• Korean Journal of Fisheries and Aquatic Sciences
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• v.37 no.5
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• pp.359-365
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• 2004

To study the lipid adsorption characteristic of chitosans with different molecular weights and the degrees of deacetylation, in vitro test and near-infrared (NIR) spectroscopic analysis have been performed for the measurement of lipid adsorption characteristics of chitosan. The degrees of deacetylation in chitosans were $70{\%},\;85{\%}\;and\;92{\%}$ at different deacetylation times (1 hr, 2 hrs, 3 hrs), respectively. The molecular weight of each chitosan was controlled by enzymatic hydrolysis, and then the molecular weight of the chitosan was 4 kDa. The bulk density, water holding capacity and fat binding capacity of each chitosan powder were $96.2-504.0{\%},\;374.4-1217.9{\%},\;and\;307.0-659.3{\%}$, respectively. The higher molecular weight of chitosan was exhibited the lower bulk density and the higher water and fat binding capacities. Bindinf capacities of chitosan powders to bile salts, cholesterol and linoleic acid were $41.2-63.3{\%},\;40.8-67.4{\%},\;42.6-72.6{\%}$, respectively. In NIR spectrum of lipid adsorbed chitosan the occurrence static eletronical binding between chitosan and lipid was identified by NIR spectrum peak induced from combination of carboxylic group in lipid and amino group in chitosan. In conclusion, the higher degree of deacetylation and molecular weight of chitosan showed the higher lipid binding capacity and the lipid adsorption of chitosan were occurred by combination of carboxylic group in lipids and amino group in chitosan.

• Toxicological Research
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• v.17
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• pp.329-333
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• 2001

Apoptosis is the normal physiological process of cell death essential for the maintenance of homeostasis. The function of nicotinamide adenine dinucleotide (NAD) and adenine diphosphate (ADP) ribosylation (transfer of ADP-ribose to proteins) reactions in modifying apoptosis have recently been of great interest. Recently. CD38. a type 2 transmembrane glycoprotein expressed in hematopoietic and non hematopoietic cell lines. has been reported to possess NAD glycohydrolase activity (Han. 1999) and PC-1 and CD38 NADase regulates T cells by inhibition of phosphodiesterase/pyrophosphatase activity of PC-1 by its association with glycosaminoglycan (Hozada et al., 1999). Sindhuphak et al. (2000) has reported that cervical cancer cells can be differentiated from normal cells by using FTIR (Fourier-Transformed Infrared) technique. which has characterized shifts to be due to the phosphodiester bond in nucleic acid. protein amide I&II. carbohydrate and glycogen bands. Mechanisms how phosphodiester bond shift in cervical cancer cells as compared to control cells remain to be elucidated. Suramana et al. (2000) as well as Lohitnavy and Sinhaseni (1998) have studied methomyl and colchicine effects in rat splenocytes. Lactate Dehydroge-nase Isozymes 3 (LDH3) and LDH4 were observed to increase transiently and subsided in plasma of rats exposed to 6~8 mg/kg methomyl after 48 hours. Phosphodiester bond shift of nucleic acid. detected by FTIR. was also reported (Suramana et al., 2000). We report here, after analysis of bond shift patterns. a similar bond shifts detected by FTIR spectrum observed in human cervical cells and splenocytes of rats exposed orally to 2~8 mg/kg methomyl as well as rats exposed to colchicine 2~6 mg/kg orally.

• Journal of the Korean Society of Propulsion Engineers
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• v.19 no.4
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• pp.24-36
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• 2015

In the present study, numerical predictions of infrared spectrum of rocket plume with considering effect of particles based on approximation theories were performed by using a line-by-line radiation model with radiation databases. The high-resolution radiation databases were used to predict thermal emission spectra of gas molecules within the rocket plume regime. The particles were modeled as soot particles by using 1st term approximation of Mie theory and Rayleigh approximation. The reliability of modeled effect of soot particles using the two approximation theories was verified, and the spectral radiance of rocket plume was predicted based on the verification. The results were improved in the short wavelength range by considering the effect of soot particles.

