Browse > Article
http://dx.doi.org/10.12652/Ksce.2011.31.4B.377

A Study about Development of Hydrogen Peroxide Stabilizer in Modified Fenton Reaction Using Anion Surfactant  

Kim, Han Ki (한양대학교 대학원 건설환경공학과)
Park, Kang Su (한양대학교 대학원 토목공학과)
Kim, Jeong Hwan (한양대학교 대학원)
Park, Joo Yang (한양대학교 건설환경공학과)
Publication Information
KSCE Journal of Civil and Environmental Engineering Research / v.31, no.4B, 2011 , pp. 377-382 More about this Journal
Abstract
In this study, hydrogen peroxide is stabilized in modified Fenton reaction to improve the soil remediation. Phenanthrene, which is the typical compound in PAHs, was spiked into soil samples to copy the original contaminated site. Anionic surfactant, SDS (Sodium dodecyl sulfate) was used for hydrogen peroxide stabilizer. 4 mM of Fe(II), 5~50 mM of SDS and 102.897 mM of $H_2O_2$ was injected into soil samples which is contaminated by 125 mg/kg of phenanthrene to analyze decomposition rate of phenanthrene in modified Fenton reaction. In condition which SDS was injected 30 mM, decomposition rate of phenanthrene has best efficiency as 95% and in condition which SDS was injected over 30 mM, decomposition rate is lower than SDS 30 mM because SDS enacted as scavenger in the system. Results which assess the change of hydrogen peroxide concentration after injecting hydrogen peroxide stabilizer showed that hydrogen peroxide concentration was 14.6995 mM so that is stabilized at Fe(II) 2 mM condition in 48 hours. On the other hand, hydrogen peroxide is not stable in Fe(III) condition. SDS concentration was fixed and iron concentration was changed 2~8 mM to find out optimize proportion between iron concentration and SDS concentration in modified Fenton reaction. Consequentially, in condition of which Fe(II) 4 mM and SDS 30 mM, reaction has the highest removal rate as 95%.
Keywords
hydrogen peroxide stabilizer; modified fenton reaction; surfactant; SDS; phenanthrene;
Citations & Related Records
연도 인용수 순위
  • Reference
1 김정환, 최영무, 김정환, 박주양(2007) Phenanthrene의 goethite 촉매에 의한 Fenton 산화에 있어서 음이온/비이온 및 혼합 계면활성제의 영향. 대한환경공학회.한국대기환경학회.한국폐기물학회 공동학술대회 논문집, 한국폐기물학회, P025, pp. 2545-2548.
2 김정환, 최원호, 김정환, 박주양(2009) Phenanthrene의 goethite 촉매에 의한 Fenton 산화에 있어서 음이온/비이온 계면활성제의 영향. 대한토목학회논문집, 대한토목학회, 제29권 제2B호, pp. 207-212.
3 박준석(2006) 펜톤산화 공정을 이용한 난분해성 오염토양의 처리. 지반환경공학회지, 한국지반환경공학회, 제7권 제2호, pp. 28- 33.
4 Ananthula, Rajeshwar., Takahiro Yamada, Philip H. Taylor (2007) Kinetics of oh radical reaction with phenanthrene : New Absoulute Rate Measurements and Comparison with Othe PAHs, International Journal of Chemical Kinetics, Vol. 39, pp. 629-637.   DOI   ScienceOn
5 Ang, Carolina C. and Abdul S. Abdul (1991) Aqueous Surfactant washing of residual oil contamination from sandy soil. Ground Water Monitoring and Remediation, Vol. 11, Issue 2, pp. 121- 127.   DOI
6 Bielski, B.H.J. and Allen, A.O. (1977) Mechanism of the disproportionation of superoxide radicals. J. Phys. Chem. Vol. 81, No. 11, pp. 1048-1050.   DOI
7 Barbeni, M., Minero, C., and Pelizzetti, E. (1987) Chemical degradation of chlorophenols with Fenton's reagent $(Fe^{2+} + H_{2}O_{2})$. Chemosphere, Vol. 16, pp. 22-25.
8 Beak, S.O., Field, R.A., Goldstone, M.E., Kirk, P.W., Lester, J.N., and Perry, R. (1991) A review of atmospheric polycyclic aromatic hydrocarbons; Source, fate and behavior. Water, Air & Soil Pollution, Vol. 60, No. 3-4, pp. 279-300.   DOI
9 Berardescok, G., Dyhman, S., Gallagher, E., and Shiaris, M.P. (1998) Spatial and temporal variation of phenanthrene degrading bacteria in intertidal sediments. Appl. Environ. Microbial, Vol. 64, No. 7, pp. 2560-2565.
10 Blumer, M., Blumer, W., and Reich, T. (1997) Polycyclic aromatic hydorcarbons in soil of a mountain valley: correlation with highway traffic and cancer incidence. Environ. Sci. Technol., Vol. 11, No. 12, pp. 1082-1084.
11 C. von Sonntag (2006) Free-radical-induced DNA damage and its repair: A Chemical Perspective. Springer, Berlin, pp. 357-481.
12 Goi., A., Veressinina, Y., and Trapido, M. (2008) Degradation of salicylic acid by Fenton and modified Fenton treatment. Chemical Engineering Journal, Vol. 143, Issues 1-3, pp. 1-9.   DOI
13 Eisenberg, G.M. (1943) Colorimetric determination of hydrogen peroxide, Industrial and Engineering Chemistry, Vol. 15, No. 5, pp. 327-328.
