• Title/Summary/Keyword: inter-particle

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CMP properties of $SnO_2$ thin film by different slurry (슬러리 종류에 따른 $SnO_2$ 박막의 광역평탄화 특성)

  • Lee, Woo-Sun;Choi, Gwon-Woo;Ko, Pil-Ju;Kim, Wan-Tae;Seo, Yong-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.389-392
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    • 2004
  • As the integrated circuit device shrinks to the smaller dimension, the chemical mechanical polishing (CMP) process was required for the global planarization of inter-metal dielectric(IMD) layer with free-defect. The effect of alternative commerical slurries pads, and post-CMP cleaning alternatives are discuess, with removal rate, scratch dentisty, surface roughness, dishing, erosion and particulate density used as performance metrics. we investigated the performance of $SnO_2$-CMP process using commonly used silica slurry, ceria slurry, tungsten slurry. This study shows removal rate and non-uniformity of $SnO_2$ thin film used to gas sensor by using Ceria, Silica, W-Slurry after CMP process. This study also shows the relation between particle size and CMP with particle size analysis of used slurry.

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COLLECTIVE BEHAVIORS OF SECOND-ORDER NONLINEAR CONSENSUS MODELS WITH A BONDING FORCE

  • Hyunjin Ahn;Junhyeok Byeon;Seung-Yeal Ha;Jaeyoung Yoon
    • Journal of the Korean Mathematical Society
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    • v.61 no.3
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    • pp.565-602
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    • 2024
  • We study the collective behaviors of two second-order nonlinear consensus models with a bonding force, namely the Kuramoto model and the Cucker-Smale model with inter-particle bonding force. The proposed models contain feedback control terms which induce collision avoidance and emergent consensus dynamics in a suitable framework. Through the cooperative interplays between feedback controls, initial state configuration tends to an ordered configuration asymptotically under suitable frameworks which are formulated in terms of system parameters and initial configurations. For a two-particle system on the real line, we show that the relative state tends to the preassigned value asymptotically, and we also provide several numerical examples to analyze the possible nonlinear dynamics of the proposed models, and compare them with analytical results.

Properties of Inter-Locking Block with the Contents of the Fine Particles (미립분의 혼입율 변화에 따른 인터로킹 블록의 특성)

  • 이상태;김기철;신병철;이동남;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.171-174
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    • 1999
  • The objective of this study is to investigate the properties of fine particles in the process of producing crushed fine aggregates under various fine particle contents. According to the test results, when fine particles are added as substitution of aggregates by about 10%, it shows that the qualities of interlocking block such as compressive strength, flexural strength and absorption ratio are improved. The application of fine particles provide various advantages in the sides of recycling of materials

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Effects of Oxidation and Hot Corrosion on the Erosion of Silicon Nitride

  • Kim, Jong Jip
    • Corrosion Science and Technology
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    • v.4 no.4
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    • pp.136-139
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    • 2005
  • The effect of oxidation and hot corrosion on the solid particle erosion was investigated for hot-pressed silicon nitride using as-polished, pre-oxidized and pre-corroded specimens by molten sodium sulfates. Erosion tests were performed at 22, 500 and $900^{\circ}C$ using angular silicon carbide particles of mean diameter $100{\mu}m$. Experimental results show that solid particle erosion rate of silicon nitride increases with increasing temperature for as-polished or pre-oxidized specimens in consistent with the prediction of a theoretical model. Erosion rate of pre-oxidized specimens is lower than that of as-polished specimens at $22^{\circ}C$, but it is higher at $900^{\circ}C$. Lower erosion rate at $22^{\circ}C$ in the pre-oxidized specimens is attributed due to the blunting of surface flaws, and the higher erosion rate at $900^{\circ}C$ is due to brittle lateral cracking. Erosion rate of pre-corroded specimens decreases with increasing temperature. Less erosion at $900^{\circ}C$ than at $22^{\circ}C$ is associated with the liquid corrosion products sealing off pores at $900^{\circ}C$ and the absence of inter-granular crack propagation observed at $22^{\circ}C$.

Rate Capability of Electric Double-Layer Capacitor (EDLC) Electrodes According to Pore Length in Spherical Porous Carbons

  • Ka, Bok-H.;Yoon, Song-Hun;Oh, Seung-M.
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.252-256
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    • 2007
  • A series of spherical porous carbons were prepared via resorcinol-formaldehyde (RF) sol-gel polymerization in the presence of cationic surfactant (CTAB, cetyltrimethylammonium bromide), wherein the carbon sphere size was controlled by varying the CTAB introduction time after a pre-determined period of addition reaction (termed as "pre-curing"). The sphere size gradually decreases with an increase in the pre-curing time within the range of 30-150 nm. The carbons possess two types of pores; one inside carbon spheres (intra-particle pores) and the other at the interstitial sites made by carbon spheres (inter-particle pores). Of the two, the surface exposed on the former was dominant to determine the electric double-layer capacitor (EDLC) performance of porous carbons. As the intra-particle pores were generated inside RF gel spheres by gasification, the pore diameter was similar for all these carbons, thereby the pore length turned out to be a decisive factor controlling the EDLC performance. The charge-discharge voltage profiles and complex capacitance analysis consistently illustrate that the smaller-sized RF carbons deliver a better rate capability, which must be the direct result of facilitated ion penetration into shorter pores.

