• Title/Summary/Keyword: hydrate change

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Evaluation of energy consumption of gas hydrate and reverse osmosis hybrid system for seawater desalination (해수담수화 공정을 위한 가스하이드레이트-역삼투 공정의 에너지 소모량 평가)

  • Ryu, Hyunwook;Kim, Minseok;Lim, Jun-Heok;Kim, Joung Ha;Lee, Ju Dong;Kim, Suhan
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.4
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    • pp.459-469
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    • 2016
  • Gas hydrate desalination process is based on a liquid to solid (Gas Hydrate, GH) phase change followed by a physical process to separate the GH from the remaining salty water. The GH based desalination process show 60.5-90% of salt rejection, post treatment like reverse osmosis (RO) process is needed to finally meet the product water quality. In this study, the energy consumption of the GH and RO hybrid system was investigated. The energy consumption of the GH process is based on the cooling and heating of seawater and the heat of GH formation reaction while RO energy consumption is calculated using the product of pressure and flow rate of high pressure pumps used in the process. The relation between minimum energy consumption of RO process and RO recovery depending on GH salt rejection, and (2) energy consumption of electric based GH process can be calculated from the simulation. As a result, energy consumption of GH-RO hybrid system and conventional seawater RO process (with/without enregy recovery device) is compared. Since the energy consumption of GH process is too high, other solution used seawater heat and heat exchanger instead of electric energy is suggested.

A study on Intraparticle Diffusivity for Adsorptive Removal of Orthophosphate Ion by the Ziriconium Oxide Hydrate-Activated Carbon Complex (산화질리코늄수화물-활성탄 복합체에 의한 오르토인산이온의 흡착제거에서 입자내 확산계수에 관한 연구)

  • 김성빈;김성근
    • Journal of the Korean Graphic Arts Communication Society
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    • v.6 no.1
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    • pp.75-86
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    • 1988
  • This is a experiment about change of highlight point by HBU and HLM of auxiliary function of gradation in color scanner. The result of change - over by HBU and HLM are summerized as follows. Therefore, the determination for the effective point and the amount of HBU and HLM are decided by the Table 1 and Table 2.

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Characterization of the Chemical Mechanical Micro Machining for Single Crystal Silicon (실리콘의 화학기계적 미세가공 특성)

  • Jeong, Sang-Cheol;Park, Jun-Min;Lee, Hyeon-U;Jeong, Hae-Do
    • Journal of the Korean Society for Precision Engineering
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    • v.19 no.1
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    • pp.186-195
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    • 2002
  • The mechanism of micro machining of reacted layer on silicon surface were proposed. The depth of reacted layer and the change of mechanical property were measured and analyzed. Depth of hydrated layer which is created on the surface of silicon by potassium hydrate was analyzed with SEM and XPS. The decrease of the micro victors hardness of silicon surface was shown with the increase of the concentration of potassium hydrate and the change of the dynamic friction coefficient by chemical reacted layer was measured due to the readiness of machining. The experiment of groove machining was done with 3-axis machine with constant load. With chemical mechanical micro machining the surface crack and burrs generated by both brittle and ductile micro machining were diminished. And the surface profile and groove depth was shown in accordance with the machining speed and reaction time with SEM and AFM.

Gas Hydrate (가스 하이드레이트)

  • Ryu Byong-Jae
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.609-614
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    • 2005
  • Gas hydrates are ice-l ike sol id compounds that are composed of water and natural gas. All common gas hydrates belong to the three crystal structures that are composed of five polyhedral cavities formed by hydrogen bonded water molecules and stable in specific high pressure and low temperature conditions. Gas hydrates contain large amounts of organic carbon and widely occur in deep oceans and permafrost regions, and they may therefore represent a potential energy resource in the future. United States and Japan perform the national R&D programs for the commercial production of gas hydrates in 2010's. The study on gas hydrates are also important for exploration and development of natural gas in the regions where gas hydrates are accumulated and could be formed. Although their global abundance is debated, they play an important role in global climate change since methane is a 50 times more effect ive greenhouse gas than carbon dioxide. Natural gas hydrates also form a possible natural hazard if rapidly dissociated and can cause slides and slumps and in the marine environment associated tsunamis.

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Fine Structural Change of PET Film Treated with Hydrazine Hydrate in Methanol (Hydrazine/Methanol 처리에 의한 PET Film의 미세구조의 변화)

  • Sung, Woo-Kyung;Cho, Hyun-Hok;Kim, Kyung-Hwan
    • Textile Coloration and Finishing
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    • v.2 no.2
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    • pp.1-6
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    • 1990
  • In order to investigate the fine structural changes of poly (ethylene terephthalate) film by hydrazinolysis, PET was treated with hydrazine hydrate in methanol at $30^{\circ}C$ for various times. Initially apparent crystallite size and degree of orientation are increased and then, gradually decreased with hydrazinolysis. According to thermoluminescence measurement, trap site decreased by dissolution and then gradually increased with growth of defect in structure. Maximum peak temperature of tan and dynamic loss modulus E" upon hydrazinolysis shifted to the lower temperature in the progress of hydrazinolysis.ysis.

