• 제목/요약/키워드: injection efficiency

검색결과 1,289건 처리시간 0.03초

Study on the Electron Injection of Newly Synthesized Organic Sensitizer in Dye-Sensitized Solar Cell

  • 강태연;이도권;고민재;김경곤
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.310-310
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    • 2010
  • Electronic and photovoltaic characteristics of two sensitizers (TA-BTD-CA and TA-BTD-St-CA), composed of a different $\pi$-conjugation in the linker group, have been investigated by theoretical and experimental methods. The electronic structure, transition dipole moment and oscillator strengths of two sensitizers have been scrutinized by using density functional theory (DFT) and time-dependent DFT (TD-DFT) method. The LUMO level and the oscillator strength of TA-BTD-St-CA was higher than that of TA-BTD-CA, which may facilitate the electron injection process as well as increase the absorption coefficient. The relative efficiencies of the electron injection from the excited sensitizer to nanocrystalline TiO2 and SnO2 films have also been investigated by nanosecond transient absorption spectroscopy. The relative electron injection efficiency of TA-BTD-St-CA exhibited similar injection efficiency for two different semiconductors. However, in the case of TA-BTD-CA sensitizer, electron injection into SnO2 was approximately three times larger than that into TiO2. This enhancement of electron injection of TA-BTD-CA for the SnO2 is due to the increment of the driving force caused by positive shift of conduction band of semiconductor, which was also confirmed from the investigation for the photovoltaic characteristics according to the electrolyte additive, such as LiI additive.

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SBR에서 아세트산을 이용한 양돈폐수의 질소·인 제거 특성 (Removal Characteristics of Nitrogen and Phosphorus in swine wastewater by Using Acetic acid on the SBR Process)

  • 허목;강진영
    • 유기물자원화
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    • 제12권1호
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    • pp.84-93
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    • 2004
  • 본 연구는 생물학적 처리공정의 하나인 SBR을 이용하여, 양돈폐수중의 유기물과 질소, 인의 동시 제거를 목적으로 적정의 수리학적 체류시간(HRT)과 반응기간 중 교반/폭기 시간비(M/A) 및 적정의 교반/폭기 시간비에서의 외부탄소원의 주입기간(Injection Time)에 따른 변화에 따른 실험 결과로부터 다음과 같은 결론을 얻었다. (1) $NH_4{^+}-N$의 제거효율은 M/A가 0.0/22.0일 때(Run 1) 가장 효율이 좋았으며, 외부탄 소원을 주입했을 경우 탈질균의 증식으로 인해서 질산화가 잘 이루어지지 않기 때문에 주입시간이 길어질수록 증가하였다. T-N의 제거효율은 M/A가 증가할수록, 외부탄소원 주입시간이 길어질수록 증가하였다. (2) T-P의 제거효율은 운전조건에 따라 큰 차이를 보이고 있으며, M/A가 증가할수록 제거효율은 증가하였으며, 외부탄소원의 주입기간을 두고 보았을때, 주입기간을 짧게 할 경우 탈질균의 증식으로 인해서 탈질이 더 효율적으로 이루어지기 때문에 그 제거효율은 증가하였다. (3) 총 반응시간 22시간 중 M/A 16.5/5.5, 무산소 기간의 16.5시간 중 15시간동안 외부탄소원을 주입했을 경우(Run 4-1)의 운전조건에서 유기물 및 질소 제거에 가장 효율적이었다. 각각의 효율을 살펴보면, $COD_{Cr}$, $COD_{Mn}$ 그리고 $BOD_5$인 경우, 각각 90.6%, 87.7% 그리고 96.1%이고, T-N의 경우 86.6%, T-P인 경우는 84.5%로 나타났다.