14 Lauren, L., Bissey, Jeffrey, L., Smith and Richard, J. Watts (2006) Soil organic matter-hydrogen peroxide dynamics in the treatment of contraminated soils and groundwater using catalyzed $H_{2}O_{2}$ propagation (modified Fenton's reagent). Water Research. Vol. 40, Issue 13, pp. 2477-2484.   DOI   ScienceOn
15 Johnsen, Anders, R., Lukas, Y. Wick and Hauke Harms (2005) Principles of microbial PAH-degradation in soil. Envrionmental Pollution, Vol. 133, pp. 71-84.   DOI   ScienceOn
16 Kiwi, J., Lopez, A., and Nadtochenko, V. (2000) Mechanism and Kinetics of the OH- radical intervention during Fenton Oxidationin the Presence of a Significant Amount of Radical Scavenger (Cl-). Envrion. Sci. Technol., Vol. 34, No. 11, pp. 2162- 2168.   DOI   ScienceOn
17 Laflamme, R.E. and Hites, R.A. (1978) The global distribution of polycyclic aromatic hydrocarbons in recent sediments, Geochimica et Cosmochimica Acta., Vol. 42, Issue 3, pp. 289-303.   DOI   ScienceOn
18 Lin, Sheng H., Chi, M. Lin, and Horng, G. Leu (1999) Operating characteristics and kinetic studies of surfactant wastewater treatment by Fenton oxidation. Wat. Res., Vol. 33, No. 7, pp. 1735-1741.   DOI   ScienceOn
19 Lin, J.-M., Nakagawa, M., Uchiyama, M., and Hobo, T. (1999) Determination of Critical Micelle Concentration of SDS in Formamide by Capillary Electrophoresis. Chromatographia, Vol. 50, No. 11/12, pp. 739-744.   DOI
20 Martens, Dean A. and William T. Frankenberger, Jr (1995) Enhanced degradation of polycyclic aromatic hydrocarbons in soil treatment with an advanced oxidative process - Fenton's reagent, Journal of Soil Contamination, Vol. 4, No. 2, pp. 175-190.   DOI
21 Morillo, E., Romero, A.S., Maqueda, C., Madrid, L., Ajmone-Marsan, F., Grcman, H., Davidson, C.M., Hursthouse, A.S., and Villaverde, J. (2007) Soil Pollution by PAHs in urban soils : a comparison of three European cities. J. Environ. Monit., Vol. 9, pp. 1001-1008.   DOI   ScienceOn
22 Stull, Daniel R. (1947) Vapor pressure of pure substnaces organic compounds. Industrial and Engineering chemistry, Vol. 39, No. 4, pp. 517-540.   DOI
23 Murphy, A.P., Boegli, W.J., Price, M.K., and Moody, C.D. (1989) A Fenton-like reaction to neutralize formaldehyde waste solutions. Environ. Sci. Technol., Vol. 23, No. 2, pp. 166-169.   DOI   ScienceOn
24 Rickabaugh, J., Clement, S., Martin, J., Sunderhaus, M., Lewis, R.F. (1986) Chemical and microbial stabilization techniques for remedial action sites. proceedings of the Twelfth annual reaserch symposium, EPA/600/9-85/022, pp. 193.
25 Sedlack, D.L. and Andren, A.W. (1991) Aqueous-Phase oxidation of polychlorinated biphenyls by hydroxil radicals. Environ. Sci. Technol., Vol. 25, pp. 1419-1427.   DOI
26 Tyre, B.W., Watts, R.J., and Miller, G.C., (1991) Treatment of four biorefractory contaminates in soils using catalyzed hydrogen peroxide, J. Environ. Qual., 20, pp. 832-838.
27 Watts, R.J., Udell, M.D., Rauch, P.A., and Leung, S.W. (1990) Treatment of pentachlorophenol-contaminated soils using Fenton's reagent. Hazardous Waste and Hazardous Materials, Vol. 7, No. 4, pp. 335-345.   DOI
28 Watts, R.J., Dennis, D. Finn, Lynn, M. Cutler, Jeremy, T. Schmidt, and Amy, L. Teel. (2007) Enhanced stability of hydrogen peroxide in the presence of subsurface solids. Journal of Contaminant Hydrology, Vol. 91, Issues 3-4, pp. 312-326.   DOI   ScienceOn
29 Wilcke, Wolfgang (2000) Polycyclic Aromatic Hydrocarbons (PAHs) in Soils - A Review. J. Plant Nutr. Soil Sci., Vol. 163, pp. 229- 248.   DOI
30 Chu, W. (2003) Remediation of contaminated soils by surfactantaided soil washing. Pract. Periodical of Haz., Toxic, and Radioactive Waste Mgmt., Vol. 7, Issue 1. pp. 19-24.
31 Yeom, Ick tae, Mriganka M. Ghosh and Chris D. Cox (1996) Kinetics Aspects of Surfactant Solubilization of Soil-Bound Polycyclic Aromatic Hydrocarbons. Environ. Sci. Technol., Vol. 30, No. 5, pp. 1589-1595.   DOI   ScienceOn
32 Zhao, Baowei, Lizhong Zhu, Wei Li and Baoliang Chen (2005) Solubilization and biodegradation of phenanthrene in mixed anionic-nonionic surfactant solution. Chemosphere, Vol. 58, pp. 33-40.   DOI   ScienceOn
33 Yunfu Sun and Joseph J. Pignatello. (1993) Activation of Hydrongen Peroxide by Iron(III) chelates for Abiotic Degradation of Herbicides and Insecticides in Water. J. Agric. Food Chem., 41, pp. 308-312.   DOI