• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2015년도 제46회 하계학술대회
• /
• pp.1038-1039
• /
• 2015

미니트램(Mini-Tram)의 에너지 공급시스템은 유도급전(IPT: Inductive Power Transfer) 기반의 무선급속충전(Wireless High Speed Charging) 및 슈퍼커패시터(Supercapacitor) 기술을 융합하여 구성되었다. 기존의 전기이중층 커패시터(EDLC) 및 하이브리드 커패시터(LIC)는 급속충전을 위한 출력성능은 충족하지만, 낮은 에너지밀도 때문에 미니트램의 활용성을 제한하고 있다. 이에 수송시스템 분야에서의 커패시터의 경쟁력을 향상하기 위해서는 최소한의 공간 및 무게 조건을 충족함과 동시에 에너지 밀도를 극대화할 수 있는 하이브리드 커패시터의 개발이 요구된다. 본 논문에서는 개발 중인 미니트램의 에너지 요구량을 산정하여 매체의 개발목표 사양을 도출하고 이를 실현하기 위한 방안에 대해서 논하고자 한다.

• Journal of Ceramic Processing Research
• /
• 제13권spc1호
• /
• pp.154-157
• /
• 2012

We present the simultaneous growth of single-walled carbon nanotubes and graphene with the optimal conditions of the synthesizing parameters. The dense and vertically aligned SWNTs having the length of over 100 ㎛ was grown by 2 nm-thick Fe catalytic layer. From 650 ℃, the vertically well-grown SWNTs were obtained by increasing the temperature. The severallayered graphene was synthesized with the gas mixing ratio of 15 : 1(H2 : C2H2) at 650 ℃ and higher temperatures. With these optimal conditions, the vertically well-grown SWNTs and the several-layered graphene were synthesized simultaneously. The presence of SWNTs and the layer of graphene were verified by field emission scanning electron microscopy and high resolution transmission electron microscopy. From the result of this simultaneous synthesizing approach, the possibility of one step growth process of CNTs and grapheme could be verified.

• Bulletin of the Korean Chemical Society
• /
• 제26권11호
• /
• pp.1653-1668
• /
• 2005

Assembly of hybrid mesophases through the combination of amphiphilic block copolymers, acting as structuredirecting agents, and silicon sources using low acid catalyst concentration regimes is a versatile strategy to produce large quantities of high-quality ordered large-pore mesoporous silicas in a very reproducible manner. Controlling structural and textural properties is proven to be straightforward at low HCl concentrations with the adjustment of synthesis gel composition and the option of adding co-structure-directing molecules. In this account, we illustrate how various types of large-pore mesoporous silica can easily be prepared in high phase purity with tailored pore dimensions and tailored level of framework interconnectivity. Silica mesophases with two-dimensional hexagonal (p6mm) and three-dimensional cubi (Fm$\overline{3}$m, Im$\overline{3}$m and Ia$\overline{3}$d) symmetries are generated in aqueous solution by employing HCl concentrations in the range of 0.1−0.5 M and polyalkylene oxide-based triblock copolymers such as Pluronic P123 $(EO_{20}-PO_{70}-EO_{20})$ and Pluronic F127 $(EO_{106}-PO_{70}-EO_{106})$. Characterizations by powder X-ray diffraction, nitrogen physisorption, and transmission electron microscopy show that the mesoporous materials all possess high specific surface areas, high pore volumes and readily tunable pore diameters in narrow distribution of sizes ranging from 4 to 12 nm. Furthermore, we discuss our recent advances achieved in order to extend widely the phase domains in which single mesostructures are formed. Emphasis is put on the first synthetic product phase diagrams obtained in $SiO_2$-triblock copolymer-BuOH-$H_2O$ systems, with tuning amounts of butanol and silica source correspondingly. It is expected that the extended phase domains will allow designed synthesis of mesoporous silicas with targeted characteristics, offering vast prospects for future applications.