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AMESim을 이용한, GDI 엔진에서 연료의 분사조건 변화에 따른 분사량 변화 예측 (Simulation Injection Mass with Variable Injection Condition in GDI Engine using AMESim)

  • 신석신;송진근;박종호
    • 한국분무공학회지
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    • 제18권1호
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    • pp.61-65
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    • 2013
  • In case of GDI engine, shape of injected fuel and injection mass are one of the most important factors for good fuel efficiency and power. But it should be too inefficient and difficult to acquire injection mass data by experiment because condition in engine vary with temperature, pressure, and so on. So, this paper suggests the AMESim (Advanced Modeling Environment for Simulation of Engineering Systems) as simulation program to calculate injection mass. For both simulation and experiment, n-heptane is used as fuel. In AMESim, I modeled the GDI injector and simulated several cases. In experiment, I acquired the injection mass using Bosch method to apply ambient pressure. The AMESim show reasonable result in comparison with experimental data especially at injection pressure 15 MPa. Other conditions are also in good accord with experimental data but error is a little bit large because the injection mass is so low.

저압 분사조건에 따른 직접분사 LPG의 분무 및 연소특성 연구 (An Study on Spray and Combustion Characteristics of Direct Injection LPG under Low Pressure Injection Condition)

  • 황성일;정성식;염정국;이진현
    • 한국가스학회지
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    • 제20권1호
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    • pp.52-61
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    • 2016
  • 액화석유가스는 환경 친화적이며 에너지 효율성과 출력성능이 뛰어나 실용성이 높고, 경쟁연료에 비해 가격 경쟁력이 우수하기 때문에 촉망받는 대체연료 중 하나로 간주된다. 스파크점화 엔진에서 직분식 기술은 엔진 체적효율을 눈에 띄게 증가시키며, 상대적으로 더 높은 연소효율이 가능한 성층급기를 이용해 엔진을 작동시킨다. 본 연구에서는 가솔린직접분사 엔진의 원리를 적용하여 가시화 시스템을 장착한 연소실을 설계하였다. 이를 통해 스파크점화직분식 LPG의 점화성과 화염전파 과정을 디지털 방식으로 기록하고 분석하였다. 이러한 연구의 결과는 스파크점화직분식 LPG 엔진의 설계 및 최적화를 위한 광범위한 기초 자료로서 기여하고자 한다.

Effective structure of electron injection from ITO bottom cathode for inverted OLED

  • Chu, Ta-Ya;Chen, Szu-Yi;Chen, Jenn-Fang;Chen, Chin H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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    • pp.972-974
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    • 2005
  • For display drivers employ typically a-Si n-channel field effect transistors, they require an inverted OLED structure with a cathode as the bottom contact. ITO is regarded as the bottom cathode and can be applied to large size AM-OLED and transparent inverted OLEDs. We report the effective structure to improve the efficiency of electron injection from ITO cathode to $Alq_3$. We report the effective structure to improve the efficiency of electron injection from ITO cathode to Alq3 and studied the current density-voltage characteristics of trilayer ($Alq_3-LiF-Al$), LiF and Mg inserted between ITO and $Alq_3$, respectively. We discovered that 1 nm Mg afforded the highest efficiency.

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2행정 디젤기관의 소기압력이 성능특성에 미치는 영향 (The Effect of Scavenging pressure on Performance Characteristics in Two-Stroke Diesel Engine)

  • 김기복
    • 한국산업융합학회 논문집
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    • 제21권2호
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    • pp.45-51
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    • 2018
  • Compression ignition diesel engine can reduce carbon emission than gasoline engine in case of high efficiency, output and durability. So, compression ignition diesel engine is used in various fields such as automobiles, industries and so on. Due to reducing of emission exhaust by Developing of injection and combustion type of diesel engine, emission of pollution substance is developed compared the past. Moreover, its efficiency and reduce of carbon emission is better than gasoline engine and it is used in power source of industries, transports and others because of its high efficiency and durability nowadays. In this study, we experiment by making and designing of compression ignition diesel engine witch has air-cooling, 2 cylinder and 2 strokes.

