• 제목/요약/키워드: heavy metal analysis

검색결과 823건 처리시간 0.027초

체계적인 광산관리를 위한 광산현황 및 광산공간정보 구축 기술 분석 (Analysis of the Status of Mine and Methods of Mine Geospatial Information Construction Technology for Systematic Mine Management)

  • 박준규;이근왕
    • 한국산학기술학회논문지
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    • 제19권9호
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    • pp.355-361
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    • 2018
  • 광업은 국가 산업발전의 기반이 되는 에너지와 원료자원을 공급하는 국가 기간산업으로 중요성을 가지고 있다. 한편 광산 개발은 필연적으로 광해를 동반하는데 대표적인 예로 지반침하, 중금속 오염, 수질오염 등을 들 수 있다. 광해는 피해의 범위가 크고, 복구에 많은 시간과 비용이 필요하며, 기간 지속적으로 피해가 발생할 수 있기 때문에 이를 방지하기 위한 체계적인 광산관리가 필요한 실정이다. 이에 본 연구에서는 국내 광산 및 광산공간정보 구축 현황과 광산관리를 위한 광산공간정보 구축 기술을 분석하였다. 조사된 광산은 95%가 비금속광으로 석회석 광산이 67%로 가장 많았으며, 구축된 광산공간정보는 2차원의 현황도 및 단면도, 지질도로 3차원 광산공간정보는 구축되어 있지 않은 것으로 나타났다. 3D 레이저 스캐너에 대한 조사 및 분석 결과와 우리나라 광산의 특징을 고려할 때 광산공간정보 구축을 위한 방안으로 이동식 스캐너가 가장 적합할 것으로 판단된다. 3D 레이저스캐너를 통해 취득되는 데이터는 대상물을 효과적으로 시각화 할 수 있으며, 갱내 도면의 제작, 체적의 산출 등 다양한 활용이 가능하기 때문에 체계적인 광산관리에 기여할 것이다.

한의과대학 본초학 교육과정의 개정 및 보완을 위한 설문조사 연구 (Survey on Revision and Complements for the Current Curriculum of Herbology)

  • 김홍준;최고야;김철;이금산;김정훈;이승호;황성연;주영승
    • 대한한의학회지
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    • 제30권4호
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    • pp.118-128
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    • 2009
  • Objects: This study was conducted to investigate the current educational environment of herbology and to develop a future-oriented curriculum for oriental medicine. The questionnaire used in this research was drawn up based on the current curriculum referring to the current curriculum of herbology and pharmacognosy. Methods: The survey was carried out presenting the questionnaires to a total 12,754 of the students and doctors of oriental medicine through e-mailing five times; of these, 2,074 replied. Results: 1. Among the respondents, about 97% agreed that it was necessary to revise and complement the current curriculum of herbology. 2. The respondents felt that the assigned lecture time of subject was "sufficient" (19%), "insufficient" (39%) and "average" (39%), respectively, and the level of lecture was "insufficient" (37%) or "average" (43%) respectively. According to priority, it showed that the contents which needed complement in lecture were discrimination of medicinal herbs (24%), practical use of action and indications (23%), and correlation with modern disease (21%). In theoretical lectures, 69% of the respondents agreed on the introduction of natural scientific methods 3. In practice, 51% of the respondents replied that the lecture time for practice was insufficient. The contents which needed to be complemented in practice were as follows: audio-visual materials for discrimination of medicinal herbs (22%), concrete exercise for the processing of medicinal herbs (21%), and attempts for the objective discrimination of medicinal herbs using instruments (microscope, analytical instrument, residual pesticide, heavy metal, genetic analysis) (16%). 70% replied that the discrimination of medicinal herbs of high price and rarity was "none or insufficient". 4. 56% replied that it was necessary to introduce and practice physicochemical analysis, and they showed higher requests according to the increase of their educational level. However, 86% replied that they had never experienced concrete attempts for objective discrimination of medicinal herbs, which seemed to indicate that, excepting some schools, practice exercise was rarely performed. Conclusions: According to results, it seems that an urgent review on the current course of herbology and a workshop on the process of experimental practice for professors is needed.

