• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2012년도 춘계학술발표대회
• /
• pp.91.2-91.2
• /
• 2012

The TiB2-reinforced iron matrix nanocomposite (Fe-TiB2) was in-situ fabricated from titanium hydride (TiH2) and iron boride (FeB) powders by a simple and cost-effective process that combines the mechanical activation (MA) and a subsequent heat treatment (HT). Effect of milling factors and synthesized temperatures on the formation of the nanocomposite were presented and discussed. A differential thermal analyser (DSC-TG) was employed for examination of thermal behavior of MAed powders. Phases of the nanocomposite were confirmed by X-ray diffraction analysis (XRD). The morphologies and microstructure of nanocomposite were investigated by field emission-scanning electron microscopy (FE-SEM) and energy-dispersive X-ray spectroscopy (EDS). Phase composition and distribution were analyzed by electron probe X-ray microanalysis (EPMA). Results showed that TiB2 particles formed in nanoscale were uniformly distributed in alloyed Fe matrix.

• 한국진공학회지
• /
• 제19권1호
• /
• pp.14-21
• /
• 2010

Ge은 Si에 비하여 높은 이동도를 갖기 때문에 차세대 고속 metal oxide semiconductor field effect transistors (MOSFETs) 소자를 위한 channel 물질로서 각광받고 있다. 그러나 화학적으로 안정한 게이트 산화막의 부재는 MOS 소자에 Ge channel의 사용에 주요한 장애가 되어왔다. 특히, Ge 기판 위에 고품질의 계면 특성을 갖는 게이트 절연막의 제조는 필수 요구사항이다. 본 연구에서, $HfO_xN_y$ 박막은 Ge 기판 위에 플라즈마 원자층 증착법(plasma-enhanced atomic layer deposition, PEALD)을 이용하여 증착되었다. 플라즈마 원자층 증착공정 동안에 질소는 질소, 산소 혼합 플라즈마를 이용한 in situ 질화법에 의하여 첨가되었다. 산소 플라즈마에 대한 질소 플라즈마의 첨가로 성분비를 조절함으로써 전기적 특성과 계면 성질을 향상시키는데 초점을 맞추어서 연구를 진행하였다. 질소 산소의 비가 1：1이었을 때, EOT의 값의 10% 감소를 갖는 고품질의 소자특성을 보여주었다. X-ray photoemission spectroscopy (XPS)와 high resolution transmission electron microscopy (HR-TEM)를 사용하여 박막의 화학적 결합 구조와 미세구조를 분석하였다.

• Advances in nano research
• /
• 제14권4호
• /
• pp.355-362
• /
• 2023

Physical exercise, especially intense exercise and high intensity interval training (HIIT) by trampoline, can lead to muscle injuries. These effects can be reduced with intelligent products made of nanocomposite materials. Most of these nanocomposites are polymers reinforced with silicon dioxide, alumina, and titanium dioxide nanoparticles. This study presents a polymer nanocomposite reinforced with silica. As a result of the rapid reaction between tetraethyl orthosilicate and ammonia in the presence of citric acid and other agents, silica nanostructures were synthesized. By substituting bis (4-amino phenoxy) phenyl-triptycene in N, N-dimethylformamide with potassium carbonate, followed by catalytic reduction with hydrazine and Pd/C, the diamine monomer bis (4-amino phenoxy) phenyl-triptycene is prepared. We synthesized a new polyaromatic (imide) with triptycene unit by sol-gel method from aromatic diamines and dianhydride using pyridine as a condensation reagent in NMP. PI readily dissolves in solvents and forms robust and tough polymer films in situ. The FTIR and NMR techniques were used to determine the effects of SiO₂ on the sol-gel process and the structure of the synthesized nanocomposites. By using a simultaneous thermal analysis (DTA-TG) method, the appropriate thermal operation temperature was also determined. Through SEM analysis, the structure, shape, size, and specific surface area of pores were determined. Analysis of XRD results is used to determine how SiO₂ affects the crystallization of phases and the activation energy of crystallization.

