• 한국물환경학회지
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• 제33권1호
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• pp.34-39
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• 2017

Under a corrosive environment, electrodes that are applied in the water-treatment system need not only very high electrochemical activity for fast reactions, but also high durability for cost saving. Therefore, the fabrication condition of iridium electrodes was examined to produce a more durable iridium electrode in this study. Tantalum was selected as a binder to enhance the durability of the iridium electrode. Investigation of the weight ratio between the catalyst and the binder to improve electrochemical activity was performed. Also, to compare the effect of the different coating amounts of the catalyst, the results of CV (Cyclic Voltammetry) and EIS (Electrochemical Impedance Spectroscopy) were discussed. Furthermore, an ALT(Accelerated Lifetime Test) was designed and applied to the electrodes to determine the conditions for highly durable electrode fabrication.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.181-181
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• 2012

The microwave probe for measuring plasma density is widely used for its advantages: First, it is not affected by the reactive gas. Second, it can measure local plasma parameters such as plasma density, plasma potential and plasma temperature. Third, it is simple and robust. A cut-off probe is the one of the most promising microwave probe. Recently, Kim et al. reveals the physics of the cut-off probe but the effect of the sheath on the determination of the plasma density is not explained. In this presentation, for taking account of sheath effects on determination of plasma density from the cut-off peak, a simplified circuit modeling and an E/M simulation are conducted. The results show that occupation ratio of sheath volume between two tips of the cut-off probe and subsequence pressure condition mainly change position of the cut-off peak with respect to plasma frequency. Magnitude of relative voltage taken on the impedance of sheath and the impedance of bulk plasma can explain this effect. Furthermore, effects of gap size, tip radius, and tip length ware revealed based on above analysis.

• 한국수소및신에너지학회논문집
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• 제12권3호
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• pp.231-238
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• 2001

Electrocatalytic activity of palladium for hydrogen oxidation and reduction was studied using AC impedance method. The system under study was arranged in electrolytic mode consisting of Pd electrode under study, Pt counter electrode and Nafion electrolyte between them. Two types of Pd electrodes were used - carbon-supported Pd (Pd/C) and Pd foil electrode. Pd/C anode contacting pure hydrogen showed a steady decrease of charge transfer resistance with the increase of anodic overpotential, which is an opposite trend to that found with Pd foil anode. But Pd foil cathode also exhibited a decrease of the resistance with the increase of cathodic overpotential. The relationship between imposition of overpotential and subsequent change of the charge transfer resistance is determined by the ratio of the rate of faradaic process to the rate of mass transportation; if mass transfer limitation holds, increase of overpotential accompanies the increase of charge transfer resistance. Regardless of the physical type of Pd electrode, the anode contacting hydrogen/oxygen gas mixture did not reveal any independent arc originated from local anodic oxygen reduction.

• 한국전자파학회논문지
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• 제18권3호
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• pp.315-322
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• 2007

본 논문에서는 UHF RFID Reader 장치에서 고주파 신호 송신을 위한 발진기형 능동 안테나를 설계 제작하였다. 능동 안테나의 방사체로는 임피던스 정합이 용이하면서 좌선 원형 편파 특성을 갖는 소형화된 사각형 링 패치 안테나가 제안되었다. 이를 기반으로 링 패치 내부의 빈 공간에 RF증폭 회로를 위치시켜 사각형 링 패치와 상호연결하여 궤환 구조를 형성함으로써 발진 회로를 구성하였다. 발진 중심 주파수는 915 MHz이며 링 패치는 발진기의 공진기로 활용하였다. 실험 결과, 임피던스 대역폭 29 MHz, 3 dB 축비 대역폭 20 MHz, 3 dB 빔폭 $85^{\circ}$, 그리고 유효 방사 전력을 8.8 dBm을 얻었다.

• 한국전기전자재료학회논문지
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• 제13권4호
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• pp.306-311
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• 2000

The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. The temperature dependence of conductivity impedance spectroscopy and electrochemical properties of PDF/PAN electrolytes as a function of a mixed ratio were reported for PVDF/PAN based polymer electrolyte films which were prepared by thermal gellification method of preweighed PVDF/PAN plasticizer and Li salt. The conductivity of PVDF/PAN electrolytes was 10$\^$-3/S/cm. 20PVDF5PEN LiCiO$\_$4//PC$\_$10//EC$\_$10/ electrolyte has the better conductivity compared to others. 20PVDF5PANLICIO$\_$4//PC$\_$10//EC$\_$10/ electroylte remains stable up to 5V vs. Li/Li$\^$+/. Steady state current method and ac impedance were used for the determination of transference numbers in PVDF/PAN electrolyte film. The transference number of 20PVDF5PANLiCO$\^$4//PC$\_$10//EC$\_$10/ electrolyte is 0.48.