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포도와 포도 가공품에 함유되어 있는 trans-resveratrol의 함량 분석 (Analysis of trans-Resveratrol Contents of Grape and Grape Products Consumed in Korea)

  • 김대중;김상균;김명희;이희봉;이준수
    • 한국식품과학회지
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    • 제35권5호
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    • pp.764-768
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    • 2003
  • 본 연구는 생물학적, 비생물학적인 스트레스에 대한 방어물질중의 한가지인 trans-resveratrol를 포도와 포도가공품(포도주, 포도쥬스)으로부터 분석하는 방법을 확립하였다. trans-Resveratrol 기기분석 조건은 다음과 같다. 분석 column은 Nucleosil 100-5 C18을 사용하였으며 이동상은 acetonitrile: water(40:60, v/v)로서 UV검출기(306 nm)를 이용하여 0.3 mL/min의 유속으로 측정하였다. 분석한 결과, 재현성과 반복성의 CV%는 10%이하였으며, 회수율은 $90{\sim}110%$이었다. 또한, 포도, 포도주 그리고 포도쥬스의 최소검출한계는 14.5 ng/g, 3.62 ng/mL 그리고 4.02 ng/mL이고, 최소정량한계는 14.8 ng/g, 3.69 ng/mL 그리고 4.10 ng/mL이었다. 표준물질인 trans-resveratrol 농도가 $0.048{\sim}2.4\;{\mu}g/mL$일때 $R^2$ 값은 0.999이었다. 32품종의 포도, 9종류의 포도주 그리고 9종류의 포도쥬스 내의 trans-resveratrol 함량은 각각 $0.76{\sim}207.14\;{\mu}g/100\;g$, $5.41{\sim}275.66\;{\mu}g/L$ 그리고 $63.25{\sim}751.55\;{\mu}g/L$로 분석되었다.

Diversity of Arbuscular Mycorrhizal Fungi Associated with a Sb Accumulator Plant, Ramie (Boehmeria nivea), in an Active Sb Mining

  • Wei, Yuan;Chen, ZhiPeng;Wu, FengChang;Li, JiNing;ShangGuan, YuXian;Li, FaSheng;Zeng, Qing Ru;Hou, Hong
    • Journal of Microbiology and Biotechnology
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    • 제25권8호
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    • pp.1205-1215
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    • 2015
  • Arbuscular mycorrhizal fungi (AMF) have great potential for assisting heavy metal hyperaccumulators in the remediation of contaminated soils. However, little information is available about the symbiosis of AMF associated with an antimony (Sb) accumulator plant under natural conditions. Therefore, the objective of this study was to investigate the colonization and molecular diversity of AMF associated with the Sb accumulator ramie (Boehmeria nivea) growing in Sb-contaminated soils. Four Sb mine spoils and one adjacent reference area were selected from Xikuangshan in southern China. PCR-DGGE was used to analyze the AMF community composition in ramie roots. Morphological identification was also used to analyze the species in the rhizosphere soil of ramie. Results obtained showed that mycorrhizal symbiosis was established successfully even in the most heavily polluted sites. From the unpolluted site Ref to the highest polluted site T4, the spore numbers and AMF diversity increased at first and then decreased. Colonization increased consistently with the increasing Sb concentrations in the soil. A total of 14 species were identified by morphological analysis. From the total number of species, 4 (29%) belonged to Glomus, 2 (14%) belonged to Acaulospora, 2 (14%) belonged to Funneliformis, 1 (7%) belonged to Claroideoglomus, 1 (7%) belonged to Gigaspora, 1 (7%) belonged to Paraglomus, 1 (7%) belonging to Rhizophagus, 1 (7%) belonging to Sclervocystis, and 1 (7%) belonged to Scutellospora. Some AMF sequences were present even in the most polluted site. Morphological identification and phylogenetic analysis both revealed that most species were affiliated with Glomus, suggesting that Glomus was the dominant genus in this AMF community. This study demonstrated that ramie associated with AMF may have great potential for remediation of Sb-contaminated soils.

