• Title/Summary/Keyword: high-aspect ratio

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Electrochemical Synthesis of Dumbbell-like Au-Ni-Au Nanorods and Their Surface Plasmon Resonance

  • Park, Yeon Ju;Liu, Lichun;Yoo, Sang-Hoon;Park, Sungho
    • Journal of Electrochemical Science and Technology
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    • v.3 no.2
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    • pp.57-62
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    • 2012
  • In this report, we demonstrate that the longitudinal localized surface plasmon resonance mode can be suppressed when the nanorods were in dumbbell shape. The seed nanorods were synthesized by electrochemical deposition of metals into the pores of anodic aluminum oxide templates. The dumbbell-like nanorods were grown from seed Au-Ni-Au nanorods by a rate-controlled seed-mediated growth strategy. The selective deposition of Au atoms onto Au blocks of Au-Ni-Au nanorods produced larger diameter of Au nanorods with bumpy surface resulting in dumbbell-like nanorods. The morphology of nanorods depended on the reduction rate of $AuCl_4^-$, slow rate producing smooth surface of Au nanorods, but high reduction rate producing bumpy surface morphology. Through systematic investigation into the UV-Vis-NIR spectroscopy, we found that the multiple localized surface plasmon resonance (LSPR) modes were available from single-component Au nanorods. And, their LSPR modes of Au NRs with bumpy surface, compared to the smooth seed Au NRs, were red-shifted, which was obviously attributed to the increased electron oscillation pathways. While the longitudinal LSPR modes of smoothly grown Au NRs were blue-shifted except for a dipole transverse LSPR mode, which can be interpreted by decreased aspect ratio. In addition, dumbbell-like nanorods showed an almost disappeared longitudinal LSPR mode. It reflects that the plasmonic properties can be engineered using complex nanorods structure.

Synthesis of Needle-like Aragonite from Limestone without Calcinations in the Presence of Magnesium Sulfate

  • Hu, Zeshan;Shao, Minghao;Cai, Qiang;Jiao, Zhaojie;Zhong, Chenhua;Deng, Yulin
    • Advanced Composite Materials
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    • v.18 no.2
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    • pp.187-195
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    • 2009
  • Much attention has been paid to the processing of inorganic whisker, especially calcium carbonate whisker, which can be used as reinforcement materials of polymer composite due to its low price. Unfortunately, the present synthesis technique of calcium carbonate whisker starts from calcinations of limestone, which involves high energy consumption and furthermore is a highly environment polluting reaction. In this report, needle-like aragonite was synthesized with a reversible solution reaction from limestone without calcination. Optical microscopy, scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques were used to characterize the morphology and crystal structure of intermediates as well as that of the product, aragonite. GCC (grinding calcium carbonate) powder was dissolved in an aqueous solution of magnesium sulfate with reflux and air flush. EDTA titration was used to evaluate reaction rate of the dissolution. A kinetics equation of the dissolution reaction was constructed, which displayed second-order kinetics with respect to the concentration of magnesium sulfate. A rate constant of $0.0015\;l^{-3}{\cdot}mol^{-1}{\cdot}h^{-1}$ was obtained. The dissolution reaction gave fiber-like magnesium hydroxide sulfate and gypsum crystal. Then needle-like aragonite with a length of $9.13\;{\pm}\;1.02\;{\mu}m$ and an aspect ratio of $5.64\;{\pm}\;1.37$ was synthesized from the dissolution product with $CO_2$ bubbling at $70^{\circ}C$.