• 자원환경지질
• /
• 제45권2호
• /
• pp.79-88
• /
• 2012

최근 개발된 상용 X-선원들은 기존 선원들에 비하여 비약적으로 증가된 휘도와 집속율을 보임으로써 다양한 형태의 연구실 규모의 분말회절 분석을 가능하게 하고 있다. 더욱이, 개선된 소프트웨어 및 시료환경 장치와 더불어 2차원 검출기의 성능향상은 다양한 온도, 압력하에서의 상전이 현상 및 이온교환 반응과 같은 새로운 형태의 실시간 및 시간분해 회절실험을 가능하게 하고 있다. 본 논문에서는 (1) 나트로라이트의 이온교환 특성에 관한 실시간 측정, (2) 이온교환된 나트로라이트의 탈수 및 열팽창 특성에 관한 실시간 측정, (3) 이온교환된 나트로라이트의 정수압(靜水壓) 하에서의 상전이 현상의 관찰 등의 내용을 소개하고자 한다. 측정된 회절자료의 양과 품질은 각 반응의 진행경로를 확인할 수 있게 하고 선택된 자료의 리트벨트 분석을 통해 구조해석까지 가능케 한다. 이와 같은 형태의 개별 연구실 기반 실시간 회절분석 연구는 추후 연관되어 수행될 방사광가속기를 이용한 보다 특화된 실험에 대한 사전 예측성을 더욱 증가시킬 것으로 사료된다.

• KIEAE Journal
• /
• 제17권4호
• /
• pp.41-48
• /
• 2017

Purpose : Currently, 25% of the domestic energy consumption structure is used as building energy, and more than 18% of this energy is consumed in the residential. Accordingly, various efforts and policies that can save energy of the building is being performed. The various researchers are conducting research to diagnose the thermal performance of existing buildings. This study is to apply in the field of precision thermal insulation performance diagnostic method for thermal performance analysis of existing detached house in Seoul, Gangreung, Gyeongju, Pohang. And this paper is analyzed quantitatively measure the existing detached house energy performance. Method: Research methodology analyzed the thermal performance over the Heat Flow Meter method by applying the measurement process and method by applying the criteria of ISO 9869-1 & ASTR method. In this study, the surface heat transfer coefficient was calibrated by applying indoor surface heat transfer resistance with reference to ISO 6946 standard. The measurement error rate between the HFM diagnosis method and the ASTR diagnosis method was reduced and the measurement reliability was obtained through measurement method error verification. Result : As a result of the study, the thermal performance vulnerable parts of the building were quantitatively analyzed, and presented for methods which can be improved capable of efficient energy use buildings.

• 터널과지하공간
• /
• 제23권5호
• /
• pp.372-382
• /
• 2013

고준위폐기물처분장에 대한 열-수리-역학적 거동 모델링은 처분장의 성능 및 안전성 평가를 위해서 선행되어야 할 중요한 연구과제이다. 본 연구에서는 $\ddot{A}$sp$\ddot{o}$ 원형처분장의 열적 거동을 해석하고, 현장 실험데이터와의 비교를 통해 모델 계산결과의 타당성을 검증하였다. 모델 시뮬레이션에서는 처분공과 처분터널 및 그 주변 암반에 대한 온도분포를 분석하였다. 현장 실험데이터와의 비교는 처분공 DH-6를 대상으로 수행하였다. 그 결과 모델 계산치는 측정위치에 따라 실험치 보다 약 2-$5^{\circ}C$ 정도 높은 온도값을 보였으나, 온도변이 곡선은 비슷한 패턴을 보여 주었다. 실험치와 모델 계산치의 이러한 차이는 모델에 의한 열적거동 해석에서 암반을 제외한 완충재, 벤토나이트 펠렛, 뒷채움재 내의 수리학적 및 역학적 거동을 고려하지 않았기 때문으로 판단되었다.

• 방사성폐기물학회지
• /
• 제10권4호
• /
• pp.281-294
• /
• 2012

현재까지 개발된 고준위폐기물 심지층처분장의 열-수리-역학적 복합거동 해석을 위한 전산 코드의 현황을 조사하고, 문헌에 보고된 각 코드에 의한 계산치와 현장실험 측정치의 비교 결과를 이용하여, 기존 전산 코드들의 신뢰도를 분석하였다. 개발된 전산코드들은 완충재가 없는 처분장에서는 붕괴열에 따른 암반의 열-수리-역학적 거동을 비교적 잘 모사하였으나, 포화 경암층에 위치한 완충재가 존재하는 처분장의 공학적방벽시스템 내에서 일어나는 열-수리-역학적 복합거동의 예측은 만족스럽지 못하였다. 현재 제안된 열-수리-역학적 복합거동 해석모델을 고준위폐기물 처분장 공학적방벽시스템의 거동 해석에 적용하기 위해서는 완충재 내의 수분함량 및 전 압력 분포를 보다 정교하게 모사할 수 있도록 수학적 모델의 개선이 필요하다.

