• Title/Summary/Keyword: injection efficiency

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Study on the Electron Injection of Newly Synthesized Organic Sensitizer in Dye-Sensitized Solar Cell

  • Gang, Tae-Yeon;Lee, Do-Gwon;Go, Min-Jae;Kim, Gyeong-Gon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.310-310
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    • 2010
  • Electronic and photovoltaic characteristics of two sensitizers (TA-BTD-CA and TA-BTD-St-CA), composed of a different $\pi$-conjugation in the linker group, have been investigated by theoretical and experimental methods. The electronic structure, transition dipole moment and oscillator strengths of two sensitizers have been scrutinized by using density functional theory (DFT) and time-dependent DFT (TD-DFT) method. The LUMO level and the oscillator strength of TA-BTD-St-CA was higher than that of TA-BTD-CA, which may facilitate the electron injection process as well as increase the absorption coefficient. The relative efficiencies of the electron injection from the excited sensitizer to nanocrystalline TiO2 and SnO2 films have also been investigated by nanosecond transient absorption spectroscopy. The relative electron injection efficiency of TA-BTD-St-CA exhibited similar injection efficiency for two different semiconductors. However, in the case of TA-BTD-CA sensitizer, electron injection into SnO2 was approximately three times larger than that into TiO2. This enhancement of electron injection of TA-BTD-CA for the SnO2 is due to the increment of the driving force caused by positive shift of conduction band of semiconductor, which was also confirmed from the investigation for the photovoltaic characteristics according to the electrolyte additive, such as LiI additive.

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Removal Characteristics of Nitrogen and Phosphorus in swine wastewater by Using Acetic acid on the SBR Process (SBR에서 아세트산을 이용한 양돈폐수의 질소·인 제거 특성)

  • Huh, Mock;Kang, Jin-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.12 no.1
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    • pp.84-93
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    • 2004
  • This study was performed : 1) to find the suitable HRT(hydralic retention time), 2) to evaluate the effects of the ratio of mixing/aeration time and injection time of external carbon source, for the removal of organics, nitrogen and phosphorus in swine wastewater by SBR(sequencing batch reactor process), which is one of the biological treatment process. The result of this study were summarized as follows : (1) As the ratio of mixing/aeration time was higher, $NH_4{^+}-N$ removal efficiency was increased and it was increased with increasing injection time of external carbon source because nitrification was affected by denitrification microbes propagation when injection time of external carbon soruce was shorted. T-N removal efficiency was increased with increasing the ratio of mixing/aeration time and injection time of external carbon source. (2) The T-P removal efficiency showed a great difference in each operating condition, and it was increased with increasing the ratio of mixing/aeration time increased and when the injection time of external carbon source was shorted because denitrification was done with effect by denitrification microbes propagation. (3) The highest removal efficiency of organic and nitrogen were obtained by the operating condition of Run 4-1(the ratio of mixing/aeration time : 16.5/5.5, injection time of external carbon source : 15hours) and T-P were obtained by the operation condition of Run 4-2(the ratio of mixing/aeration time : 16.5/5.5, injection time of external carbon source : 3hours), and efficiency(effluent concentration)of $BOD_5$, $COD_{Mn}$, $COD_{Cr}$, T-N and T-P in the treated water was 96.1%, 87.7%, 90.6%, 86.6% and 84.5%, respectively.

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Simulation Injection Mass with Variable Injection Condition in GDI Engine using AMESim (AMESim을 이용한, GDI 엔진에서 연료의 분사조건 변화에 따른 분사량 변화 예측)

  • Shin, Suk Shin;Song, Jingeun;Park, Jongho
    • Journal of ILASS-Korea
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    • v.18 no.1
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    • pp.61-65
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    • 2013
  • In case of GDI engine, shape of injected fuel and injection mass are one of the most important factors for good fuel efficiency and power. But it should be too inefficient and difficult to acquire injection mass data by experiment because condition in engine vary with temperature, pressure, and so on. So, this paper suggests the AMESim (Advanced Modeling Environment for Simulation of Engineering Systems) as simulation program to calculate injection mass. For both simulation and experiment, n-heptane is used as fuel. In AMESim, I modeled the GDI injector and simulated several cases. In experiment, I acquired the injection mass using Bosch method to apply ambient pressure. The AMESim show reasonable result in comparison with experimental data especially at injection pressure 15 MPa. Other conditions are also in good accord with experimental data but error is a little bit large because the injection mass is so low.