Soft Magnetic Property of Ternary Fe-9.8Si-6.0Al Alloy Using by Recycling Fe-Si Electrical Steel Sheet Scrap (Fe-Si 전기강판 폐스크랩을 이용한 3원계 Fe-9.8Si-6.0Al 합금의 연자성 특성)

  • Hong, Won Sik;Yang, Hyoung Woo;Park, Ji-Yeon;Oh, Chulmin;Lee, Woo Sung;Kim, Seung Gyeom;Han, Sang Jo;Shim, Geum Taek;Kim, Hwi-Jun
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.1
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    • pp.1-8
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    • 2017
  • Fe-9.8Si-6.0Al mother alloy was manufactured using by Fe-3.5Si recycled scrap and Si powder. And then, soft magnetic alloy powder of $D_{50}$ size and sphere type were prepared by gas atomization process. To obtain the soft magnetic powder of a high aspect ratio, in the first, we conducted the ball milling process for 8 hours. And heat treatment was performed under $650^{\circ}C$, 2 hours and $N_2$ atmosphere condition for reducing the residual stress of the powder. Based on these process, we made around $50{\mu}m$ diameter Fe-9.8Si-6.0Al powder, which morphology and shape was a similar to the commercial Fe-Si-Al powder. Finally, the soft magnetic sheets were prepared by tape casting process using by those powders. The permeability of the tape casting sheet was measured, and we confirmed the possibility of reusing to the soft magnetic materials of Fe-Si electric sheet scrap.

Developing High Altitude Long Endurance (HALE) Solar-powered Unmanned Aerial Vehicle (UAV) (고고도 장기체공 태양광 무인기 개발)

  • Hwang, SeungJae;Kim, SangGon;Lee, YungGyo
    • Journal of Aerospace System Engineering
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    • v.10 no.1
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    • pp.59-65
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    • 2016
  • Korea Aerospace Research Institute (KARI) is developing an electric-driven HALE UAV in order to secure system and operational technologies since 2010. Based on the 5 years of flight tests and design experiences of the previously developed electric-driven UAVs, KARI has designed EAV-3, a solar-powered HALE UAV. EAV-3 weighs 53 kg, the structure weight is 21 kg, and features a flexible wing of 19.5 m in span with the aspect ratio of 17.4. Designing the main wing and empennage of the EAV-3 the amount of the bending due to the flexible wing, 404 mm at 1-G flight condition based on T-800 composite material, and side wind effects due to low cruise speed, V_cr = 6 m/sec, are carefully considered. Also, unlike the general aircraft there is no center of gravity shift during the flight. Thus, the static margin cuts down to 28.4% and center of gravity moves back to 31% of the Mean Aerodynamic Chord (MAC) comparing to the previously developed scale-down HALE UAVs, EAV-2 and EAV-2H, to minimize a trim drag and enhance a performance of the EAV-3. The first flight of the EAV-3 has successfully conducted on the July 29, 2015 and the test flight above the altitude 14 km has efficiently achieved on the August 5, 2015 at the Goheung aviation center.

Effects of Rice-Winter Cover Crops Cropping Systems on the Rice Yield and Quality in No-tillage Paddy Field

  • Lee, Young-Han;Son, Daniel;Choe, Zhin-Ryong
    • Korean Journal of Environmental Agriculture
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    • v.28 no.1
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    • pp.53-58
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    • 2009
  • The propose of this study was to find out optimum conditions for no-tillage rice-winter cover crops cropping system. A field research was conducted to evaluate productivity and quality of rice cultivars (Dongjinbyeo and Junambybyeo) in rice-winter cover cropping systems at Doo-ryangmyeon., Sacheon, Gyeongsangnam-do, Korea from January 2005 to October 2006. The experimental soil was Juggog series (fine silty, mesic family of Fluvaquentic Eutrndepts). The rice cultivars were experimented under some different high residue farming systems, i.e. no-tillage no treatment (NTNT), no-tillage amended with rice straw (NTRS), no-tillage amended with rye (NTR), no-tillage amended with Chinese milkvetch (NTCMV), tillage no treatment (TNT), and conventional cropping system (Control). The miss-planted rate was 8.8% in 2005 and range of 10.8% to 13.3% in 2006 at NTR, and the other treatments were carried out at miss-planted rate ranging from 1.2% to 5.0%. Tiller numbers of Junambyeo, and Dongjinbyeo in both of years were the highest in Control, and decreased nearly in NTCMV, NTR, NTRS, NTNT, and TNT in that order. The lowest grain yield was observed in TNT both cultivars due to the lower tiller numbers per area, and spikelet numbers per panicle. Also, no-tillage treatments were lower grain yield than control. On the other hand, 1,000-grain weight was lowest in control due to higher tiller numbers per area, and spikelet numbers per panicle. Ripened grain ratio was a similar aspect in all treatments. The palatability score of milled rice was lowest in control while protein content of milled rice was highest in control. The NTCMV was considered an effective sustainable farming practice for rice yield and quality.