• 한국세라믹학회지
• /
• 제51권3호
• /
• pp.162-169
• /
• 2014

This paper introduces a microwave-assisted synthesis method to prepare hybrid $Bi_2Se_3-GR/TiO_2$ nanocomposites, which exhibit superior properties over single component materials. The as-prepared composites were characterized by XRD, UV-vis absorbance spectra, SEM,TEM, EDX, and BET analyses, revealing uniform covering of the graphene nanosheet with $Bi_2Se_3$ and $TiO_2$ nanocrystals. For visible light photocatalysis of Rh.B, a significant enhancement in the reaction rate was consequently observed with $Bi_2Se_3-GR/TiO_2$ composites. The degradation rate($k_{app}$) obtained for sonophotocatalysis was $6.8{\times}10^{-3}min^{-1}$, roughly 2.2 times better than that of VL photocatalysis under higher concentrations of Rh.B. The sonophotocatalysis was faster due to greater formation of reactive radicals as well as an increase of the active surface area of the $Bi_2Se_3-GR/TiO_2$ composites. The high activity is attributed to the synergetic effects of high charge mobility and red shift of the absorption edge of $Bi_2Se_3-GR/TiO_2$.

• Composites Research
• /
• 제24권6호
• /
• pp.25-30
• /
• 2011

본 연구에서는 유리섬유, 탄소섬유 및 유리섬유-탄소섬유 복합재에 MWCNT층을 삽입하는 경우 복합재의 전자파차폐 물성에 대한 연구를 수행하였다. 유리섬유 복합재의 경우, $200mm{\times}200mm$ 면적에 0.1~0.2 g의 MWCNT를 도포했을 때 (1.8~3.6 ${\mu}m$ 두께) 전자파차폐효과가 현격히 증가함을 발견하였다. 아울러, 두개 이상의 MWCNT층을 삽입하는 경우, 이들을 분산배치 하는 것 보다는 복합재 중앙에 집중배치 하는 것이 더 효과적이었다. 반면, 탄소섬유 및 유리섬유-탄소섬유 복합재의 경우, MWCNT층이 전자파차폐효과에 영향을 미치지 않음을 알 수 있었다. MWCNT를 비롯한 탄소나노소재를 전자파차폐용 소재로 효과적으로 활용하기 위해서는, 탄소나노소재의 첨가에 의한 다양한 전자파차폐 메커니즘 간 상관관계를 이해하는 것이 중요하다.

• Macromolecular Research
• /
• 제15권1호
• /
• pp.65-73
• /
• 2007

Chitosan, fibroin, and hydroxyapatite are natural biopolymers and bioceramics that are biocompatible, biodegradable, and resorb able for biomedical applications. The highly porous, chitosan-based, bioceramic hybrid composite, chitosanlfibroin-hydroxyapatite composite, was prepared by a novel method using thermally induced phase separation. The composite had a porosity of more than 94% and exhibited two continuous and different morphologies: an irregularly isotropic pore structure on the surface and a regularly anisotropic multilayered structure in the interior. In addition, the composite was composed of an interconnected open pore structure with a pore size below a few hundred microns. The chemical composition, pore morphology, microstructure, fluid absorptivity, protein permeability, and mechanical strength were investigated according to the composition rate of bioceramics to biopolymers for use in tissue engineering. The incorporation of hydroxyapatite improved the fluid absorptivity, protein permeability, and tenacity of the composite while maintaining high porosity and a suitable microstructure.

• 한국전기전자재료학회논문지
• /
• 제27권9호
• /
• pp.571-575
• /
• 2014

We synthesized new materials of $Zn(HPB)_2$ and Ir-complexes as blue or red emitting material. We fabricated white Organic Light Emitting Diodes (OLED) by using $Zn(HPB)_2$ for the blue emitting layer, Ir-complexes for the red emitting layer and $Alq_3$ for the green emitting layer. We fabricated white OLED by using double emitting layers of $Zn(HPB)_2$:Ir-complexes and $Alq_3$. The doping rate of Ir-complexes was varied, such as 0.2%, 0.4%, 0.6%, and 0.8%, respectively. When the doping rate of $Zn(HPB)_2$:Ir-complexes was 0.6%, white emission was achieved. The Commission Internationale de l'Eclairage (CIE) coordinates of the white emission was (0.322, 0.312).