An Study on Spray and Combustion Characteristics of Direct Injection LPG under Low Pressure Injection Condition (저압 분사조건에 따른 직접분사 LPG의 분무 및 연소특성 연구)

  • Hwang, Seong-Ill;Chung, Sung-Sik;Yeom, Jeong-Kuk;Lee, Jin-Hyun
    • Journal of the Korean Institute of Gas
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    • v.20 no.1
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    • pp.52-61
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    • 2016
  • Liquefied petroleum gas is regarded as a promising alternative fuel as it is eco-friendly, has good energy efficiency and output performance, practically and has high cost competitiveness over competing fuels. In spark-ignition engine, direct injection technology improves engine volumetric efficiency apparently and operates engine using the stratified charge that has relatively higher combustion efficiency. This study designed a combustion chamber equipped with visualization system by applying gasoline direct injection engine principle. In doing so, the study recorded and analyzed ignition probability and flame propagation process of spark-ignited direct injection LPG in a digital way. The result can contribute as a basic resource widespread for spark-ignited direct injection LPG engine design and optimization extensively.

Effective structure of electron injection from ITO bottom cathode for inverted OLED

  • Chu, Ta-Ya;Chen, Szu-Yi;Chen, Jenn-Fang;Chen, Chin H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.972-974
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    • 2005
  • For display drivers employ typically a-Si n-channel field effect transistors, they require an inverted OLED structure with a cathode as the bottom contact. ITO is regarded as the bottom cathode and can be applied to large size AM-OLED and transparent inverted OLEDs. We report the effective structure to improve the efficiency of electron injection from ITO cathode to $Alq_3$. We report the effective structure to improve the efficiency of electron injection from ITO cathode to Alq3 and studied the current density-voltage characteristics of trilayer ($Alq_3-LiF-Al$), LiF and Mg inserted between ITO and $Alq_3$, respectively. We discovered that 1 nm Mg afforded the highest efficiency.

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The Effect of Scavenging pressure on Performance Characteristics in Two-Stroke Diesel Engine (2행정 디젤기관의 소기압력이 성능특성에 미치는 영향)

  • Kim, Gi-Bok
    • Journal of the Korean Society of Industry Convergence
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    • v.21 no.2
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    • pp.45-51
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    • 2018
  • Compression ignition diesel engine can reduce carbon emission than gasoline engine in case of high efficiency, output and durability. So, compression ignition diesel engine is used in various fields such as automobiles, industries and so on. Due to reducing of emission exhaust by Developing of injection and combustion type of diesel engine, emission of pollution substance is developed compared the past. Moreover, its efficiency and reduce of carbon emission is better than gasoline engine and it is used in power source of industries, transports and others because of its high efficiency and durability nowadays. In this study, we experiment by making and designing of compression ignition diesel engine witch has air-cooling, 2 cylinder and 2 strokes.

The Fundamental Study on Liquid Phase LPG Injection System for Heavy-Duty Engine (II) (대형엔진용 액상분사식 LPG 연료공급방식에 대한 기초연구 (2))

  • 김창업;오승묵;강건용
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.6
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    • pp.1-7
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    • 2001
  • Recently, several LPG engines for heavy-duty vehicles have been developed, which can replace some diesel engines that are one of a main source for air pollution in urban area. As a preliminary study on the liquid phase LPG injection (hereafter LPLI) system applicable to a heavy duty LPG engine, the engine output and combustion performance were investigated with various combustion chambers and fuel compositions using a single cylinder engine equipped. Experimental results revealed that ellipse, double ellipse and nebula type combustion chamber made a more advantage in breaking swirl flow into small turbulence scale than bathtub type. Especially, performance of nebula type showed most highest efficiency and engine output under lean mixture conditions. An investigation fur various LPG fuel compositions was also carried out, and revealed that the case with 40% propane and 60% butane shows the lowest efficiency at stoichiometry, however, as the mixture became leaner its efficiency increased and became even higher for 100% propane case.

