. Ali, J. Appl. Polym. Sci., 60, 879 (1996).   DOI
19 S. Kumari, A. K. Mishra, D. K. Chattopadmay, and K. V. S. V. Raju, J. Polym. Sci. Part A: Polym. Chem., 45, 2673 (2007).   DOI   ScienceOn
20 A. Srivastava, D. Agarwal, S. Mistry, and J. Singh, Pigment & Resin Technol., 37, 217 (2008).   DOI   ScienceOn
21 B. K. Kim, K. H. Lee, and H. D. Kim, J. Appl. Polym. Sci., 60, 799 (1996).   DOI