Mitigation of wind-induced responses of cylinder solar tower by a tiny eddy current tuned mass damper based on elastic wind tunnel tests

  • Liu, Min;Li, Shouying;Chen, Zhengqing
    • Smart Structures and Systems
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    • v.26 no.5
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    • pp.619-629
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    • 2020
  • Solar towers, which often has a large aspect ratio and low fundamental natural frequency, were extremely prone to large amplitude of wind-induced vibrations, especially Vortex-Induced Vibration (VIV). A tiny Tuned Mass Damper (TMD) with conveniently adjustable eddy current damping was specially designed and manufactured for elastic wind tunnel tests of a solar tower. A series of numerical simulations by using the COMSOL software were conducted to determine three key parameters, including the thickness of the back iron plate and the conductive plate (Tb and Tc), the distance between the magnet and the conductive plate (Td). Based on the results of numerical simulations, a tiny TMD was manufactured and its structural parameters were experimentally identified. The optimized values of the tiny TMD can be conveniently realized. The tiny TMD was installed at the top of the elastic test model of a 243-meter-high solar tower, and a series of wind tunnel tests were carried out to examine the effectiveness of the TMD in suppressing wind-induced responses of the test model. The results showed that the wind-induced responses could be obviously reduced by the TMD, especially in the cross-wind direction. The cross-wind RMS and peak responses at the critical wind velocity can be reduced by about 86% and 75%, respectively. However, the maximum reduction of the responses at the design wind velocity is about 45%, obviously less than that at the critical wind velocity.

Numerical Study on the Side-Wind Aerodynamic Forces of Chambered 3-D Thin-Plate Rigid-Body Model (캠버가 있는 3차원 박판 강체 모형의 측풍 공기력에 대한 수치 연구)

  • Shin, Jong-Hyeon;Chang, Se-Myong;Moon, Byung-Young
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.43 no.2
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    • pp.97-108
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    • 2015
  • In the design of sailing yachts, para-glider, or high-sky wind power, etc., the analysis of side-wind aerodynamic forces exerted on a cambered 3-D model is very important to predict the performance of various machinery systems. To understand the essential flow physics around the three-dimensional shape, simplified rigid-body models are proposed in this study. Four parameters such as free stream velocity, angle of attack, aspect ratio, and camber are considered as the independent variables. Lift and drag coefficients are computed with CFD technique using ANSYS-CFX, and the results with the visualization of post-processed flow fields are analyzed in the viewpoint of fluid dynamics.

Synthesis of vertically aligned silicon nanowires with tunable irregular shapes using nanosphere lithography

