• Title/Summary/Keyword: inorganic(organic) acid

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Electrical Properties of Organic/Inorganic Hybrid Composites for Insulation Materials

  • Kim, Sang-Cheol;Ok, Jeong-Bin;Aho, Myeong-Jin;Park, Do-Hyun;Lee, Gun-Joo
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.1
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    • pp.9-13
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    • 2002
  • In this work, the surface of inorganic fillers were modified with some functional groups such as stearic acid, aliphatic long chain, vinylsilane and aminosilane to control the interaction between inorganic fillers and polymer matrix. Ethylene-vinyl acetate copolymers (EVA) with various amount of vinyl-acetate and copolyether-ester elastomer were used as polymer matrix. The addition of inorganic fillers increases flame retardancy, but results in steep drop of electrical and mechanical properties, which may be caused by the defects in the interface between organic/inorganic hybrid composites. The hybrid composites are found to show better mechanical properties and higher volume resistivities as inorganic fillers are well dispersed and have good adhesion with polymer matrix. Also, the most effective type of functional group coated on fillers depends on the chemical structure of polymer.

Synthesis and Luminescence Preparation of Organic/Inorganic Polymer Hybrid from Novolac Derivatives

  • Konishi, Gen-ichi;Kimura, Tsuyoshi
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.316-316
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    • 2006
  • The preparation of an organic/inorganic polymer hybrid from a novolac derivatives is described. The hybrid was prepared by the acid-catalyzed solgel reaction of phenyl-trimethoxysilane (PhTMOS) in the presence of anisole novolac. The resulting film was transparent and showed a high heat stability. The dispersion of two components might be due to the utilization of the p-p interaction between the phenyl ring of the silica matrix and that of novolac. This makes it possible to prepare a hybrid glass having a highly content of novolac derivatives.

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Development of Fluid Silicic Acid Coating with Paint Materials of the Steel Electric Power Facilities (강재 전력시설물을 위한 액상 규산질 도장제 개발에 대한 연구)

  • Kwon, Seung-Jun;Park, Sang-Sun;Lee, Sang-Min;Lee, Myung-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.1
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    • pp.57-64
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    • 2008
  • Generally, organic paint on steel towers can guarantee durability in normal condition but occasionally shows its deterioration on the power line tower and electric power facilities, exposed to light(ultra violet) or heat. The objective of this study is to develope the inorganic paint material based on fluid silicic acid for steel electric power facilities. For the purpose, optimal mixture proportion is derived through 6 preliminary test and, additionally physical and durability performance test are carried out for selected specimens. The performances of developed organic paint material is similar to those of organic paint material. If resistance to chemical attack is improved, the developed inorganic paint is evaluated to replace the organic paint and obtain wide application.

Influence of light Regime on Nitrate Reductase Activity and Organic and norganic Solute Composition of Four Sedges (Carex spp.)

  • Choo, Yeon-Sik;Roland-Albert;Song, Seung-Dal
    • Animal cells and systems
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    • v.2 no.4
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    • pp.455-462
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    • 1998
  • A survey was conducted on the inorganic and organic solute patterns of plants in connection with nitrate metabolism according to different light regimes (1.9, 16.0, 91.5 $Wm^{-2}$). Besides measuring in vivo NRA, we also quantitatively analyzed ater-soluble inorganic ions, organic acids, low molecular weight carbohydrates, amino aciss and total N (% DW). Among 4 Carex species, C. pilosa is known as shade-adapted species and the others as half (C. gracilis) to full (C. rostrata & C. distans) light-adapted species. Compared to species adapted to high light intensity, shade-adapted C. pilosa showed reduced productivity under the highest light intensity. In general, nitrate and amino acid levels decreased at higher light intensity, while sugar and organic acid concentrations increased. In C. pilosa osmolality tended to rise with increasing light intensity, while in the other species it tended to fall. Under low light intensity, the drop in soluble carbohydrate contents is osmotically compensated for by an enhanced nitrate concentration. It is concluded that competition between nitrate and $CO_2$reduction for reductants and ATP from photosynthesis may have important ecological consequences for the adaptation of plants to low or high light conditions. Additionally, the patterns of ionic changes due to increased light intensities were essentially the same in all selected species, indicating similar characteristics of heir mineral ion and organic acid metabolism as well as in field-grown Carex species.

