• Title/Summary/Keyword: hemihydrate

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A Study on Soil Improvement Agent for Rainfall-Induced Erosion on the Soil Slope (흙 사면의 강우 침식보강을 위한 토양개량제 개발에 관한 연구)

  • Kang, Dae-Heung;Kim, Young-Suk;Hwang, In-Taek;Kim, Jae-Hong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.3
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    • pp.237-246
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    • 2021
  • With climate change, debris flow has been increasing due to the collapse and erosion of shallow slopes caused by extreme rainfall. It is preferred to an economical and eco-friendly method rather than reinforcement of soil slopes with the earth anchor or nailing method. In this study, a soil improvement agent was developed by utilizing insitu soil, leaf mold, and used harbal medicine to help sufficient vegetation. In addition, to prevent surface erosion, shear strength of the soil was increased by using micro cement and hemihydrate gypsum as additives. The optimum mix ratio of the mixture is determined by increasing the shear strength by checking the erosion progress of the ground surface layer due to rainfall through an laboratory test. The safety factor of soil slope has been improved on the slope surface reinforced by the improvement agent, and the strength of erosion has been increased, making it efficient to cope with heavy rain during wet season.

Feasibility Study on CLSM for Emergency Recovery of Landfill Bottom Ash (매립장 석탄회의 긴급복구용 CLSM으로 활용 가능성)

  • Ha-Seog Kim;Ki-Suk Kim
    • Land and Housing Review
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    • v.14 no.2
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    • pp.137-145
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    • 2023
  • In this study, the characteristics such as flowability, bleeding rate, and strength of the CLSM (Controlled Low Strength Material) according to physical properties such as particle size distribution and particulate content of the pond ash were investigated as part of the practical development of technology for CLSM using pond ash. As a result of analyzing the properties of the collected pond ash, it was found that the density and particle size distribution characteristics were different. And that the bleeding ratio did not satisfy the standard in the case of the specimen with a large amount of fly ash and a lot of addition of mixing water. As a result of the compressive strength test, the strength development of 0.5 MPa or more for four hours was found to be satisfactory for the specimens using hemihydrate gypsum with a unit binder amount of 200 or more, and the remaining gypsum showed poor strength development. Although it was determined that landfill coal ash can be used as a CLSM material, it is necessary to identify and apply the physical and chemical characteristics of coal ash buried in the ash treatment plant of each power generation company.

Elution profiles of metronidazole from calcium sulfate beads

  • Burasarin Ithisariyanont;Saranya Poapolathep;Amnart Poapolathep;Pareeya Udomkusonsri
    • Journal of Veterinary Science
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    • v.24 no.6
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    • pp.74.1-74.15
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    • 2023
  • Background: Antibiotic beads are used to treat local bacterial infections by delivering high drug concentrations to infected tissue. Objectives: This study examined the elution characteristics of metronidazole from metronidazole-calcium sulfate (MCa) and metronidazole-calcium-potassium sulfate (MCaK) beads over 20 days and the antibacterial efficacy of the beads after storage. Methods: The MCa and MCaK beads were prepared by mixing 250 mg of metronidazole and 10 g of calcium sulfate hemihydrate with water and a 3% potassium sulfate solution, respectively. The beads were placed in phosphate-buffered saline for the elution study. The metronidazole eluents were determined using high-performance liquid chromatography. The microstructures were examined by scanning electron microscopy (SEM), and the antimicrobial activity was evaluated by a microbioassay. Results: For the 20-day study, the total amount of metronidazole released was greater in the MCa beads than in the MCaK beads by 6.61 ± 0.48 mg (89.11% ± 3.04%) and 4.65 ± 0.36 mg (73.11% ± 4.38%), respectively. The amounts of eluted drugs from the MCa and MCaK beads were higher than the minimum inhibitory concentration at 0.5 ㎍/mL against anaerobic bacteria at both 20 days and 14 days. SEM showed that calcium crystals on the outer surface had dissolved after elution, and thinner calcium crystals were prominent in the MCaK beads. The MCa and MCaK beads exhibited antibacterial activity after setting, followed by storage at room temperature or 4℃ for 21 days. Conclusions: The MCa beads could release more drug than the MCaK beads, but all eluted metronidazole amounts were effective in controlling bacterial infections. Both metronidazole beads could be stored at ambient temperature or in a refrigerator.