• Bulletin of the Korean Chemical Society
• /
• 제32권1호
• /
• pp.95-99
• /
• 2011

$CaTi_{1-x}Fe_xO_3(0{\leq}x{\leq}0.4)$ solid solution photocatalysts were synthesized by iron doping during the conventional solid state reaction at $1100^{\circ}C$ for 5 h and characterized by ultraviolet-visible (UV-vis) absorption spectroscopy, X-ray diffraction, morphological analysis. We found that $CaTi_{1-x}Fe_xO_3$ samples not only absorb UV but also the visible light photons. This is because the Fe substitution at Ti-site in $CaTi_{1-x}Fe_xO_3$ lattice induces the band transition from Fe3d to the Fe3d + Ti3d hybrid orbital. The photocatalytic activity of Fe doped $CaTiO_3$ samples for hydrogen production under UV light irradiation decreased with the increase in the Fe concentration. There exists an optimized concentration of iron in $CaTiO_3$, which yields a maximum photocatalytic activity under visible light ($\lambda\geq420nm$) photons.

• 융합정보논문지
• /
• 제8권5호
• /
• pp.95-100
• /
• 2018

금속 산화물/그래핀 형태의 복합 나노소재는 높은 전기용량을 갖는 2차 전지의 전극용 소재 또는 고감도 가스 센서의 감지물질 등으로 활용되는 매우 유용한 기능성 소재이다. 본 논문에서는 열 화학기상증착(CVD, Chemical Vapor Deposition)으로 Cu Foil 위에 대면적으로 합성된 CVD 그래핀 및 고정렬 열분해 흑연(HOPG, Highly Oriented Pyrolytic Graphite)으로부터 기계적으로 박리된 그래핀 기판 위에 이산화바나듐($VO_2$) 나노구조물을 기상수송방법으로 직접 성장시키는 연구를 수행하였다. 연구결과 CVD 그래핀 기판의 경우, 그래핀 결정 경계에서 상대적으로 많이 존재하는 기능기들이 $VO_2$ 나노구조물에서 핵형성의 씨앗으로 작용하는 것이 확인되었다. 반면에 HOPG에서 기계적으로 박리된 그래핀 나노시트 표면에는 기능기가 균일하게 분포하기 때문에, 2차원과 3차원 형태로 $VO_2$ 나노구조물이 성장되었다. 이러한 연구결과는 고기능성 $VO_2$/그래핀 나노복합소재를 이용하여 높은 전기용량을 갖는 2차 전지 전극소재 및 고감도 가스 센서의 감지물질 합성에 유용하게 활용될 것으로 전망된다.

• 한국재료학회지
• /
• 제20권10호
• /
• pp.513-517
• /
• 2010

There have been many efforts to modify and improve the properties of functional thin films by hybridization with nano-sized materials. For the fabrication of electronic circuits, micro-patterning is a commonly used process. For photochemical metal-organic deposition, photoresist and dry etching are not necessary for microscale patterning. We obtained direct-patternable $SnO_2$ thin films using a photosensitive solution containing Ag nanoparticles and/or multi-wall carbon nanotubes (MWNTs). The optical transmittance of direct-patternable $SnO_2$ thin films decreased with introduction of nanomaterials due to optical absorption and optical scattering by Ag nanoparticles and MWNTs, respectively. The crystallinity of the $SnO_2$ thin films was not much affected by an incorporation of Ag nanoparticles and MWNTs. In the case of mixed incorporation with Ag nanoparticles and MWNTs, the sheet resistance of $SnO_2$ thin films decreased relative to incorporation of either single component. Valence band spectral analyses of the nano-hybridized $SnO_2$ thin films showed a relation between band structural change and electrical resistance. Direct-patterning of $SnO_2$ hybrid films with a line-width of 30 ${\mu}m$ was successfully performed without photoresist or dry etching. These results suggest that a micro-patterned system can be simply fabricated, and the electrical properties of $SnO_2$ films can be improved by incorporating Ag nanoparticles and MWNTs.