• 농업과학연구
• /
• 제37권1호
• /
• pp.81-86
• /
• 2010

The urban thermal environment can be an important index to detect heat island phenomena and manage it to improve urban life quality. Cheongju is a typical plain-city that main part has been formed and developed in lowland. The Mushim stream crosses the city from south to north. We reviewed the use of thermal remote sensing in stream around areas and the thermal environments, focusing primarily on the Urban Heat Island(UHI) effect. The purpose of this study is to determine the relationship between the stream nearby urban area and the stream cooling effect of UHI. The objectives are to determine the usefulness of KOMPSAT-2 bands MS3 and MS4 for vegetation cover mapping, and the usefulness of LANDSAT TM band 6 in identifying thermal environmental characteristics and UHI. Land Surface Temperatures (LST) are retrieved by single-channel algorithm to study the UHI from the 6th band (thermal infrared band) of LANDSAT TM images and thermal radiance thermometer based on remote sensing method and the LST distribution maps are accomplished according to the retrieval results. There is also comparison of satellite-derived and in situ measured temperature. The results indicated that the LST of urban center is higher than that of suburban area, the temperature of mountain and water are the lowest area, so it is clearly proved that there are obvious UHI effects by stream. The surface temperature distribution of Mushim stream is detected $2^{\circ}C$ lower than urban area.

• Journal of Microbiology and Biotechnology
• /
• 제20권6호
• /
• pp.1032-1041
• /
• 2010

The comparative influence of two nanoparticles [viz., superparamagnetic iron oxide nanoparticles (SPION) and nanobarium titanate (NBT)] upon the in vitro and in situ low-density polyethylene (LDPE) biodegradation efficiency of a potential polymer-degrading microbial consortium was studied. Supplementation of 0.01% concentration (w/v) of the nanoparticles in minimal broth significantly increased the bacterial growth, along with early onset of the exponential phase. Under in vitro conditions, ${\lambda}$-max shifts were quicker with nanoparticles and Fourier transform infrared spectroscopy (FTIR) illustrated significant changes in CH/$CH_2$ vibrations, along with introduction of hydroxyl residues in the polymer backbone. Moreover, simultaneous thermogravimetric-differential thermogravimetry-differential thermal analysis (TG-DTG-DTA) reported multiple-step decomposition of LDPE degraded in the presence of nanoparticles. These findings were supported by scanning electron micrographs (SEM), which revealed greater dissolution of the film surface in the presence of nanoparticles. Furthermore, progressive degradation of the film was greatly enhanced when it was incubated under soil conditions for 3 months with the nanoparticles. The study highlights the significance of bacteria-nanoparticle interactions, which can dramatically influence key metabolic processes like biodegradation. The authors also propose the exploration of nanoparticles to influence various other microbial processes for commercial viabilities.

• 태양에너지
• /
• 제17권3호
• /
• pp.3-11
• /
• 1997

Recently the construction of atrium buildings has increased but along with it many problems in thermal environment have arised. since the exterior wall of glass, indoor temperature is greatly influenced by weather conditions and since the space volume is very large, the vertical air temperature is not uniform. So, in this study, a Vertical Temperature Distribution Model was developed to predict the vertical air temperature of an atrium and evaluate the effects of the design parameters on the air temperature distribution of an atrium. To consider the characteristics of the vertical air temperature distribution in an atrium, the Satosh Togari's Macroscopic Model was used basically for the calculation of the vertical air temperature distribution in large space and the solar radiation analysis model and natural ventilation analysis model in atrium. And to calculate the unsteady-state inside wall surface temperature(boundary condition), the finite difference method was used. For the verification of the developed temperature distribution program, numerical evaluation of air flow by the ${\kappa}-{\varepsilon}$ turbulence model and in-situ test was conducted in parallel. The results of this study, the developed temperature distribution program was seen to predict the thermal condition of the atrium very accurately.