• Journal of Electrochemical Science and Technology
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• 제1권1호
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• pp.57-62
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• 2010

The lithium ion concentration dependant ionic conductivity and thermal properties of poly(ethylene glycol) methyl ether methacrylate (PEGMA)/acrylonitrile-based copolymer electrolytes with $LiClO_4$ have been studied by differential scanning calorimetry (DSC), linear sweep voltammetry (LSV) and AC complex impedance measurements. In systems with 11 wt% of acrylonitrile all liquid electrolytes were obtained regardless of lithium ion concentration. Complex impedance measurements with stainless steel electrodes give ambient ionic conductivities $8.1\times10^{-6}\sim1.4\times10^{-4}S cm^{-1}$. On the other hand, a hard and soft films at ambient temperature were obtained in copolymer electrolyte system consists of 15 wt% acrylonitrile with 6 : 1 and 3 : 1 of [EO] : [Li] ratio, respectively. DSC measurements indicate the crystalline melting temperature of poly(PEGMA) disappeared completely after addition of $LiClO_4$ in this system due to the complex formation between ethylene oxide (EO) unit and lithium salt. As a result, free standing film with room temperature ionic conductivity of $1.7\times10^{-4}S cm^{-1}$ and high electrochemical stability up to 5.5V was obtained by controlling of acrylonitrile and lithium salt concentration.

• 대한화학회지
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• 제14권4호
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• pp.327-332
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• 1970

A simple and convenient device for deflection-type direct reading the variations in electrolytic conductance is described and applied to the analysis of sulfur by combustion-$H_2O_2$ oxidation method. The apparatus consisted of a high resistance-ratio bridge in which the other adjacent arms are the differential cells. By adopting unusually high a-c voltage source for the bridge excitation, the a-c method for unbalanced bridge is established, decreased sensitivity owing to reduced bridge factor, 0.01, is overcome and also the absolute sensitivity and linearity are greatly improved. Over 50% variations in impedance of the balanced cell, within 1% deviation from the linearity can be attained with a volt (rms)order of output which was detected directly with VTVM without further amplification. Analysis of the bridge shows that these useful features are natural result of the constant current character of the high source impedance generator and the performance of the device agreed with the theoretical predictions. A standard procedure for the rapid analysis of sulfur using the bridge is also given, the analytical accuracy was approximately 1%. A determination takes not more than 5 minutes.

• 전력전자학회논문지
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• 제22권6호
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• pp.469-475
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• 2017

Using impedance matching techniques as a way to increase system power transferability in capacitive wireless power transmission has been widely investigated in conventional studies. However, these techniques tend to increase the circuit volume and thus counterbalance the advantage of the simplicity in the energy link structure. In this paper, a compact circuit topology with one leakage-enhanced transformer is proposed in order to minimize the circuit volume for the capacitive power transfer system. This topology achieves a reactive compensation, and the system quality factor value can be reduced by the turn ratio. As a result, this topology not only reduces the overall system volume but also minimizes the voltage stress of the link capacitor. An optimal design guideline for the leakage-enhanced transformer is also presented. The advantages of the proposed scheme over the conventional method in terms of power efficiency and circuit volume are revealed through an analytic comparison. The feasibility of applying the new topology is also verified by conducting 50 W hardware tests.

• Journal of Power Electronics
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• 제13권6호
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• pp.1008-1015
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• 2013

By using fractional calculus and the circuit-averaging technique, the modeling and analysis of a Buck converter with fractional order inductor and fractional order capacitor in discontinuous conduction mode (DCM) operations is investigated in this study. The equivalent averaged circuit model of the fractional order Buck converter in DCM operations is established. DC analysis is conducted by using the derived DC equivalent circuit model. The transfer functions from the input voltage to the output voltage, the duty cycle to the output voltage, the input impedance, and the output impedance of the fractional order Buck converter in DCM operations are derived from the corresponding AC-equivalent circuit model. Results show that the DC equilibrium point, voltage ratio, and all derived transfer functions of the fractional order Buck converter in DCM operations are affected by the inductor order and/or capacitor order. The fractional order inductor and fractional order capacitor are designed, and PSIM simulations are performed to confirm the correctness of the derivations and theoretical analysis.

• Structural Engineering and Mechanics
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• 제80권5호
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• pp.563-583
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• 2021

Composite materials, composed of multiple constituent materials with dissimilar properties, are actively adopted in a wide range of industrial sectors due to their remarkable strength-to-weight and stiffness-to-weight ratio. Nevertheless, the failure mechanism of composite materials is highly complicated due to their sophisticated microstructure, making it much harder to predict their residual material lives in real life applications. A promising solution for this safety issue is structural damage detection. In the present paper, damage detection of composite material via electrical resistance-based technique and infrared thermography is reviewed. The operating principles of the two damage detection methodologies are introduced, and some research advances of each techniques are covered. The advancement of IR thermography-based non-destructive technique (NDT) including optical thermography, laser thermography and eddy current thermography will be reported, as well as the electrical impedance tomography (EIT) which is a technology increasingly drawing attentions in the field of electrical resistance-based damage detection. A brief comparison of the two methodologies based on each of their strengths and limitations is carried out, and a recent research update regarding the coupling of the two techniques for improved damage detection in composite materials will be discussed.