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Reaction Products and Properties of Clay Mixed with Lime (점토와 석회의 혼합에 의한 반응생성물과 물성변화)

  • 김병규;황진연
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.03a
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    • pp.505-512
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    • 1999
  • Soft marine clay deposits pose several foundation problems. Generally, lime stabilization is used worldwide for solidifying of soft marine clay deposits. In this paper, a series of laboratory tests were conducted to verify clay-lime reaction. A clay was collected from Pusan, which was mixed with various quantities of quick lime and slaked lime. Various compounds produced by clay-lime reaction were identified by X-ray diffraction analysis. The physico-chemical properties of the clay were also investigated. Compounds such as calcium silicate hydrate (CSH), calcium aluminate hydrate (CAH), calcium aluminate (CA), hillebrandite, and gehlenite were identified. It is likely that such compounds were mainly produced by pozzolanic reaction. Based on the change of physico-chemical properties obtained by the reaction, the water content was considerably decreased when lime was added to the clay. In addition, unconfined strength was increased. In the other hand, quick lime was more effective than slaked lime in decreasing and increasing of the water content and unconfined strength, respectively. Fewer cracks were produced when the clay was mixed with quick lime. It is suggested that these beneficial changes produced by the mixing of the clay and lime depend on the properties of compounds obtained by chemical reaction.

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Characteristics of Microbial Community Structures of the Methane Hydrate Sediments in the Ulleung Basin, East Sea of Korea (동해 울릉분지 메탄 하이드레이트 퇴적토의 미생물 군집 특성)

  • Shin, Ji-Hye;Nam, Ji-Hyun;Lee, Jin-Woo;Lee, Dong-Hun
    • Korean Journal of Microbiology
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    • v.50 no.3
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    • pp.191-200
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    • 2014
  • Gas hydrates play a significant role in the global carbon cycle and climate change because methane, a greenhouse gas, can be released from the dissociation of gas hydrate. Anaerobic oxidation of methane (AOM) is an important process that consumes more than 90% of the methane released into the hydrosphere and atmosphere. In this study, the microbial community associated with the methane gas hydrate sediment in the Ulleung basin, East Sea of Korea (UBGH) was analyzed by phylogenetic analysis of the mcrA and 16S rRNA gene libraries. A vertical stratification of the dominating anaerobic methane oxidizer (ANME)-1 group was observed at the surface and the sulfate methane transition zone (SMTZ). The ANME-2c group was found to be dominant in the high methane layer. The archaea of marine benthic group B, which is commonly observed in the AOM region, accounted for more than 50% of the identifications in all sediments. Nitrate reducing bacteria were predominant at SMTZ (Halomonas: 56.5%) and high methane layer (Achromobacter: 52.6%), while sulfate reducing bacteria were not found in UBGH sediments. These results suggest that the AOM process may be carried out by a syntrophic consortium of ANME and nitrate reducing bacteria in the gas hydrates of the Ulleung Basin of the East Sea.

A Study on the Early-Age Strength Property of Concrete Using Liquid Admixture (액상형 조강제를 사용한 콘크리트의 초기강도 특성에 관한 연구)

  • Song, Tae-Hyeob;Lee, Sea-Hyun;Ryu, Deug-Hyun;Park, Cho-Bum
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.469-472
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    • 2006
  • Amount used of admixture fare is increasing for concrete economic efficiency and ability security. Security of economic efficiency and ability can expect by use of this admixture fare but is displaying a lot of problems on early age strength hold by hydrate delay relatively. Specially, in the case of construction site, concrete strength can speak that interrelation is high with mold removal of forms time. Therefore, is economical and need examination of plan that can secure robber within 3 days using admixture fare such as fly ash and blast furnace slage differential speech to secure function. In this study, adding liquid admixture within 1% of a binding agent quantity to examine these problem with physical characteristic after hardening ago specially, strength change at standard and air dry curing of observed change in priority. Air dried and water curing total strength enhancement effects appeared by thing which is in case of add test result liquid admixture by below 1% and strength deputy by passage of age could know is not big.

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Shrinkage Strain Property of the Magnesium Oxide Matrix According to Magnesium Chloride Addition Ratio (염화마그네슘 첨가율에 따른 산화마그네슘 경화체의 길이변화 특성)

  • Jung, Byeong-Yeol;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.150-151
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    • 2013
  • Recently, the internal space organization of the building changes to the frame construction and flat slab construction in the wall type structure. And the use of light weight panel changing the internal joint use easily is increased. Therefore, in this research, the length change characteristic that the magnesium chloride addition rate reaches to the magnesium curing body tries to be studied. It could confirm according to the length change specific result that the magnesium chloride amount of addition reaches to the magnesium oxide curing body to expand. And the thing described below was the large-scale expansion the magnesium oxide addition rate 60%. And it showed up as 50, 40, 30, 20, and order of 10s (%). It could look at to form the hydrate of the SEM picture result needle-shaped of the Hardened.

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Changes in Cement Hydrate Characteristics and Chloride Diffusivity in High Performance Concrete with Ages (재령에 따른 고성능 콘크리트의 수화 특성치와 염화물 확산성 변화)

  • Koh, Tae-Ho;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.6
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    • pp.9-17
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    • 2019
  • Cement hydrates and the related characteristics change with ages, and the behaviors are much related with chloride diffusion. In this work, 30% replacement ratio with FA(Fly Ash) and GGBFS(Ground Granulated Blast Furnace Slag) are considered for concrete with three levels of W/B (Water to Binder ratio) and 2 years of curing period. Chloride diffusion coefficients from accelerated condition are obtained at 5 measurement period (28days, 56days, 180days, 365days, and 730days), and the results are compared with porosity, binding capacity, and permeability from program-DUCOM. The similar changing pattern between chloride diffusion and permeability is observed since permeability is proportional to the square of porosity. Curing period is grouped into 4 periods and the changing ratios are investigated. Cement hydrate characteristics such as porosity, permeability, and diffusion coefficient are dominantly changed at the early ages (28~56 days), and diffusion coefficient in OPC concrete with low W/B continuously changes to 180days.