• Title/Summary/Keyword: improving reaction

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The Performance of Photocatalyst filter for an Air Cleaner-Effect of novel metal (공기정화기용 광촉매 필터의 성능-귀금속 담지 영향)

  • Jang, Hyun-Tae;Kim, Jeong-Keun;Cha, Wang-Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.6
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    • pp.1284-1291
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    • 2006
  • This work examined improving the activity of photocatalyts by novel metal doping for the degradation of volatile organic compounds, such as formaldehyde and acetone. The activity was determined with type of dopant novel metal and volatile organic compounds. The palladium-doped $TiO_2$ was found to be improved the decomposition of acetone. The photocatalytic degradation rate for acetone was increased with decreasing temperature to $45^{\circ}C$. The optmum temperature of photocatalytic degradation rate for formaldehyde was $75^{\circ}C$. The enhancement of reaction rate with novel metal were 1.0 wt.% of palladium for acetone, 1.0 wt.% of plaitnum for formaldehyde.

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Optimization of inlet concentration condition for uniform film growth in a cylindrical CVD chamber (원통형 화학증착로에서 균일한 박막형성을 위한 입구 농도분포의 최적화)

  • Jo, Won-Guk;Choe, Do-Hyeong;Kim, Mun-Eon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.2
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    • pp.173-183
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    • 1998
  • An optimization procedure to find the inlet concentration profile that yields the most uniform deposition rate in a cylindrical CVD chamber has been developed. Assuming that the chemical reaction time is negligibly small, a SIMPLE based finite-volume method is adopted to solve the fully elliptic equations for momentum, temperature, and concentration. The inlet concentration profile is expressed by a linear combination of Chebyshev polynomials and the coefficients of which are determined by the local random search technique. It is shown that the present method is very effective in improving the uniformity of the deposition rate, especially when Re is high and/or the wafer is placed close to the inlet. The optimal profiles have been obtained for various Re, Gr, and geometry combinations.

Effect of Neutral Salts on the Reactive Dyeing of Silk(I) -Effect of Cations- (중성염이 견의 반응염색에 미치는 영향(I) - 양이온의 영향-)

  • 도성국;박찬헌;권지윤
    • Textile Coloration and Finishing
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    • v.12 no.6
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    • pp.372-379
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    • 2000
  • Four kinds of neutral salts with different cations, LiCl, NaCl, KCl, and CsCl, were added to the dye bath to accurately understand the effect of cations on the reactive dyeing of silk with C. I. Reactive Black 5. The cations of salts added lowered the negative surface potential of the silk, improving equilibrium adsorption and the accessibility of the dyestuff to the fiber greatly and speeding up the dyeing rate in the order of $Li^+>Na^+>K^+>Cs^+$. The activation energy$(E_a)$ for the dyeing was in the order of$Li^+>Na^+>K^+>Cs^+$ but the activation free energy$(\Delta{G}^*)$, or the real energy barrier for the reaction, was in the order of $Li^+>Na^+>K^+>Cs^+$ because the degree of the contribution of E$^{a}$ to the activation entropy$(\Delta{S}^*)$ was $Li^+>Na^+>K^+>Cs^+$. It was found from this result that LiCl had the strongest lowering effect on the negative surface potential of silk. The decrease in $\Delta{S}^*$ should be attributed to the loosely bonded activated complex of dyestufffs, cations and fiber molecules at transition state. It was clarified from the Bronsted equation that salts had the ionic strength effect and the specific salt effect on the reactive dyeing.

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Sodium Hypochlorite Solution As a Chemical Wounding Agent for Improving Agrobacterium-mediated Chinese Cabbage Seed Transformation (Sodium hypochlorite처리에 따른 배추종자의 Agrobacterium이용 형질전환 증대)

  • Shin Dong-Il;Park Hee-Sung
    • Journal of Life Science
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    • v.15 no.6 s.73
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    • pp.1034-1036
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    • 2005
  • Chinese cabbage (Brassica campestris ssp. napus var. pekinensis Makino) seeds/seedlings were transformed via vacuum-infiltration with recombinant Agrobacterium tumefaciens LBA4404 cells. The agroinfiltration method was determined to be unsuccessful for Chinese cabbage transformation during the analysis of hepatitis B surface antigen expression by ELISA. However, treatment of sodium hypochlorite solution, prior to agroinfiltration, to pregerminated or germinating 1 day- or 2 days-old seeds was proven effectively to enhance transformation efficiency, suggesting that chemical wounding caused by sodium hypochlorite reaction might facilitate Agrobacterium infection and, therefore, transient gene expression in Chinese cabbage sprouts.