• Korean Journal of Soil Science and Fertilizer
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• v.36 no.2
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• pp.92-103
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• 2003

Research and technological advances in the field of remote sensing have greatly enhanced the ability to detect and quantify physical and biological stresses that affect the productivity of agricultural crops. Reflectance in specific visible and near-infrared regions of the electromagnetic spectrum have proved useful in detection of nutrient deficiencies. Especially crop canopy sensors as a ground remote sensing measure the amount of light reflected from nearby surfaces such as leaf tissue or soil and is in contrast to aircraft or satellite platforms that generate photographs or various types of digital images. Multi-spectral vegetation indices derived from crop canopy reflectance in relatively wide wave band can be used to monitor the growth response of plants in relation to environmental factors. The normalized difference vegetation index (NDVI), where NDVI = (NIR-Red)/(NIR+Red), was originally proposed as a means of estimating green biomass. The basis of this relationship is the strong absorption (low reflectance) of red light by chlorophyll and low absorption (high reflectance and transmittance) in the near infrared (NIR) by green leaves. Thereafter many researchers have proposed the other indices for assessing crop vegetation due to confounding soil background effects in the measurement. The green normalized difference vegetation index (GNDVI), where the green band is substituted for the red band in the NDVI equation, was proved to be more useful for assessing canopy variation in green crop biomass related to nitrogen fertility in soils. Consequently ground remote sensing as a non destructive real-time assessment of nitrogen status in plant was thought to be useful tool for site specific crop nitrogen management providing both spatial and temporal information.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.57 no.3
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• pp.296-300
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• 2012

Discrimination of geographic origin of agricultural products is a important issue in Korea because the price difference between Korean domestic and imported cereals is a key among some reasons. NIRS (Near Infrared Reflectance Spectroscopy) has been applied to classify the geographical origin of soybeans. Total 135 samples (Korean domestic 92 and foreign 43) were used to obtain calibration equation through 400~2,500 nm wavelength. The math treatment with 1st derivative and 4 nm gap and the modified partial least squares(MPLS)regression was outstanding for calibration equation. The standard error of calibration and determination coefficient in calibration set(n=115) was 6.65 and 0.98, respectively. And it showed that the extra 20 samples for validation equation were identified their authentication correctly. This study describes that the application of NIRS would be possible for discrimination of geographical origin between Korean domestic and imported soybeans.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.2
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• pp.141.1-141.1
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• 2012

CIBER (Cosmic Infrared Background ExpeRiment) is a sounding-rocket borne experiment which is designed to find the evidence of the First stars (Pop.III stars) in the universe. They are expected to be formed between the recombination era at z ~ 1100 and the most distant quasar (z ~ 8). They have never been directly detected due to its faintness so far, but can be observed as a background radiation at around $1{\mu}m$ which is called the Cosmic Near-Infrared Background (CNB). The CIBER is successfully launched on July 10, 2010 at White Sands Missile Range, New Mexico, USA. It consists of three kinds of instruments. One of them is a LRS (Low Resolution Spectrometer) which is a refractive telescope of 5.5 cm aperture with spectral resolution of 20 ~ 30 and wavelength coverage of 0.7 to $2.0{\mu}m$ to measure the spectrum of the CNB. Since LRS detects not only CNB but also stellar components, we can study their spectral features with the broad band advantage especially at around $1{\mu}m$ which is difficult at ground observations because of the atmospheric absorption by water vapor. I identified around 300 stars from observed six fields. If we can classify their spectral types with SED fitting, we can study their physical conditions of the stellar atmosphere as well as making a stellar catalogue of continuous stellar spectrum.