동진강 상류하천 유역의 수질특성 (Characteristics of Water Quality in Upper Stream Watershed of Dongjin River)

  • 손재권;박종민;최진규;송재도
    • 농촌계획
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    • 제9권2호
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    • pp.19-28
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    • 2003
  • It is the purpose of this study to investigate the change of stream water quality in upper stream of Dongjin river, and to give the basic information for the conservation of water quality. Water samples were taken periodically at 9 sampling sites during 8 months from March to October in 2002. The results of this study were as follows : 1. The water temperature and pH of stream water were ranged $9.0{\sim}29.4^{\circ}C,\;6.48{\sim}9.33$, respectively. The COD values of stream water was ranged from 0.60 to 19.06. The contents of T-N and T-P mainly affected by the livestock wastes, and agricultural activity were $1.88{\sim}6.74\;mg/L$, ND(not deleted)${\sim}0.50\;mg/L$, respectively. 2. The SS, DO and BOD values of stream water were ranged $0.4mg/L{\sim}274.0mg/L$, $0.5{\sim}6.0\;mg/L$, and $7.3{\sim}13.7\;mg/L$ respectively. 3. The cation is one of the important components in analysis of stream water quality. The contents of analysis, $Ca^{++},\;Mg^{++},\;Na^+$ and $K^+$ were ranged $1.96{\sim}11.08\;mg/L$, $1.21{\sim}6.16\;mg/L$, $3.38{\sim}18.44\;mg/L$, $1.12{\sim}7.96\;mg/L$, respectively. SAR was ranged $0.31{\sim}1.63$ below 2.0. The contents of cation showed in the order $Na^{++}>Ca^{++}>K^+>Mg^+$. 4. The contents of heavy metal Zn, Cu, and Pb were $ND{\sim}0.071\;mg/L$, $ND{\sim}0.012\;mg/L$, and $ND{\sim}0.043\;mg/L$, respectively. Cd was not detected in all samples. 5. As a result of these researches showed water quality in upper stream watershed of Dongjin river more affected by livestock wastes and living sewage than agricultural activity.

환경매체별 카드뮴의 생태위해성평가 (Ecological Risk Assessment for Cadmium in Environmental Media)

  • 이병우;이병천;윤효정;박경화;김필제
    • 한국환경보건학회지
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    • 제44권6호
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    • pp.548-555
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    • 2018
  • Objectives: We conducted ecological risk assessment for cadmium, a heavy metal and carcinogen, to identify safety standards by environmental media and to determine its impact on ecosystems by estimating and evaluating exposure levels. Methods: Species sensitivity distributions (SSDs) were generated using ECOTOX DB. A hazardous concentration of 5% (HC5) protective of most species (95%) in the environment was estimated. Using this estimate, predicted no effect concentrations (PNECs) were calculated for aquatic organisms. Based on the calculated PNECs for aquatic organisms, PNEC values for soil and sediment were calculated using the partition coefficient. Predicted exposure concentrations (PECs) were also calculated from environmental monitoring data with hazard quotients (HQs) calculated using PNECs for environmental media. Results: Chronic toxicity data were categorized into four groups and 11 species. In species sensitivity distribution (SSD) analysis, HC5 was $0.340{\mu}g/L$. Based on this value, the PNEC value for aquatic organisms was calculated as $0.113{\mu}g/L$. PNEC values for soil and sediments using a partition coefficient were calculated as 15.02 mg/kg and 90.61 mg/kg, respectively. In an analysis of environmental monitoring data, PEC values were calculated as $0.017{\mu}g/L$ for water, 1.01 mg/kg for soil, and 0.521 mg/kg for sediment. Conclusions: HQs were 0.150, 0.067 and 0.006 for water, soil and sediment, respectively. HQs of secondary toxicity were 0.365 for birds and 0.024 for mammals. In principle, it is judged that an HQ above 1 indicates a high level of risk concern while an HQ less than 1 indicates an extremely low level of risk concern. Therefore, with HQs of cadmium in the environment being <1, its risk levels can be considered low for each media.

