• Korean Journal of Materials Research
• /
• v.22 no.3
• /
• pp.159-167
• /
• 2012

Hydrogen is in the spotlight as an alternative next generation energy source for the replacement of fossil fuels because it has high specific energy density and emits almost no pollution, with zero $CO_2$ emission. In order to use hydrogen safely, reliable storage and transportation methods are required. Recently, solid hydrogen storage systems using metal hydrides have been under extensive development for application to fuel cell vehicles and fuel cells of MCFC and SOFC. For the practical use of hydrogen on a commercial basis, hydrogen storage materials should satisfy several requirements such as 1) hydrogen storage capacity of more than 6.5wt.% $H_2$, moderate hydrogen release temperature below $100^{\circ}C$, 3) cyclic reversibility of hydrogen absorption/desorption, 4) non toxicity and low price. Among the candidate materials, Li based metal hydrides are known to be promising materials with high practical potential in view of the above requirements. This paper reviews the characteristics and recent R&D trends of Li based complex hydrides, Li-alanates, Li-borohydrides, and Li-amides/imides.

• Transactions of the Korean hydrogen and new energy society
• /
• v.33 no.6
• /
• pp.623-635
• /
• 2022

As global warming accelerates, clean hydrogen production becomes more important to mitigate it. However, importing hydrogen is necessary for countries that have high energy demands but insufficient resources to produce clean hydrogen. In line with the trend, this study investigated both the economic and environmental viability of an overseas hydrogen supply chain between Australia and the Republic of Korea. Several possible methods of water electrolysis and hydrogen carriers are compared and effect of renewable electricity price on the cost of hydrogen production is evaluated.

• Transactions of the Korean hydrogen and new energy society
• /
• v.33 no.1
• /
• pp.1-7
• /
• 2022

Interest in hydrogen productions that do not emit carbon dioxide and can produce hydrogen at a low price is increasing. Reforming and electrolysis are widely used, but they have limitations, such as carbon dioxide problems and costs. The methane can be decomposed as hydrogen and solid carbon without carbon dioxide emission at high temperatures. In this research, the methane pyrolysis experiment was conducted at 1,200℃ and 1,400℃ in a ceramic tube. The composition of the produced gas was measured by gas chromatography before carbon blocked the tube. The methane conversion rate and hydrogen selectivity were calculated based on the results. The hydrogen selectivity was derived as 60% and 55% at the highest point at 1,200℃ and 1,400℃, respectively. The produced solid carbon was expected to be carbon black and was analyzed using scanning electron microscope.

• Environmental and Resource Economics Review
• /
• v.16 no.2
• /
• pp.275-311
• /
• 2007

Hydrogen energy is emphasized as a substitutable energy of carbon-based energy system in the future, since it is non-depletable and clean energy. Long term vision of Korean government on the national energy system is to promote hydrogen energy by 15% of final energy demand until 2040. This study analyzes economic impacts of hydrogen energy development employing a dynamic CGE model for Korea. Frontier technology such as hydrogen energy is featured as slow diffusion at the initial stage due to the learning effect and energy complementarity. Without government intervention, hydrogen energy would be produced upto 6.5% of final energy demand until 2040. However, if government subsidizes sales price of hydrogen energy by 10%, 20%, and 30%, share of hydrogen energy would increase 9.2%, 15.2%, and 37.7% of final energy demand. This result shows that the slow diffusion problem of hydrogen energy as frontier technology could be figured out by market incentive policy. On the other hand, production levels of transportation sector would increase while growth rate of oil and electricity sectors would decline. Household consumption would be affected negatively since increase of consumption due to the price decrease would be overwhelmed by income reduction owing to the increase of tax. Overall, GDP would not decrease or increase significantly since total production, investment, and export would increase even if household consumption declines.

• Transactions of the Korean hydrogen and new energy society
• /
• v.21 no.6
• /
• pp.595-603
• /
• 2010

This paper deals with an economic evaluation of domestic window type photoelectrochemical hydrogen production utilizing solar cells. We make some sensitivity analysis of hydrogen production prices by changing the values of input factors such as the initial capital cost, the solar to hydrogen conversion efficiency, and the system duration time. The hydrogen production price of the window type photoelectrochemical system was estimated as 1,168,972 won/$kgH_2$. It is expected that hydrogen production cost can be reduced to 47,601 won/$kgH_2$ if the solar to hydrogen conversion efficiency is increased to 14%, the system duration time is increased to 20,000 hours, and the initial capital cost is decreased to 25% of the current level. We also evaluate the hydrogen production cost of the water electrolysis using the electricity produced by solar cells. The corresponding hydrogen production cost was estimated as 37,838 won/$kgH_2$. The photoelectrochemical hydrogen production is evaluated as uneconomical at this time, and we need to enhance the solar to hydrogen conversion efficiency and the system duration time as well as to reduce prices of the system facilities.

