• 한국추진공학회지
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• 제13권4호
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• pp.16-21
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• 2009

과산화수소의 저장성 평가 방법을 소개하고, 고농도 과산화수소의 저장성을 평가하였다. 농도 측정 방법을 통하여 저장성을 평가하였으며, 과산화수소의 MIL-PRF-16005F 기준 만족 여부와 저장 온도 및 저장 용기의 마개 재질을 실험 변수로 선정하여 저장성을 평가하였다. 8~24개월 동안 측정을 수행한 결과, 안정제가 포함된 과산화수소가 추진제급 과산화수소에 비해 저장성이 매우 떨어졌으며, 과산화수소 증기와 반응을 보이지 않은 파라핀 필름으로 용기를 밀폐하였을 때, 플라스틱 마개를 사용한 경우에 비해 좋은 저장성을 나타내었다. 또한 과산화수소의 저장성에는 온도가 매우 큰 영향을 미쳐 상온에 비해 $10^{\circ}C$ 이하에서 보관하였을 때 저장성이 크게 향상되었다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제18권7호
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• pp.25-31
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• 2013

Hydrogen peroxide takes much of the cost for Fenton reaction applied for treatment of organic contaminants. Therefore, the effective use of hydrogen peroxide makes the technology more cost effective. The effective use of hydrogen peroxide is especially needed in the soil and groundwater remediation where complete mixing is not possible and it takes a long time for reactive species to transport to the fixed target compounds. Stabilization ability for hydrogen peroxide of malonic acid was evaluated in Fenton and Fenton-like reactions in this study. Malonic acid contributes on the stabilization of hydrogen peroxide by weak interaction between iron and the stabilizer and inhibiting the catalytic role of iron. The stabilization effect increased as the solution pH decrease below the $pK_{a1}$. The stabilization effect increased as the concentration of malonic acid increased and the effect was maximized at the malonic acid concentration of about ten times higher than the iron concentration. The model organic contaminant was successfully oxidized in the presence of the stabilizer but the degradation rate was slower than the system without the stabilizer. The stabilization effect was also proved in a Fenton-like reaction where magnetite and hematite were used instead of soluble iron species.

• 대한토목학회논문집
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• 제31권4B호
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• pp.377-382
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• 2011

본 연구에서는 modified fenton 반응에서 과산화수소를 안정화하여 오염토양 정화의 효과를 증대시키고자 하였다. 오염토양을 모사하기 위하여 PAHs 계열의 대표적인 오염물질인 phenanthrene을 사용하였다. 과수안정제로는 음이온 계면활성제인 SDS(Sodium dodecyl Sulfate)를 사용하였다. Modified Fenton 반응에서 phenanthrene의 제거율을 확인하기 위하여 Fe(II) 4 mM, SDS 5~50 mM 및 $H_2O_2$ 102.897 mM를 phenanthrene 125 mg/kg으로 오염된 토양에 주입하였다. 과수안정제인 SDS가 30 mM이 사용된 경우 phenanthrene의 제거 효율이 95%로 가장 높게 나타났으며 30 mM이싱에서는 시스템에서 SDS가 scavenger로 작용하여 오염물질의 제거효율이 SDS 30 mM 일 때 보다 낮게 나타났다. 과수안정제를 사용한 뒤 과산화수소의 농도변화를 분석한 결과 Fe(II) 2 mM에서 48시간 이후 14.6995 mM 이상 남아있어서 가장 안정적이었지만, Fe(III)을 주입한 경우에는 과산화수소가 안정화되지 않았다. Modified Fenton 반응에서 철과 SDS 농도 사이의 최적의 비율을 찾기 위하여 SDS의 농도는 30 mM로 고정하고 철의 농도를 2~8 mM로 변화시켜 실험한 결과 Fe(II) 4 mM 및 SDS 30 mM에서 약 95%의 가장 높은 제거율을 보였다.