  • Gu, Ja-Hun;Lee, Tae-Yun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.88.1-88.1
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    • 2012
  • Silicon nanowires (SiNWs), due to their unusual quantum-confinement effects that lead to superior electrical and optical properties compared to those of the bulk silicon, have been widely researched as a potential building block in a variety of novel electronic devices. The conventional means for the synthesis of SiNWs has been the vapor-liquid-solid method using chemical vapor deposition; however, this method is time consuming, environmentally unfriendly, and do not support vertical growth. As an alternate, the electroless etching method has been proposed, which uses metal catalysts contained in aqueous hydrofluoric acids (HF) for vertically etching the bulk silicon substrate. This new method can support large-area growth in a short time, and vertically aligned SiNWs with high aspect ratio can be readily synthesized with excellent reproducibility. Nonetheless, there still are rooms for improvement such as the poor surface characteristics that lead to degradation in electrical performance, and non-uniformity of the diameter and shapes of the synthesized SiNWs. Here, we report a facile method of SiNWs synthesis having uniform sizes, diameters, and shapes, which may be other than just cylindrical shapes using a modified nanosphere lithography technique. The diameters of the polystyrene nanospheres can be adjustable through varying the time of O2 plasma treatment, which serve as a mask template for metal deposition on a silicon substrate. After the removal of the nanospheres, SiNWs having the exact same shape as the mask are synthesized using wet etching technique in a solution of HF, hydrogen peroxide, and deionized water. Different electrical and optical characteristics were obtained according to the shapes and sizes of the SiNWs, which implies that they can serve specific purposes according to their types.

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The Finite Element Analysis for a Micro Turbine Fabricated by LIGA-like Process (LIGA-like 공정으로 제작된 마이크로 터빈의 유한 요소 해석)

  • Oh, J.;Choi, B.;Kim, N.
    • Journal of Sensor Science and Technology
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    • v.9 no.5
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    • pp.380-388
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    • 2000
  • The finite element analysis of a micro turbine was made to investigate safety margin of its operating condition for the high aspect ratio nickel micro turbine blades fabricated by conventional LIGA-like method. From our study, we found that the fabricated turbine could not exceed its yield strength even if the pressure difference between inlet and outlet of turbine blade was about 44kPa, and the correlation of friction coefficient and the maximum stress, caused by contact friction between outer diameter of shaft and inner diameter of turbine blade, was somewhat reciprocal. The maximum stress was decreased with the increasing contact friction, when turbine blade was in its state of rotation. By the results of our study, we conclude that it is possible to fabricate metal micro turbine more easily han surface micromachining technology and to operate with no risk of metal structure's damage, which is caused by yield strength, if the operating condition with the design of micro turbine itself are optimized. It is useful to adopt other applications which have the contact problems between a moving part and the fixed one in micro structures.

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Causes and Overcoming of the Algae Excess in a Dam Water - Based on the Data of Water Quality Analysis of Mulgum Area - (댐호화된 하천의 조류 과다 발생원인과 해소 방안 - 낙동강 물금 지역의 수질 분석 데이터를 중심으로 -)

  • Yang, Shi-Chun;Xia, Tian-Tian;Kang, Tai-Ho
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.20 no.4
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    • pp.1-13
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    • 2017
  • The purpose of this study is to analyze a term of decade of water quality data of the Mulgum intake station on the Nakdong river(dam) to find the cause of algal blooms and to set an alternative to prevent artificial lake water pollution. Our study shows that water quality changes have regular periodic regularity and there was a certain correlation between specific analytical items. According to the analysis results of each factor, the decline in precipitation was not the main reason for algal blooms. TP concentration had a slight effect on Chl-a concentration but was not a limiting nutrient of a bloom. TN concentration had a strong correlation with Chl-a and strongly negative correlation with temperature, but was not a bloom's limiting nutrient, and was only a dependent variable. As the temperature was negatively correlated with the Chl-a concentration, it is found that the aspect of the ecological influence of the temperature was the most important factor of the phytoplankton concentration change. The N/P ratio lies under a power function with a high degree of reliability by the TP concentration, and the phenomenon appeared to be the same as the results of two other comparative areas. This result confirms that TN is dependent on TP and the biota in the lake that TN is a dependent variable whose concentration is determined by TP it. In conclusion, the increase in lake bloom is the result of a food chain change, and it is necessary to control the ecosystem by the food chain in the lake in order to reduce the lake's bloom. In particular, it is important to keep the benthic ecosystem as wide as possible in the aerobic state.