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Influence of N Forms to the Ionic Balance of Tobacco Plants (담배식물의 이온균형(均衡)에 미치는 형태별(形態別) 질소(窒素)의 영향)

  • Lee, Yun-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.2
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    • pp.139-145
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    • 1986
  • In order to study the influence of nitrate reduction to ionic balance in tissue of tobacco plant, differneces in amounts of those cations and anions were determined and these balances were compared with contents of organic acids and activities of nitrate reductase, while they were fertilized with different nitrogen sources ($NO_3-N$, $NH_4-N$, $NO_3+NH_4-N$) in water culture. The results of studies are summerized as follows; 1. Total uptake of inorganic cations was the highest in nitrate-fed plants, whereas that of inorganic anions showed the highest level in the plants grown with the mixture ($NO_3+NH_4$). The amounts of inorganic cations and anions were comparable in two treatments containing $NH_4-N$, but in plants treated with nitrate only had much higher level of inorganic cations than others. 2. Deficiency in the amount of inorganic anions in nitrate-fed plants was balanced with organic acids, dominantly with malic acid among them. But another two $NH_4-N$ fed plant sustained equilibrium between inorganic cations and anions. 3. Reduction of nitrate was raised in tissues of nitrate-fed plants. By the results of nitrate reduction, cations maintained equilibrium with nitrate ion were let loose. The replacement of inorganic anions with organic anions could be a compensation process for the loss of uptaken nitrate ions which must be reduced to be incorporated into organic N compounds.

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Cultivation Characteristics and Optimal Conditions for Mycelial Growth of Volvariella bombycina (흰비단털버섯(Volvariella bombycina)의 배양적 특성 및 균사 배양 조건 설정)

  • Gyeong Jin Min;Hye Sung Park;Tai Moon Ha;Eun Ji Lee
    • Journal of Mushroom
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    • v.21 no.1
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    • pp.15-21
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    • 2023
  • Volvariella bombycinais an edible mushroom commercially cultivated in Korea and other countries. In this study, the culture characteristics and optimal growth conditions of milky mushroom strains were determined. The growth temperature and pH range of V. bombycinawas extensively investigated between 15 and 35℃ and pH 3-11. For efficient cultivation, 20 types of nutrient sources were selected, specifically, 21 carbon sources, 6 organic nitrogen sources, 7 inorganic nitrogen sources, 13 amino acids, 9 organic acids, and 13 inorganic salts. The impact of each of the selected nutrition sources and their concentration on growth was investigated. The optimum temperature and pH were determined to be 30℃ and pH 8.0, respectively. The optimum concentration of medium elements required for mycelial growth of V. bombycinawas determined to be as follows: carbon source, 0.7% Soluble starch; organic nitrogen source, 0.7% Soytone; inorganic nitrogen source, 1.0% (NH4)2C4H4O6; amino acid, 0.1% cysteine; organic acid, 0.07% lactic acid; and inorganic salt, 0.07 mM CaCl2.

Formation, Breakage and Reformation of Humic Flocs by Inorganic and Organic Coagulants

  • Kam, Sang-Kyu;Lee, Min-Gyu;Kang, Kyung-Ho;Xu, Mei-Lan
    • Journal of Environmental Science International
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    • v.17 no.3
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    • pp.275-285
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    • 2008
  • The floc formation, breakage and reformation of humic acid by inorganic (alum and PAC) and organic coagulants (cationic polyelectrolytes) at several conditions (pH, ionic strength and floc breakage time) were examined and compared among the coagulants at different conditions using a continuous optical monitoring method, with controlled mixing and stirring conditions. For alum, the shapes of formation, breakage and reformation curves at different pH (5 and 7) were different, but the shapes and the sizes of initial floc and reformed floc were nearly the same in the absence and presence of electrolytes at pH 7. For PAC, similar shapes of the curves were obtained at different pH and ionic strength, but the sizes were different, except for those of reformed flocs at different pH. However, for these coagulants, reformed flocs after floc breakage, occurred irreversibly for all the conditions used in this study. For organic coagulants, the time to attain the initial plateau floc size, the extent of floc strength at high shear rate and reversibility of reformed floes were different, depending floc formation mechanism. Especially, for the cationic polyelectrolyte forming humic flocs by charge neutralization or electrostatic patch effect mechanism, reformed flocs occurred reversibly, regardless of pH and floc breakage time, but occurred irreversibly in the presence of electrolytes.