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Effect of Cations on the open-Circuit Photovoltage and the Charge-Injection Efficiency of Dye-Sensitized Nanocrys-talline Rutile $TiO_2$ Films

  • Park, Nam Gyu;Jang, Sun Ho;Kim, Gang Jin
    • Bulletin of the Korean Chemical Society
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    • v.21 no.10
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    • pp.1047-1048
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    • 2000
  • Dye-sensitized nanocrystalline rutile $TiO_2$ solar cells were prepared, and the influence of Li+ and 1,2-dimethyl-3-hexyl imidazolium ions in the electrolyte on the photovoltaic properties was compared. The electrolyte con-taining Li+ ions produced a lower open-circuit photovoltage than the electrolyte with 1,2-dimethyl-3-hexyl im-idazolium ions, suggesting that the adsorption of Li+ ions to the rutile $TiO_2$ surface causes a shift in the band edges toward more positive potentials. At the same time, both the short-circuit photocurrent and the maximum value of the incident-photon-current conversion efficiency (IPCE) of the electrolyte containing Li+ ions were relatively higher. Data analysis suggests that presence of adsorbed Li+ ions improves via the phenomenon of band-edge movement the charge-injection efficiency by altering both the energy and number of excited state levels of the dye that participate in electron injection.

Analysis on Performance and Emission with Different Diesel Injection Methods in a Dual-Fuel Engine (디젤 분사방식에 따른 이종연료 엔진의 성능 및 배기 분석)

  • Park, Hyunwook;Lee, Junsun;Oh, Seungmook;Kim, Changup;Lee, Yonggyu;Jang, Hyungjoon
    • Journal of ILASS-Korea
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    • v.27 no.2
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    • pp.101-108
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    • 2022
  • Performance and emissions with different diesel injection methods were analyzed in a natural gas-diesel, dual-fuel engine under low-load conditions. Natural gas was supplied to intake port during the intake stoke to form a natural gas-air premixed mixture for all methods. Diesel was injected directly into the cylinder during the compression stroke in three ways: early injections, late injections, and a combination of early and late injections. The early injections had the highest thermal efficiency among the three methods owing to its highest combustion efficiency. The wide dispersion of diesel before the combustion initiation also allowed superior emissions characteristics.

Effectiveness of elimination inflowing algae in water treatment plant using natural algae remover (천연 조류 제거제를 이용한 정수장 유입 조류 제거 효율)

  • Jung, Hoyoung;Kim, Younghee
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.4
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    • pp.311-319
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    • 2019
  • The purpose of this study was to analyze water treatment characteristics, including the efficiency of removing algae from water purification plants, by installing a demonstration facility for decontamination of algae, including natural algae remover injection equipment, in the water purification plant. Jar-test showed that the optimum injection of natural decontaminant was 20 mg/L. Of the water contaminant treatment efficiency of the intake and water purification plants, Chl-a averaged 74.0% elimination efficiency from $5.0mg/m^3$ to $1.3mg/m^3$ and the maximum treatment efficiency was 91.5% removal efficiency when the inflow concentration of Chl-a was $11.8mg/m^3$. In addition, 51.2% and 47.1% of the taste and odor indicator items, geosmin and 2-MIB, resulted from the overgrowth and decaying of algae, respectively, to identify toxic substances and odor reduction effects. In addition, elimination efficiencies of SS and Turbidity materials were higher than 70.0%. In the injection of natural algae remover, no effects such as sudden changes in water quality due to secondary reactions were found, and appropriate levels were maintained under water treatment conditions.