• 펄프종이기술
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• 제44권1호
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• pp.65-73
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• 2012

Nowadays, the concern on the environmental load of bleaching process gave rise to the process of ECF(elemental chlorine free) and TCF(total clorine free). These sequences are based on oxygen-derived compounds such as oxygen, ozone, and hydrogen peroxide which is used as a typical eco-friendly bleaching agent. In this study, paper mulberry pulp was bleached with hydrogen peroxide and some bleaching process were accompanied with ultrasonication in order to increase the bleaching efficiency. The best bleaching efficiency of paper mulberry pulp was obtained in the condition of hydrogen peroxide and ultrasonication(20 kHz) bleaching system at $45^{\circ}C$ for 30 min. The brightness and kappa number of paper mulberry pulp were gained to 5.09% and 3.52 respectively. and yield was slightly loosed to 2%. Therefore, the efficiency of hydrogen peroxide and ultrasonication bleaching system of paper mulberry pulp was superior to the conventional hydrogen peroxide bleaching system. Magnesium sulfate acted as a bleaching stabilizer for the increasement of yield. As a result, the yield and viscosity were increased to 2.2% and 12% respectively.

• 분석과학
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• 제31권1호
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• pp.47-56
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• 2018

사건 현장에 남겨진 혈흔을 찾는 것은 사건을 재구성하거나 해결하기 위해서 매우 중요하다. 사건현장에서 사용할 수 있는 수많은 시약들이 개발되었지만, 루미놀이 가장 대표적인 시약이라고 할 수 있다. 최근에는 블루스타라는 시약이 주로 사용되고 있지만, 가격이 비싸고 시약을 제조한 후 보관이 불가능하다는 단점이 있다. 본 연구에서는 블루스타 수준의 발광강도를 유지하면서 제조 후 장시간 보관할 수 있는 새로운 루미놀 시약을 개발하고자 했다. 루미놀은 알칼리 수용액에서 잘 녹기 때문에, 시약을 제조할 때 수산화나트륨의 사용은 과산화수소의 분해를 촉진시킬 수 있다. 루미놀 시약을 제조할 때 과산화수소 안정화제로 황산마그네슘, 규산나트륨, 삼인산칼륨을 농도별로 첨가한 후, 혈흔과 반응할 때 시약의 발광강도 및 보관기간에 미치는 영향을 확인했다. 과산화수소 안정화제 첨가는 발광강도에 별다른 영향을 주지 않았고, 보관 중 루미놀 시약의 pH를 일정하게 유지시켜 줌으로서 시약의 보관기간을 크게 늘려줬다. 과산화수소 안정화제로 황산마그네슘이 가장 적절하였다. 과산화수소 대신 과붕산나트륨을 산화제로 사용했을 경우, 희석 혈흔에 대한 민감도와 발광강도에 큰 변화는 없었지만 제조 후 보관기간이 단축되었다. 그렇지만, 혈흔과 반응한 후 혼합액의 pH 상승 폭이 과산화수소로 제조한 시약보다 줄어들었다.

• Transactions on Electrical and Electronic Materials
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• 제4권2호
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• pp.1-4
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• 2003

The purpose of this study was to investigate the characteristics of slurry including phosphoric acid for chemical-mechanical planarization of copper and tantalum nitride. In general, the slurry for copper CMP consists of alumina or colloidal silica as an abrasive, organic acid as a complexing agent, an oxidizing agent, a film forming agent, a pH control agent and additives. Hydrogen peroxide (H$_2$O$_2$) is the material that is used as an oxidizing agent in copper CMP. But, the hydrogen peroxide needs some stabilizers to prevent decomposition. We evaluated phosphoric acid (H$_3$PO$_4$) as a stabilizer of the hydrogen peroxide as well as an accelerator of the tantalum nitride CMP process. We also estimated dispersion stability and zeta potential of the abrasive with the contents of phosphoric acid. An acceleration of the tantalum nitride CMP was verified through the electrochemical test. This approach may be useful for the development of the 2$\^$nd/ step copper CMP slurry and hydrogen peroxide stability.