A Study on Organic-Inorganic Hybrid Sound Absorbing Materials Using by Recycling Gypsum (재활용 석고 부산물을 이용한 유무기 하이브리드 흡음재 개발 연구)

  • Shin, Hyun-Gyoo;Jeon, Bo-Ram;Ha, Joo-Yeon;Jeon, Chan-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.481-487
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    • 2017
  • The purpose of this study is to develop the hybrid sound-absorbing materials that is made from organic polyurethane sponge impregnated with inorganic binder solutions. The inorganic slurry which is made from ${\alpha}$-hemihydrate gypsum mixed with 60% water, and various additives including plasticizer are used as binder. The test specimens are prepared and tested for sound absorption performance by the impedance tube methods. From the test results, noise reduction coefficient(NRC) of development materials specimen bound by the inorganic binder slurry is 0.41. They are 2 times or more higher than commercial products specimens bound by organic materials only which have NRC values in the range of 0.14 to 0.28. The polyurethane sponge specimens impregnated with inorganic gypsum slurry binder have a good balance between performance and cost, and have proper properties in density, thermal conductivity, non-combustible, and absence of harmful substances as sound-absorbing internal boards for noise barrier wall. It is apparent that the good sound absorption materials can be produced according to the optimum mix design that is recommended from this study.

The Comparison of Analytical Methods for Gypsum and Gypsum Slurry (석고 및 석고 슬러리에 대한 분석방법의 비교)

  • Kim, Kyeongsook;Yang, Seugran;Park, Hyunjoo;Lim, Chunsik
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.158-165
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    • 2000
  • The purity of gypsum and quantitation of impurities of flue gas gypsum will not only play an important role in deciding of the optimal condition during a trial run of FGD (flue gas desulfurization), but also can be utilized in quality control of gypsum. The purity of gypsum can be determined from combined water, sulfur trioxide and calcium concentration. We found that the thermal analysis by TGA (thermogravimetric analysis) was the most accurate and convenient method to determine the purity of gypsum. This method will be done in a hour and the results were reproducible. On the other hand, the best way of the analysis of impurities in gypsum was fusion method using $LiBO_2$ as a fusion agent. We also determined the amount of $CO_2$ gas to analyze magnesium carbonate and calcium carbonate contents. The analyses of combined water by TGA, fusion method followed by ICP-AES (inductively coupled plasmaatomic emission spectroscopy) and determination of $CO_2$ amount can lead to more accurate and convenient method for gypsum analysis.

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Possibility of Using Landfill Coal Ash as CLSM Material for Emergency Restoration of Ground and Road Joint Parts (지반 및 도로 공동부의 긴급복구용 CLSM 재료로 매립 석탄저회 활용 가능성)

  • Jin-Man Kim;Sang-Chul Shin;Kyoung-Nam Min;Ha-Seog Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.55-61
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    • 2023
  • This study aims to develop CLSM fill material for emergency restoration using landfill coal ash. As a result of examining physical properties such as particle size distribution and fines content of landfill coal ash, bottom ash, fly ash, and general soil were mixed, and SP was found to have a density of 2.03 and a residual particle pass rate of 7.8 %. CLSM materials that secure fluidity in unit quantities without using chemical admixtures such as glidants and water reducing agents have a high risk of material separation due to bleeding. As a result of this experiment, it was found that the bleeding ratio did not satisfy the standard in the case of the specimen with a large amount of fly ash and a lot of addition of mixing water. As a result of the compressive strength test, the strength development of 0.5 MPa or more for 4 hours was found to be satisfactory for the specimens using hemihydrate gypsum with a unit binder amount of 200 or more, and the remaining gypsum showed poor strength development. Although it is judged that landfill coal ash can be used as a CLSM material, it is necessary to identify and apply the physical and chemical characteristics of coal ash buried in the ash treatment plant of each power generation company.