순환토사 재활용에 관한 연구 - 농업성토용 중심으로 - (Study on the Recycling of Waste Soil from Constructed Site - Focused on Agricultural Planting Soil -)

  • 김재형;박제철
    • 한국건설순환자원학회논문집
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    • 제7권1호
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    • pp.16-21
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    • 2019
  • 본 연구에서는 순환토사가 농지개량용으로 적용 가능성이 있는지 그리고 채움재로서의 활용 가능성이 있는지 알아보기 위하여 순환토사의 물리적 화학적 성분 분석을 평가하였고, 비교생육실험 및 발아실험 그리고 식생대층 높이에 따른 생육실험을 진행하였다. 물리적 성분 분석결과 SW와 SP계열로 조사되었으며 토성은 양질사토로 조사되었다. 순환토사를 농지개량용으로 사용하기 위해서는 점토 및 미사와 혼합하여 사용하면 될 것으로 사료된다. 화학적 성분 분석결과 pH는 일반 토양보다 높으나 중금속은 토양오염우려기준의 1지역 기준치 이내로 나타났다. 발아실험결과 순환토사를 75% 미만으로 혼합하여 사용했을때 영향이 거의 없는 것으로 조사되었고, 원예용 상토에 순환토사 40% 미만을 혼합하여 사용하면 생육장해가 미비한 것으로 나타나 일반적인 토양과 차이가 없는 것으로 확인되었다.

이산화탄소 고정 탄산화물을 적용한 콘크리트 2차 제품의 기초 특성 분석 (Analysis of mechanical properties of secondary concrete products using CO2 captured material)

  • 유혜진;서성관;박금단;권혁준;김정환
    • 한국결정성장학회지
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    • 제34권2호
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    • pp.66-72
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    • 2024
  • 본 연구에서는 탈황석고(DG)에 이산화탄소를 반응시켜 제조한 탄산화물(CCMs)을 콘크리트 2차 제품의 시멘트 대체재로서 적용 가능성을 평가하고 최적 배합비 도출을 위한 탄산화물 혼입 모르타르 및 콘크리트 시편의 기초 물성 측정을 실시하였다. 탄산화물은 다량의 CaO 및 SO3로 이루어져 있으며, 주요 결정상은 CaSO4·2H2O, Ca(OH)2, CaCO3 및 CaSO4로 나타났다. 또한 입도 분석 및 폐기물공정시험기준에 따른 중금속 측정 결과 콘크리트 2차 제품의 시멘트 대체재로서 탄산화물의 적용 가능성이 확인되었다. 모르타르 및 콘크리트 공시체 제작 후 강도 거동 측정 결과 탄산화물 혼입량이 증가할수록 강도가 감소하는 경향을 나타내었으나 최적 배합인 치환 비율 10 wt.% 배합까지 대상 제품인 인터로킹 블록 및 옹벽 블록의 기준에서 요구하는 모든 조건을 만족하였다. 따라서 콘크리트 2차 제품의 시멘트 대체재로서 적용 가능성이 확인되었다.

콩 GAP 모델 확립을 위한 재배환경의 위해요소 조사 및 분석 (Investigation and Analysis of Hazards for Cultivation Environment to Establish the Good Agricultural Practices(GAP) of Soybean)