• Bulletin of the Korean Chemical Society
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• v.13 no.2
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• pp.158-162
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• 1992

Hydrocarbon solution of $(PPh_3)_2(CO)MOSO_2CF_3(M=Rh$, Ir)reacts rapidly with Pyrazine or 4,4'-bipyridyl to yield dinuclear metal complexes $[(PPh_3)_3(CO)M({\mu}-pyrazine)M(CO)(PPh_3)_2](SO_3CF_3)_2$ (I: M= RhH; III: M=Ir) or [$(PPh_3)_2$(CO)M(${\mu}$-44'-bipyridyl)M(CO)$(PPh_3)_2](SO_3CF_3)_2$, (II: M=Rh; IV: M=Ir), respectively. Compounds, I, II, III, and IV were characterized by $^1H-NMR$, $^{13}C-NMR$, $^{31}P-NMR$, and infrared spectrum. Ethanol solution of $(PPh_3)_2(CO)MOSO_2CF_3$ (M=Rh, Ir) also reacts with $(TBA)_2$M'$(CN)_4$ (M'=Pd, Pt) to yield trinuclear metal complexes [$(PPh_3)_2$(CO)dM-NCM'$(CN)_2$CN-M(CO)$(PPh_3)_2]$ (V : M=Rh, M'=Pd; VI : M=Rh, M'=Pt; VII: M=Ir, M'=Pd; VIII: M=Ir, M'=Pt). The trinuclear metal complexes V, VI, VII, and VIII are bridged by the cyanide groups. The infrared spectrum of V, VI, VII, and VIII supports the presence of the bridged cyanide and terminal cyanide group.

• Journal of the Korean Society for Nondestructive Testing
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• v.28 no.2
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• pp.119-124
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• 2008

In recent years, gradually increasing interest has been directed to the use of terahertz technology in nondestructive testing and non-invasive measurements, and terahertz time domain spectroscopy (THz-TDS) has become a key technology in such applications. This paper deals with the terahertz pulse generation from cadmium telluride via optical rectification process of femto-second infrared laser pulses. The measured terahertz spectrum is compared with the result of model calculation based on space-time domain nonlinear Maxwell equations for coherent frequency mixing process. The propagation process of terahertz and infra-red pulses in the material as well as the surface interference and free space diffraction effects are also considered. The experimental results are in good agreements with the calculated spectrum.

• The Journal of The Korea Institute of Intelligent Transport Systems
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• v.7 no.2
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• pp.13-25
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• 2008

In this paper, we propose the Location Awareness System adjusting Ranging Technology for CSS(Chirp Spread Spectrum) which is adopted on 2.45GHz standard in IEEE 802.15.4a and TOA(Time-of-Arrival) algorithm. The conventional methods have adopted RSSI, ultrasonic waves and infrared rays in Zigbee. RSSI measures strength indication of received signal and recognizes the position of nodes in RF boundary. However, this technology has the following problems; lots of error by the change of the channel environment and much power consumption. In this paper, adopting chirp pulse on 2.45GHz standard in IEEE 802.15.4a and SDS-TWR(Symmetrical Double Side-Two Way Ranging) method using the characteristic of Spread Spectrum, a new Location Awareness System is suggested. The distance and the coordinate are measured within ${\pm}\;5cm$ by TOA(Time of Arrival) algorithm and proposed algorithm and the data in error rate is decreased less than 1%. Through these results, the algorithm suggested in this paper is verified for its performance in a computer simulation.

• Korean Journal of Soil Science and Fertilizer
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• v.20 no.4
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• pp.341-349
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• 1987

Fulvic acids extracted from seven plant materials were tested. The IR spectra and the data obtained from chemical analyses in terms of oxygen-containing functional groups complemented one another. Selected samples covered straws of grain crops (rice, barley, wheat and rye), hay of wild grass, and leaves of trees (deciduous and coniferous). 1. No significant variation in IR spectra of fulvic acids was observed among samples taken from different plant residues and at different stages of humification. 2. Oxygen-containing functional goups, such as carboxyls, phenolics, alcoholics, carbonyls, and quinones were identified on IR spectra and confirmed by chemical analyses. 3. The acidity of fulvic acids was directly related with the content of carboxyl groups. 4. Alcoholic hydroxyl groups predominated over phenolic hydroxyls. 5. The major part of fulvic acid structure appeared to be strongly aliphatic in many respects of chemical characteristics.