Synthesis of Organic-Inorganic Nanohybrids Using Epoxy-Functionalized Alkoxysilane and Their Properties (Epoxy-Functionalized Alkoxysilane을 이용한 Organic-Inorganic Nanohybrids합성과 물성)

  • Kim, Bo-Young;Kim, Juyoung
    • Journal of Adhesion and Interface
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    • v.15 no.2
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    • pp.69-76
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    • 2014
  • Two kinds of epoxy-functionalized alkoxysilane (EAS) compounds (EAS-MS and EAS-ES) were successfully synthesized through the reaction between epoxy resin (YD-128) and aminopropyl trimethoxysilane (APTMS) or aminopropyl triethoxysilane (APTES). By the hydrolysis-polycondensation reaction of EAS compounds with 3-Glycidyloxypropyl trimethoxysilane (GPTMS) and Tetraethyl orthosilicate (TEOS), silica/epoxy nanohybrids could be prepared at various compositions of EAS to GPTMS/TEOS. Prepared nanohybrids were yellow transparent and miscible with various organic solvents. By the reaction silica/epoxy nanohybrids with curing agents (TETA or acrylic acid), cured hybrids films could be obtained. These cured films showed higher thermal stability and mechanical property compared to cured neat epoxy resin. TEM and AFM images showed formation of nano-sized silica nanoparticles within cured hybrid films.

Compositions of Fatty Acids, Inorganic Components and Volatile Organic Acids in Korean Valerian Roots (한국산 쥐오줌풀의 지방산, 무기성분 및 유기산 조성)

  • Choi, Young-Hyun;Cho, Chang-Hwan
    • Korean Journal of Medicinal Crop Science
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    • v.2 no.2
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    • pp.162-167
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    • 1994
  • This study was carried out to investigate the compositions of fatty acids, inorganic components and volatile organic acids from Korean valerian roots, Valeriana fauriei var. dasycarpa Hara and Valeriana officinalis var. latifolia Miq. The contents of total lipids ranged from 3.7 % to 4.5% and the major fatty acids were linoleic, linolenic and palmitic acid. Ash contents ranged from 4.3% to 6.3%. and the contents of Na, Fe, Zn and Cu showed some quantitative differences depending upon grown region or species. Fourty components were identified from acidic fraction of dichloromethane extract of V. fauriei var. dasycarpa Hara, of which the major components were 3-methyl butanoic, dimethoxy-2-propenoic. 3, 4-dimethoxy benzoic and 3-methyl pentanoic acid.

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Preparation and Characterization of Proton Conductive Phosphosilicate Membranes Based on Inorganic-Organic Hybrid Materials

  • Huang, Sheng-Jian;Lee, Hoi-Kwan;Kang, Won-Ho
    • Bulletin of the Korean Chemical Society
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    • v.26 no.2
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    • pp.241-247
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    • 2005
  • A series of proton conductive inorganic-organic hybrid membranes doped with phosphoric acid ($H_3PO_4$) and/or triethylphosphate (PO(OEt)$_3$) have been prepared by sol-gel process with 3-glycidoxypropyltrimethoxysilane (GPTMS), 3-aminopropyltriethoxysilane (APTES) and tetraethoxysilane (TEOS) as precursors. High proton conductivity of 3.0 ${\times}$ $10^{-3}$ S/cm with composition of 50TEOS-30GPTMS-20APTES-50$H_3PO_4$ was obtained at 120 ${^{\circ}C}$ under 50% relative humidity. Thermal stability of membrane was significantly enhanced by the presence of SiO$_2$ framework up to 250 ${^{\circ}C}$. XRD revealed that the gels are amorphous. IR spectra showed a good complexation of $H_3PO_4$ in the matrix. The conductivity under 75% relative humidity was significantly improved by addition of APTES due to the increase in concentration of defected site in hybrid matrix. The effect of PO(OEt)$_3$, humidifying time, and heat-treatment were also investigated. PO(OEt)$_3$ had no improvement on conductivity and conductivity increased with humidifying time, however, decreased with heating temperature.