  • 김경열;송정언;허록원;이원경;남민지;김정숙;심원보;길중권;정찬식;박금룡;정덕화
    • 농업생명과학연구
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    • 제44권6호
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    • pp.121-132
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    • 2010
  • 콩 GAP 모델 확립을 위해 경남 창녕에 소재한 콩 재배농가 3 곳을 선정하여 각 재배환경에 대한 물리적, 화학적(중금속) 및 생물학적(위생지표세균, 병원성 미생물) 위해요소를 분석하였다. 재배환경에 대한 물리적 위해요소로는 토양과 농업용수에 혼입될 수 있는 이물 등으로 확인되었고, 화학적 위해요소 중 토양과 농업용수에서의 중금속 (Cd:0.01~0.103, Cu:0.001~6.036, As:0.006~3.045, Hg:ND~0.041, Pb:0.003~3.952, $Cr^{+6}$:0.007~0.496, Zn:0.001~66.500, Ni:0.003~18.010)이 모두 허용기준치 이하로 검출되었다. 생물학적 위해요소의 경우, 위생지표세균은 토양에서 일반세균과 대장균군이 $6.0{\pm}0.3$$3.6{\pm}1.6$ log CFU/g, 농업용수는 $3.5{\pm}0.7$$1.9{\pm}0.7$ log CFU/mL 수준으로 각각 검출되었고, E. coli는 모든 시료에서 불검출 되었다. 그러나 농업용수에서 대장균군이 허용기준치를 초과하였고, E. coli O157도 토양 중에서 약 22%가 검출됨에 따라 분변오염 방지를 위한 적절한 방안이 필요할 것으로 판단된다. 결론적으로 재배환경 중 물리적 및 화학적 위해요소 (중금속)의 오염수준은 허용기준에 적합했지만, 생물학적 위해요소의 경우 농업용수에서 대장균군이 기준치를 초과함에 따라 최종산물로의 교차오염을 방지하기 위한 체계적인 관리방안이 모색되어야 할 것으로 판단된다.

농업생산기반 정비사업의 산업연관효과분석 -황락 저수지지구를 중심으로- (Analysis of Industrial Linkage Effects for Farm Land Base Development Project -With respect to the Hwangrak Benefited Area with Reservoir -)

  • 임재환;한석호
    • 농업과학연구
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    • 제26권2호
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    • pp.77-93
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    • 1999
  • This study is aiming at identifying the foreward and backward lingkage effects of the farm land base development project. Korean Government has continuously carried out farmland base development projets including the integrated agricultural development projects. large and medium scale irrigation projects and the comprehensive development of the four big river basin including tidal land reclamation and estuary dam construction for the all weather farming since 1962. the starting year of the five year economic development plans. Consequently the irrigation rate of paddy fields in Korea reached to 75% in 1998 and to escalate the irrigation rate, the Government had procured heavy investment fund from IBRD. IMF and OECF etc. To cope with the agricultural problems like trade liberalization in accordance with WTO policy, the government has tried to solve such problems as new farmland base development policy, preservation of the farmland and expansion of farmland to meet self-sufficiency of foods in the future. Especially, farmland base development projects have been challanged to environmental and ecological problems in evaluating economic benefits and costs where the value of non-market goods have not been included in those. Up to data, in evaluating benefits and costs of the projects, farmland base development projects have been confined to direct incremental value of farm products and it's related costs. Therefore the projects'efficiency as a decision making criteria has shown the low level of economic efficiencies. In estimating economic efficiencies including Leontiefs input-output analysis of the projects could not be founded in Korea at present. Accordingly this study is aimed at achieving and identifying the following objectives. (1) To identify the problems related to the financial supports of the Government in implementing the proposed projects. (2) To estimated backward and foreward linkage effects of the proposed project from the view point of national economy as a whole. To achieve the objectives, Hwangrak benefited area with reservoir which is located in Seosan-haemi Disticts, Chungnam Province were selected as a case study. The main results of the study are summarized as follows : a. The present value of investment and O & M cost were amounted to 3,510million won and the present value of the value added in related industries was estimated at 5.913million won for the period of economic life of 70 years. b. The total discounted value of farm products in the concerned industries derived by the project was estimated at 10,495million won and the foreward and backward linkage effects of the project were amounted to 6,760 and 5,126million won respectively. c. The total number of employment opportunities derived from the related industries for the period of project life were 3,136 man/year. d. Farmland base development projects were showed that the backward linkage effects estimated by index of the sensitivity dispersion were larger than the forward linkage effect estimated by index of the power of dispersion. On the other hand, the forward linkage effect of rice production value during project life was larger than the backward linkage effect e. The rate of creation of new job opportunity by means of implementing civil engineering works were shown high in itself rather than any other fields. and the linkage effects of production of the project investment were mainly derived from the metal and non-metal fields. f. According to the industrial linkage effect analysis, farmland base development projects were identified economically feasible from the view point of national economy as a whole even though the economic efficiencies of the project was outstandingly decreased owing to delaying construction period and increasing project costs.

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