• 대한본초학회지
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• 제28권6호
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• pp.111-117
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• 2013

Objectives : This research aimed at studying the immuno modulating activity of Fermented Epimedii Herba (EHS). Method : The impacts on the cell viability, hydrogen peroxide and nitric oxide (NO) generation in cells, and cytokines such as tumor necrosis factor-alpha (TNF-${\alpha}$), interleukin (IL)-6, IL-$1{\beta}$, monocyte chemoattractant protein-1 (MCP-1) level have been measured by using Raw 264.7 cells with the specimen EHS as the fermented extract of Epimedii Herba with Saccharomyces cerevisiae STV89. Result : As a result of MTT assay to confirm the cytotoxicity of extracts from fermented Epimedii Herba, the toxicity was not excessively induced in Raw 264.7 cells when EHS were processed by concentration. EHS increased hydrogen peroxide generation in Raw 264.7 cells. EHS suppressed NO generation in Raw 264.7 cells while they significantly suppressed the increase of NO generation induced by LPS in macrophage. EHS significantly decreased the generation amount of TNF-${\alpha}$ and IL-6 induced by LPS in Raw 264.7 cells at $25{\mu}g/mL$ or more. Conclusion : It appeared that the fermented extract of Epimedii Herba manufactured from Epimedii Herba significantly has the immuno modulating acitivity as it did not excessively trigger cytotoxicity to Raw 264.7 cells, increased hydrogen peroxide generation in Raw 264.7 cells, decreased NO generation in macrophage, and especially, suppressed both TNF-${\alpha}$ and IL-6 generation in macrophage induced by LPS.

• Journal of Dairy Science and Biotechnology
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• 제22권2호
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• pp.107-112
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• 2004

과산화수소 형태의 반응성 산소에 대한 Lactobacillus Spp., Bifidobacterium spp. 및 Bacillus coagulans의 저항성과 세포 내에서 생성능력을 측정하기 위하여 본 연구가 수행되었다. Lactobacillus spp. 중에서 높은 과산화수소 저항성을 나타낸 균주는 L. acidophilus CU4111와 L. casei Cu4114인 것으로 나타났고 가장 낮은 저항성을 보인 균주는 L. brevis Cu4206이었다. Bifidobacterium longum CU4131은 높은 수준의 저항성을 나타내며 Bacillus coagulans를 포함하는 포자형성유산균주들은 전반적으로 과산화수소에 대한 저항성 이 높은 것으로 나타났다. 세포질 추출액 중의 과산화수소 함유 농도는 Bifidobacterium bifidum CU 4134가 가장 높고 Lactobacilli spp.의 세포질 추출액 중의 과산화수소 함유 농도는 L. casei CU 4114가 가장 높은 것으로 나타났다.

• 한국수소및신에너지학회논문집
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• 제34권6호
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• pp.555-561
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• 2023

In this study, we proposed a standard model for the design, construction and demonstration of the technology development and substantiation of small hydrogen powered vessel in order to respond to the alternative fuel-using vessel market that requires the use of low-carbon/carbon-free fuel as a greenhouse gas reduction measure. The hydrogen fuel cell-based electric propulsion system developed through this is optimized through performance and durability tests on the land-based test site (LBTS), and the electric propulsion system applied to this result is mounted on a small hydrogen propulsion vessel and operated. Simultaneously, through the digital twin technology between the LBTS and the hydrogen-propelled vessel on the sea, the technology that can predict and diagnose the problems that can occur in the electric propulsion system of the vessel is applied to carry out the empirical study of the hydrogen-propelled vessel. In addition, we propose a commercialization model by analyzing the economic feasibility of the demonstration vessel.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.57-60
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• 2008

KEPRI has studied planar type SOFC stacks using anode-supported single cells and kW class co-generation systems for residential power generation. A 1kW class SOFC system consisted of a hot box part, a cold BOP part and a water reservoir. A hot box part contains a SOFC stack made up of 48 single cells and ferritic stainless steel interconnectors, a fuel reformer, a catalytic combustor and heat exchangers. Thermal management and insulation system were especially designed for self-sustainable operation. A cold BOP part was composed of blowers, pumps, a water trap and system control units. When a 1kW class SOFC system was operated at $750^{\circ}C$ with hydrogen after pre-treatment process, the stack power was 1.2kW at 30 A and 1.6kW at 50A. Turning off an electric furnace, the SOFC system was operated using hydrogen and city gas without any external heat source. Under self-sustainable operation conditions, the stack power was about 1.3kW with hydrogen and 1.2kW with city gas respectively. The system also recuperated heat of about 1.1kW by making hot water.

• 전기학회논문지
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• 제57권9호
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• pp.1599-1605
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• 2008

The research was conducted in order to improve the hydrogen generation efficiency of the electrical plasma technology from tap water by using $TiO_2$ photocatalyst, mixed Cu - $TiO_2$ powder, and mixed Ni - $TiO_2$ powder as the catalysts. Experiments were performed with the pulsed power and nitrogen carrier gas. The result has shown that the hydrogen concentration with the presence of $TiO_2$ powder was created higher than that of without using photocatalyst. The hydrogen concentration with using $TiO_2$ was 3012ppm corresponding to the applied voltage of 16kV, while it without using the $TiO_2$ was 1464ppm at the same condition . The effect of $TiO_2$ powder was strongly detected at the applied voltages of 15kV and 16kV. This phenomena might be resulted from the co-effect of the pulsed power discharge and the activated state of $TiO_2$ photocatalyst. The co-effect of the mixed catalysts such as Cu-$TiO_2$ and Ni-$TiO_2$ (the mixed photocatalyst $TiO_2$ and transition metals) were also investigated. The experimental results showed that, Cu and Ni powder dopants were greatly enhancing the activity of the $TiO_2$ photocatalyst. Under these experimental conditions the extremely high hydrogen concentrations at the optimal point were produced as 4089ppm and 6630ppm, respectively.