Improved Flowability and Wettability of Whey Protein-Fortified Skim Milk Powder via Fluidized Bed Agglomeration

  • Seo, Chan Won
    • Food Science of Animal Resources
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    • v.42 no.6
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    • pp.915-927
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    • 2022
  • Recently, protein-fortified milk powders are being widely consumed in Korea to prevent sarcopenia, and the demand for high-protein food powders is continuously increasing in the Korean market. However, spray-dried milk proteins have poor flowability and wettability owing to their fine particle sizes and high inter-particle cohesive forces. Fluidized bed agglomeration is widely used to improve the instant properties of food powders. This study investigated the effect of fluidized bed agglomeration on whey protein isolate (WPI)-fortified skim milk powder (SMP) at different SMP/WPI ratios. The fluidized bed process increased the particle size distribution, and agglomerated particles with grape-like structures were observed in the SEM images. As the size increased, the Carr index (CI) and Hausner ratio (HR) values of the agglomerated WPI-fortified SMP particles exhibited excellent flowability (CI: <15) and low cohesiveness (HR: <1.2). In addition, agglomerated WPI-fortified SMP particles exhibited the faster wetting time than the instant criterion (<20 s). As a result, the rheological and physical properties of the WPI-fortified SMP particles were effectively improved by fluidized bed agglomeration. However, the fluidized bed agglomeration process led to a slight change in the color properties. The CIE L* decreased, and the CIE b* increased because of the Maillard reaction. The apparent viscosity (ηa,10) and consistency index (K) values of the rehydrated solutions (60 g/180 mL water) increased with the increasing WPI ratio. These results may be useful for formulating protein-fortified milk powder with better instant properties.

Analysis of Regional and Inter-annual Changes of Air Pollutants Emissions in China (중국 대기오염물질 배출의 시공간적 변화 분석)

  • Woo, Jung-Hun;Bu, Chanjong;Kim, Jinsu;Ghim, Young Sung;Kim, Younha
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.1
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    • pp.87-100
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    • 2018
  • Fast economic growth and urbanization of China have been causing air pollution not only over its domestic but transboundary atmosphere. Recent high fine particle pollution episodes in China made the government move toward more stringent air pollution control policies - which are mostly fuel switching and emissions control. In this research, we tried to understand characteristics of Chinese emissions and their change by analyzing its emissions inventory by year, sector, and region. From the inter-comparison of existing bottom-up emission inventories, we found relatively good agreements (<20% difference) for $SO_2$ and $NO_x$, but 30% or more discrepancies for some pollutants. Inter-comparison with top-down $NO_x$ emissions estimates also showed 20~50% differences by year. The regional distribution and inter-annual changes of emissions revealed different stages of energy/fuel mix and policy penetration. Early increase of pollutants emissions in the eastern part of China might give strong influences to the Korean peninsular in early 2000s but, more stringent control in that region would help improving air pollution in Korea in near future.

The research about properties of modified low heat slag cement (개질 처리된 저발열 슬래그시멘트 특성에 관한 연구)

  • Kim, Hong-Joo;Kim, Won-Ki;Kim, Hoon-Sang;Lee, Won-Jun;Shin, Jin-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.677-680
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    • 2008
  • The surface of particles was energetically modified by inter-grinding OPC and BFS in vibration mill for improvement of the early strength and low-heat evolution of concretes. BFS was pre-grinding in ball-mill to 2535(BS2) and 3245 $cm^2/g$(BS3), in blaine surface area. The inter-grinding time in vibration mill was changed from 10 minutes to 30 minutes. And Mixing ration of BFS to OPC was changed in 60, 70, 80%. After inter-grinding, the change of specific surface area, particle size distribution, hydration heat of cement and compressive strength of mortar were measured. As the result of comparison test with LHC, it was found that the mixture and inter-grinding time satisfying the value of over 100% of compressive strength for 7 days and under 170J/g of heat of hydration for 72 hours. and it was confirmed that the possibility of low heat slag cement utilizing blast furnace slag(BS2, BS3) with the low fineness in high volumes.

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Seasonal Characteristics of PM2.5 Water Content at Seoul and Gosan, Korea (서울과 고산의 PM2.5 수분함량 계절 특성)

  • Lee, Hyung-Min;Kim, Yong-Pyo
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.1
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    • pp.94-102
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    • 2010
  • Water content of $PM_{2.5}$ (particles in the atmosphere with a diameter of less than or equal to a nominal $2.5{\mu}m$) was estimated by using a gas/aerosol equilibrium model, SCAPE2, for the particles collected at Seoul and Gosan, Korea. From measured and analyzed characteristics of the particles, the largest difference between Seoul and Gosan is the proportions of total ammonia (t-$NH_3$=gas phase $NH_3$+particle phase ${NH_4}^+$), total nitric acid (t-$HNO_3$=gas phase $HNO_3$+particle phase ${NO_3}^-$) and sulfuric acid ($H_2SO_4$). Even though both sites have sufficient t-$NH_3$ to neutralize acidic species such as $H_2SO_4$, t-$HNO_3$, and t-HCl (total chloric acid=gas phase HCl+particle phase $Cl^-$), equivalent fraction of t-$NH_3$ and t-$HNO_3$ are higher at Seoul and $H_2SO_4$ is higher at Gosan. Based on the modeling result, it is identified that the $PM_{2.5}$ at Seoul is more hygroscopic than Gosan if the meteorological conditions are the same. To reduce water content of $PM_{2.5}$, and thus, mass concentration, control measures for ammonia and nitrate reduction are needed for Seoul, and inter-governmental cooperation is required for Gosan.