Effects of Lumbar Stabilization Exercise on Motor Neuron Excitability and Pain in Patients with Lumbar Disc Herniation

  • Kang, Jeongil;Jeong, Daekeun;Choi, Hyunho
    • Journal of International Academy of Physical Therapy Research
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    • v.10 no.2
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    • pp.1785-1790
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    • 2019
  • Background: Lumbar disc herniation (LDH) causes neurological symptoms by compression of the dura mater and nerve roots. Due to the changed in proprioception inputs that can result in abnormal postural pattern, delayed reaction time, and changed in deep tendon reflex. Objective: To investigate the effects of lumbar stabilization exercises on motor neuron excitability and neurological symptoms in patients with LDH. Design: Randomized Controlled Trial (single blind) Methods: Thirty patients with LDH were recruited; they were randomly divided into the balance center stabilization resistance exercise group (n=15) and the Nordic walking group (n=15). Each group underwent their corresponding 20-minute intervention once a day, four times a week, for four weeks. Participants' motor neuron excitability and low back pain were assessed before and after the four-week intervention. Results: There were significant differences in all variables within each group (p<.05). There were significant differences between the experimental and control groups in the changes of upper motor neuron excitability and pain (p<.05), but not in the changes of lower motor neuron excitability and Korean Oswestry Disability Index. Conclusion: Lumbar stabilization exercises utilizing concurrent contraction of deep and superficial muscles improved low back function in patients with LDH by lowering upper motor neuron excitability than compared to exercises actively moving the limbs. Lumbar stabilization exercises without pain have a positive impact on improving motor neuron excitability.

Current Status of One-Dimensional Nanostructured Catalysts for Polymer Electrolyte Membrane Fuel Cell (고분자 전해질 막 연료 전지용 1차원 나노 구조 촉매의 연구 현황)

  • Jeon, Kiung;Jung, Yeon Sik
    • Ceramist
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    • v.21 no.4
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    • pp.331-348
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    • 2018
  • With the expectation to overcome the problem of increasing energy consumption, polymer electrolyte membrane fuel cells are getting more attention as a promising environmentally friendly and sustainable next-generation energy conversion system. In spite of the rapid improvement of polymer electrolyte membrane fuel cells(PEMFCs), there are several critical issues still need to be resolved for practical commercialization. Out of the many issues, the main hurdle comes from oxygen reduction reaction(ORR), thus development of efficient ORR electrocatalysts is the main key for enhancing PEMFC performance. Among various catalysts, 1D nanostructured catalyst is a promising candidate because it holds many advantages that come from nanostructuring while supplementing the disadvantages of other nanostructures such as nanoparticles(0D) or gyroids(3D). This review focused on diverse 1D nanostructures and talks about their advantages as catalyst for ORR. Different 1D nanostructures will be introduced while applying the structures to different materials system showing the prospects of 1D nanostructures for improving PEMFC.

The addition of nitrogen oxides for improving the rate of catalytic ozone-induced oxidation of soot (산화질소 첨가에 의한 오존 기반 탄소입자상물질 촉매연소반응 속도의 개선)

  • Lee, Namhun;Park, Tae Uk;Lee, Jin Soo;Lee, Dae-Won
    • Journal of Industrial Technology
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    • v.39 no.1
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    • pp.1-5
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    • 2019
  • In this study, we examined the effect of NO addition on the ozone-induced soot oxidation activity of $LaMnO_3$ perovskite catalysts. The addition of 10~20% NO ($NO_2$) with respect to the concentration of ozone effectively enhanced the rate of ozone-induced soot oxidation rate over $LaMnO_3$. However, the excessive addition of NO ($NO_2$) was detrimental to ozone-induced soot oxidation activity. It is supposed nitrogen oxides would adsorb on the catalyst and then react with carbon-oxygen species developed on soot surface, but an excessive addition of nitrogen oxide would inhibit the formation of carbon-oxygen species, which is a key intermediate in the reaction, and consequently suppress the oxidation rate of soot.