• 한국수소및신에너지학회논문집
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• 제32권6호
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• pp.506-513
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• 2021

The use of fossil fuels is a major contributor to the increase atmospheric greenhouse gas emissions. As such problems arise, interest in new and renewable energy devices, particularly fuel cells, is greatly increasing. In this study, various characteristics of mixed strains were observed in wastewater collected by the Jeonju Environment Office to investigate the effects of microorganisms on voltage generation and voltage generation of substrates, electrode materials, electrons, electron transport media, and ash microbial fuel cells. As a result of separately measuring the voltage generated during inoculation, the inoculation voltage of Escherichia coli K12 (E. coli K12) was 0.45 V, and the maximum inoculation voltage of the mixed strain was 1.2 V. Thereafter, voltage values were collected using a digital multimeter and the amount of voltage generated over time was measured. In the case of E. coli K12, the maximum voltage reached 0.45 V, and the cell voltage was maintained above 0.23 V for 140 hours. In contrast, for the mixed strain, the maximum voltage reached 1.2 V and the voltage was slowly decreased to 0.97 V. In addition, the degree of microbial adsorption to the electrod surface after the inoculation test was confirmed using a scanning electron microscope. Therefore, these results showed the possibility of purifying pollutants at the same time as power generation through the production of hydrogen ions using microorganisms and wastewater.

• Bulletin of the Korean Chemical Society
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• 제32권12호
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• pp.4366-4370
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• 2011

A simple, green and cost-effective protocol was used for the aromatization of 1,3,5-trisubstituted-2-pyrazolines to the corresponding pyrazoles by in situ generation of iodine ($I^+$) from $H_2O_2$/AcOH or SSA or oxalic acid /KI or NaI system under thermal condition with moderate to good yields.

• 한국지하수토양환경학회지:지하수토양환경
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• 제6권1호
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• pp.3-12
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• 2001

오존산화공정에서 수산화라디칼(OH.)의 생성속도가 다양한 실험조건(오존의 주입농도, 니트로벤젠의 농도, scavenger, pH, 과산화수소)에서 측정되었다. 니트로벤젠은 오존과의 직접적인 반응보다는 수산화라디칼에 의해 분해되었으며 분해속도는 오존과 니트로벤젠의 농도의 함수로 표현되었다. 또한 수산화라디칼 scavenger의 농도가 증가할수록 반응속도는 감소하였다. 실험상에서 얻은 모든 결과는 일차반응속도식을 따랐다. Probe compound와 scavenger를 이용한 경쟁적 방법을 사용하여 수산화라디칼을 측정하였는데, 그 결과 수산화라디칼의 생성속도는 오존의 농도에 선형적으로 비례하였으며, 오존 1몰당 수산화라디칼은 0.24몰이 생성되었다. 동일 오존농도에서 pH의 변화에 따른 수산화라디칼의 생성속도가 측정되었으며, (pH 10.2 ($0.91Ms^{-1}$) > pH 7.3($0.72Ms^{-1}$) > pH 5.6($0.67Ms^{-1}$) > pH 3.4($0.63Ms^{-1}$)) 중성이하의 pH에서보다 알칼리성 pH에서 수산화라디칼은 많이 발생됨을 알 수 있다. 또한 과산화수소의 첨가도 수산화라디칼의 생성속도를 증진시키는 결과를 낳았다. pH의 조절과 과산화수소의 첨가시 발생속도를 비교해보면 과산화수소를 첨가했을 때 수산화라디칼의 발생속도는 1.6배정도 더 크게 측정되었는데 이는 수산화라디칼을 발생시키는 데 있어서 과산화수소의 첨가가 pH의 조절보다는 더 좋은 증진제로써 작용할 수 있다는 것을 설명해준다. 이러한 결과들은 오염된 토양이나 지하수를 처리하기 위한 오존을 이용한 고급산화공정에 충분히 적용될 수 있을 것이라 판단된다.

• 한국수소및신에너지학회논문집
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• 제24권5호
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• pp.353-358
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• 2013

To develop preferential CO oxidation reaction (PROX) catalyst for small scale hydrogen generation system, supported Pt catalysts have been applied for the target reaction. The supports were systematically changed to optimize supported Pt catalysts. $Pt/Al_2O_3$ catalyst showed the highest CO conversion among the catalysts tested in this study. This is due to easier reducibility, the highest dispersion, and smallest particle diameter of $Pt/Al_2O_3$. It has been found that the catalytic performance of supported Pt catalysts for PROX depends strongly on the reduction property and depends partly on the Pt dispersion of supported Pt catalysts. Thus, $Pt/Al_2O_3$ can be a promising catalyst for PROX for small scale hydrogen generation system.

• 전기화학회지
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• 제10권4호
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• pp.235-238
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• 2007

과산화수소의 발생은 일반적으로 유기 산화제를 포함한 산업적 프로세스의 넓은 분야에 응용된다. 과산화수소는 펄프와 제지 공업의 기계적, 화학적 처리를 위하여 사용되고 염소를 기초로 둔 화학제품에 알칼리 처리로 사용된다. 본 연구에서는 Nafiom과 러시아 양이온 교환막인 MK-40, 제조된 SPEEK막을 가스확산전극이 포함된 과산화수소 발생용 전해 셀에서 비교 실험한다. 다른 양성자 교환막에 효과에 따른 과산화수소 발생의 전기화학적 셀의 전압과 전류 효율, 에너지 소모를 연구한다.