• Transactions of the Korean hydrogen and new energy society
• /
• v.18 no.2
• /
• pp.207-215
• /
• 2007

The rapid changes of energy environment such as high oil price, united nations framework convention on climate change, and the hydrogen economy have been happening to provide national energy security in the 21st century, we need to build strategic approach for coping with energy environment. From a long-term viewpoint of energy technology development, it's time to develop energy technology with selection and specification. In this study, we build energy technology roadmap for establishing the hydrogen economy with a long-term strategy. We analyze economic spin-offs and commercial potential for establishing energy technology roadmap of energy technology development for establishing the hydrogen economy.

• 한국신재생에너지학회:학술대회논문집
• /
• 2006.06a
• /
• pp.29-32
• /
• 2006

Recently, many researches of the alternative and renewable energy have introduced due to the increasing oil price, the limited natural resources and the environmental pollution. In case of hydrogen energy, it has some merits, which can be substituted the existing the fossil fuel because of no contaminants from the combustion and the chemical reaction. We have been developing 1kW Hydrogen Linear Generator. In this paper, the thermal characteristic of this prototype linear generator has been investigated and obtained reliable analysis results comparing with experimental measurements. Especially, it is predicted that in case of 1kW, 60Hz test sample, the results satisfy with the temperature standards of H type insulation, which is shown average $69.0^{\circ}C$ temperature distribution at the coil.

• New & Renewable Energy
• /
• v.18 no.1
• /
• pp.35-45
• /
• 2022

The renewable energy based MG is becoming one of the prominent solutions for greenhouse gas and constructing less power lines. However, how to procure the economics of MG considering the CO₂ emission and utility network impact is one of major issues as the proportion of renewable resource increases. This paper proposes the feasibility study scheme of campus MG and shows that the LCOE and CO₂ emission can be reduced by utilizing the excess power and introducing hydrogen system and plus DR. For this, the three cases: (a) adding the PV and selling excess power to utility, (b) producing and selling hydrogen using excess power, and (c) participating in plus DR are considered. For each case, not only the topology and component capacity of MG to secure economic feasibility, but also CO₂ emission and utility network effects are derived. If an electrolyzer with a capacity of 400 kW participates in plus DR for 3,730hours/year, the economic feasibility is securable if plus DR settlement and hydrogen sale price are more than 7.08¢/kWh and 8.3USD/kg or 6.25¢/kWh and 8.6USD/kg, respectively. For this end, continuous technical development and policy support for hydrogen system and plus DR are required.

• Transactions of the Korean hydrogen and new energy society
• /
• v.32 no.5
• /
• pp.417-429
• /
• 2021

Due to fossil fuel depletion and environmental pollution, H2 production from organic waste has received an increased attention. In this study, we present an integrated process for the H2 production from biogas and evaluate the economic feasibility and sustainability via rigorous techno-economic analysis (TEA) and life-cycle assessment (LCA). Through the TEA, we determine the minimum H2 selling price using discounted cash flow analysis and investigate the main cost drivers. The environmental impact of the proposed process is quantified via LCA.

• 한국신재생에너지학회:학술대회논문집
• /
• 2011.05a
• /
• pp.109.1-109.1
• /
• 2011

KEPCO was operating power plants with diesel generators in 49 islands including Baekryeong-Do, and the generation capacity was about 66 MW in 2008. The cost of fuel is increasing by the international oil price inflation and continuous rise of oil price is predicted. For the stabilizing of electric power supply to the separate islands, renewable energy and fuel cell systems were considered. Hydrogen is made using renewable energy such as wind power and solar energy, and then a fuel cell system generates electricity with the stored hydrogen. Though the system efficiency is low, it is treated as the only way to secure the stable electric supply using renewable energy at this present. The analytic hierarchy process was used to select suitable candidate island for the system installation and 5 islands including Ulleung-Do were selected. Economic evaluation for the system composed of a kerosene generator, a wind power, an electrolysis, and a fuel cell system was conducted with levelized generation cost based on present value methode. As the result, the necessity of renewable energy combined generation system and micro grid composition in the candidated islands was confirmed. Henceforth, the development of an integration technology which connects micro grid to the total power grid will be needed.