대형엔진용 액상분사식 LPG 연료공급방식에 대한 기초연구 (2) (The Fundamental Study on Liquid Phase LPG Injection System for Heavy-Duty Engine (II))

  • 김창업;오승묵;강건용
    • 한국자동차공학회논문집
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    • 제9권6호
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    • pp.1-7
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    • 2001
  • Recently, several LPG engines for heavy-duty vehicles have been developed, which can replace some diesel engines that are one of a main source for air pollution in urban area. As a preliminary study on the liquid phase LPG injection (hereafter LPLI) system applicable to a heavy duty LPG engine, the engine output and combustion performance were investigated with various combustion chambers and fuel compositions using a single cylinder engine equipped. Experimental results revealed that ellipse, double ellipse and nebula type combustion chamber made a more advantage in breaking swirl flow into small turbulence scale than bathtub type. Especially, performance of nebula type showed most highest efficiency and engine output under lean mixture conditions. An investigation fur various LPG fuel compositions was also carried out, and revealed that the case with 40% propane and 60% butane shows the lowest efficiency at stoichiometry, however, as the mixture became leaner its efficiency increased and became even higher for 100% propane case.

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Effect of Cations on the open-Circuit Photovoltage and the Charge-Injection Efficiency of Dye-Sensitized Nanocrys-talline Rutile $TiO_2$ Films

  • 박남규;장순호;김강진
    • Bulletin of the Korean Chemical Society
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    • 제21권10호
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    • pp.1047-1048
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    • 2000
  • Dye-sensitized nanocrystalline rutile $TiO_2$ solar cells were prepared, and the influence of Li+ and 1,2-dimethyl-3-hexyl imidazolium ions in the electrolyte on the photovoltaic properties was compared. The electrolyte con-taining Li+ ions produced a lower open-circuit photovoltage than the electrolyte with 1,2-dimethyl-3-hexyl im-idazolium ions, suggesting that the adsorption of Li+ ions to the rutile $TiO_2$ surface causes a shift in the band edges toward more positive potentials. At the same time, both the short-circuit photocurrent and the maximum value of the incident-photon-current conversion efficiency (IPCE) of the electrolyte containing Li+ ions were relatively higher. Data analysis suggests that presence of adsorbed Li+ ions improves via the phenomenon of band-edge movement the charge-injection efficiency by altering both the energy and number of excited state levels of the dye that participate in electron injection.

디젤 분사방식에 따른 이종연료 엔진의 성능 및 배기 분석 (Analysis on Performance and Emission with Different Diesel Injection Methods in a Dual-Fuel Engine)

  • 박현욱;이준순;오승묵;김창업;이용규;장형준
    • 한국분무공학회지
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    • 제27권2호
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    • pp.101-108
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    • 2022
  • Performance and emissions with different diesel injection methods were analyzed in a natural gas-diesel, dual-fuel engine under low-load conditions. Natural gas was supplied to intake port during the intake stoke to form a natural gas-air premixed mixture for all methods. Diesel was injected directly into the cylinder during the compression stroke in three ways: early injections, late injections, and a combination of early and late injections. The early injections had the highest thermal efficiency among the three methods owing to its highest combustion efficiency. The wide dispersion of diesel before the combustion initiation also allowed superior emissions characteristics.

천연 조류 제거제를 이용한 정수장 유입 조류 제거 효율 (Effectiveness of elimination inflowing algae in water treatment plant using natural algae remover)

  • 정호영;김영희
    • 상하수도학회지
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    • 제33권4호
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    • pp.311-319
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    • 2019
  • The purpose of this study was to analyze water treatment characteristics, including the efficiency of removing algae from water purification plants, by installing a demonstration facility for decontamination of algae, including natural algae remover injection equipment, in the water purification plant. Jar-test showed that the optimum injection of natural decontaminant was 20 mg/L. Of the water contaminant treatment efficiency of the intake and water purification plants, Chl-a averaged 74.0% elimination efficiency from $5.0mg/m^3$ to $1.3mg/m^3$ and the maximum treatment efficiency was 91.5% removal efficiency when the inflow concentration of Chl-a was $11.8mg/m^3$. In addition, 51.2% and 47.1% of the taste and odor indicator items, geosmin and 2-MIB, resulted from the overgrowth and decaying of algae, respectively, to identify toxic substances and odor reduction effects. In addition, elimination efficiencies of SS and Turbidity materials were higher than 70.0%. In the injection of natural algae remover, no effects such as sudden changes in water quality due to secondary reactions were found, and appropriate levels were maintained under water treatment conditions.