• 한국의류학회지
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• 제29권11호
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• pp.1454-1464
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• 2005

The study was based on a three-stage, non-repetitive factorial experiment in which chemical-rotted kenaf fibers were treated separately with hydrogen peroxide concentrations of $0.5\%,\;1\%\;and\;2\%$, with pH solutions of 7, 9 and 11, and treatment times of 30, 60 and 90 minutes. Under optimal conditions, the study was conducted to determine the strength and elongation of kenaf fibers by the addition of chelators, penetrants and surfactants. The hydrogen peroxide concentration, solution pH and treatment time directly affected the strength of kenaf fibers. The hydrogen peroxide concentration, solution pH affected the elongation of kenaf fibers. It was found, however, that the interaction between pH and treatment time, concentration and treatment time, concentration and treatment time and pH affected the strength of kenaf fibers. Also, It was found that the interaction between pH and concentration, concentration and treatment time, concentration and treatment time and pH affected the elongation of kenaf fibers. Under the hydrogen peroxide conditions of $2\%$ concentration, pH 11 and a treatment time of 60 minutes, there were no effects on the strength and elongation of kenaf fibers with the addition of chelator SP, CA.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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• pp.136-139
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• 2003

Copper has attractive properties as a multi-level interconnection material due to lower resistivity and higher electromigration resistance as compared with Alumina and its alloy with Copper(0.5%). Among a variety of agents in Copper CMP slurry, $H_2O_2$ has commonly been used as the oxidizer However. $H_2O_2$ is so unstable that it requires stabilization to use as oxidizer Hence, stabilization of $H_2O_2$ is a vital process to get better yield in practical CMP process. In this article the stability of Hydrogen Peroxide as oxidizer of Copper CMP slurry has been investigated. When alumina abrasive was used, $\gamma$-particle Alumina C had a better stability than $\alpha$-particle abrasive. As adding KOH as pH buffering agent, $H_2O_2$ stability in slurry decreased. Urea hydrogen peroxide was used as oxidizer, an enhanced stability was gotten. When $H_3PO_4$ as $H_2O_2$ stabilizer was added, the decrease of $H_2O_2$ concentration in slurry became slower. Even though adding $H_2O_2$ in slurry after bead milling lead to better stability than in advance of bead milling, it had a lower dispersibility.

• Bulletin of the Korean Chemical Society
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• 제35권2호
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• pp.431-435
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• 2014

Zinc peroxide nanoparticles ($ZnO_2$ NPs) were prepared by reacting zinc(II) isobutylcarbamate, as an organometallic precursor, with hydrogen peroxide ($H_2O_2$) at $60^{\circ}C$. Polyethylene glycol and polyvinylpyrrolidone were used as stabilizers, which suppressed aggregation of the $ZnO_2$ NPs. Conditions such as concentrations of $H_2O_2$ and the stabilizer were systemically controlled to determine their effect on the formation of nano-sized $ZnO_2$ NPs. The formation of stable $ZnO_2$ NPs was confirmed by UV-vis, Raman spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy (TEM), scanning electron microscopy (SEM), and X-ray diffraction. The TEM images revealed that polyvinylpyrrolidone-stabilized $ZnO_2$ NPs (diameter, 10-30 nm) were well dispersed in the organic solvent. Quite pure ZnO NPs were obtained from the peroxide powder by simple heat treatment of $ZnO_2$. The transition temperature of $170^{\circ}C$ was determined by differential scanning calorimetry.

• 분석과학
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• 제12권2호
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• pp.125-129
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• 1999

고농도의 과산화수소(10-75%)를 생산현장에서 손쉽게 측정할 수 있는 전극 센서 시스템을 연구하였다. Teflon 전극체는 휴대에 간편하도록 길이 10 cm, 지금 1.5 cm의 봉 형태로 제작하였고, 작업 극으로는 직경 3 mm의 glassy carbon을, 보조전극으로는 내경 5 mm, 외경 9 mm의 흑연을 전극물질로 사용하였다. 과산화수소 산화전위는 0.8 V의 전위를 걸어주었다. 공장에서 생산된 고농도의 과산화수소를 일정 이온강도의 전해질 용액으로 희석해 10% 이하의 농도가 되도록 하면 과산화수소에 첨가된 안정제의 방해작용과 과산화수소의 산화작용으로 인한 전극표면의 변성을 최소화할 수 있었고, 손쉽게 정량적인 측정을 할 수 있었다. 또한 과산화수소 투과막(teflon membrane${\leq}100{\mu}m$)을 입힌 전극을 이용하면 고농도의 과산화수소를 희석하지 않고 재현성 있게 정량할 수 있었다. 반면 투과막을 이용하는 방법을 내부전해질을 자주 교환해야 하는 단점이 있었다.