Preparation and Characterization of the Polymeric Antioxidant for Improving the Chemical Durability of Polymer Electrolyte Membranes (고분자 전해질 막의 화학적 내구성 향상을 위한 고분자형 산화방지제 제조 및 특성 분석)

  • LEE, BYEOL-NIM;KODIR, ABDUL;LEE, HYEJIN;SHIN, DONGWON;BAE, BYUNGCHAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.308-314
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    • 2021
  • Chemical durability issue in polymer electrolyte membranes has been a challenge for the commercialization of polymer electrolyte membrane fuel cells (PEMFCs). In this study, we proposed a manufacturing method of Nafion composite membrane containing a stable polyimide antioxidant to improve the chemical durability of the membrane. The thermal casting of the Nafion solution with poly (amic acid) induced polyimide reaction. We evaluated proton conductivity, oxidative stability with ex-situ Fenton's test, and fluoride ion emission to analyze the effect of polyimide antioxidants. We confirmed that incorporating the polyimide antioxidant improves the chemical durability of the Nafion membrane while maintaining inherent proton conductivity.

Conversion of organic residue from solid-state anaerobic digestion of livestock waste to produce the solid fuel through hydrothermal carbonization

  • Yang, Seung Kyu;Kim, Daegi;Han, Seong Kuk;Kim, Ho;Park, Seyong
    • Environmental Engineering Research
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    • v.23 no.4
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    • pp.456-461
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    • 2018
  • The solid-state anaerobic digestion (SS-AD) has promoted the development and application for biogas production from biomass which operate a high solid content feedstock, as higher than 15% of total solids. However, the digested byproduct of SS-AD can be used as a fertilizer or as solid fuel, but it has serious problems: high moisture content and poor dewaterability. The organic residue from SS-AD has to be improved to address these problems and to make it a useful alternative energy source. Hydrothermal carbonization was investigated for conversion of the organic residue from the SS-AD of livestock waste to solid fuels. The effects of hydrothermal carbonization were evaluated by varying the reaction temperatures within the range of $180-240^{\circ}C$. Hydrothermal carbonization increased the calorific value through the reduction of the hydrogen and oxygen contents of the solid fuel, in addition to its drying performance. Therefore, after the hydrothermal carbonization, the H/C and O/C atomic ratios decreased through the chemical conversion. Thermogravimatric analysis provided the changed combustion characteristics due to the improvement of the fuel properties. As a result, the hydrothermal carbonization process can be said to be an advantageous technology in terms of improving the properties of organic waste as a solid-recovered fuel product.

Development of Extracellular Matrix (ECM) based Dermal Filler (세포외기질(ECM) 생체소재 기반 필러 개발 연구)

  • Kim, Na Hyeon;Park, Sang-Hyug
    • Journal of Biomedical Engineering Research
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    • v.40 no.4
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    • pp.137-142
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    • 2019
  • Numerous efforts are being made to develop an ideal dermal filler that should be bio-compatibility, non-immunogenicity, long-lasting and biodegradable without a toxic secretion. Biomaterials of dermal fillers are hyaluronic acid filler, calcium filler, PMMA filler and collagen filler depending on the ingredient. Although hyaluronic acid (HA) is most widely used, it has shortages such as short shelf life and low mechanical strength compare to extracellular matrix (ECM). The cartilage ECM composed of collagen type II, proteoglycans, glycosaminoglycans (GAGs) and in a minor part with glycoproteins. In this study, we developed a cartilage ECM injectable filler capable of improving biocompatibility and longevity compared with hyaluronic acid (HA) fillers. The ECM hydrogel was cross-linked by the reaction of N-(3-Dimethylaminopropyl)-N'-ethylcarbodiimide hydrochloride (EDC)/N-hydroxysuccinimide (NHS) for mechanical enhancement. Prepared ECM filler was compared with cross-linked HA by butanediol diglycidyle ether (BDDE), which is the most widely used natural polymers for dermal filler. In the results, the articular cartilage ECM hydrogel has great potential as a dermal filler to improve the biophysical and biological performance.