• Title/Summary/Keyword: heat-moisture treatment

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Heat-Treated Polyvinyl Alcohol/Cellulose Nanocrystal Film with Improved Mechanical Properties and Water Resistance (내수성 및 기계적 물성이 향상된 열처리된 폴리비닐알코올/셀룰로오스 나노결정 필름)

  • Nguyen, Son Van;Lee, Bong-Kee
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.11
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    • pp.1-8
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    • 2021
  • In this study, the water resistance and mechanical properties of heat-treated polyvinyl alcohol (PVA)/cellulose nanocrystal (CNC) films were investigated. PVA is the most commonly used synthetic biodegradable polymers owing to its excellent properties. However, the water/moisture sensitivity and relatively poor mechanical properties of PVA limits its applications. Although heat treatment is a conventionally used method to improve the mechanical strength and water resistance of PVA, the effectiveness of this method is insufficient. Therefore, CNC was used to further improve the mechanical properties and water resistance of the heat-treated PVA film. PVA/CNC nanocomposites containing CNC contents of 0, 1, 3, 5, and 10 wt% were fabricated using solvent casting and subsequent heat treatment. The mechanical properties and water resistance of PVA/CNC films were significantly improved. The tensile strength and wet strength of the PVA/CNC film with a CNC content of 5 wt% (PVA/CNC 5%) were 184.5% and 136.0% higher than those of the untreated PVA, respectively. In addition, the water absorption and solubility of PVA/CNC 5% were 56.6% and 68.2% lower than those of the untreated PVA.

Electrical Properties of TiN/TiO2/FTO Resistive Random-Access Memory Based on Peroxo Titanium Complex Sol Solution by Heat Treatment (열처리에 따른 Peroxo Titanium Complex 졸 용액 기반 TiN/TiO2/FTO Resistive Random-Access Memory의 전기적 특성)

  • Yim, Hyeonmin;Lee, Jinho;Kim, Won Jin;Oh, Seung-Hwan;Seo, Dong Hyeok;Lee, Donghee;Kim, Ryun Na;Kim, Woo-Byoung
    • Korean Journal of Materials Research
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    • v.32 no.9
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    • pp.384-390
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    • 2022
  • A spin coating process for RRAM, which is a TiN/TiO2/FTO structure based on a PTC sol solution, was developed in this laboratory, a method which enables low-temperature and eco-friendly manufacturing. The RRAM corresponds to an OxRAM that operates through the formation and extinction of conductive filaments. Heat treatment was selected as a method of controlling oxygen vacancy (VO), a major factor of the conductive filament. It was carried out at 100 ℃ under moisture removal conditions and at 300 ℃ and 500 ℃ for excellent phase stability. XRD analysis confirmed the anatase phase in the thin film increased as the heat treatment increased, and the Ti3+ and OH- groups were observed to decrease in the XPS analysis. In the I-V analysis, the device at 100 ℃ showed a low primary SET voltage of 5.1 V and a high ON/OFF ratio of 104. The double-logarithmic plot of the I-V curve confirmed the device at 100 ℃ required a low operating voltage. As a result, the 100 ℃ heat treatment conditions were suitable for the low voltage driving and high ON/OFF ratio of TiN/TiO2/FTO RRAM devices and these results suggest that the operating voltage and ON/OFF ratio required for OxRAM devices used in various fields under specific heat treatment conditions can be compromised.

Effect of Microwave Irradiation on Crystallinity and Pasting Viscosity of Corn Starches Different in Amylose Content

  • Lee, Su-Jin;Sandhu, Kawaljit Singh;Lim, Seung-Taik
    • Food Science and Biotechnology
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    • v.16 no.5
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    • pp.832-835
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    • 2007
  • Moisture content of normal, waxy, and high amylose com starches was adjusted to 10-35%, and irradiated in a microwave oven. The effect of microwave irradiation on the crystalline structure of starch was measured by using a differential scanning calorimetry (DSC), and X-ray diffractometry. Pasting viscosity profile was also determined by using a rapid viscoanalyzer (RVA). For all the 3 types of starches tested, the rate of temperature increase by the microwave irradiation was faster and more rapidly reached the maximum temperature of the pressure bomb ($120^{\circ}C$) when the moisture content was higher. X-ray diffraction and DSC data revealed that the microwave irradiated starch underwent partial disruption of crystalline structure. RVA studies showed that the irradiation caused significant reductions in maximal viscosity and breakdown, whereas pasting temperature was increased. Overall trends revealed that the microwave irradiation on the starch containing limited moisture content (less than 35%) provided the effects similar to the heat moisture treatment. These effects became more significant when the moisture content was higher. Compared to waxy com starch, normal, and high amylose com starches appeared to be more susceptible to the microwave irradiation.

Effects of Soft Steam Treatments on Quality Characteristics of Potatoes (감자의 품질특성에 대한 저온스팀 열처리 방식의 효과)

  • Cheigh, Chan-Ick;Lee, Jin-Hee;Chung, Myong-Soo
    • The Korean Journal of Food And Nutrition
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    • v.25 no.1
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    • pp.50-56
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    • 2012
  • This paper examines the effects of various methods of soft steaming(i.e., forced convection-boiler, forced convection-fan, and natural convection) on the quality of potatoes. In particular, the paper investigates the effects of cooking conditions (the steaming method, the treatment time, and the temperature) on the color(L, a, b), moisture content, texture profile, and ascorbic acid of potatoes. The results indicate that not only the cooking method, the treatment time, and the temperature but also the heat transfer mechanism had considerable influence on potato quality. In addition, natural convection steaming was superior to other treatment methods in terms of nutrient retention and texture maintenance. The results of this study should be useful for establishing commercial standards for processing potatoes and improving the quality of thermally processed foods.

Enzymatic Hydrolysis of Marine Algae Hizikia fusiforme (해조류 톳 (Hizikia fusiforme)의 효소 가수분해)

  • Song, Bu-Bok;Kim, Sung-Koo;Jeong, Gwi-Taek
    • KSBB Journal
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    • v.26 no.4
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    • pp.347-351
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    • 2011
  • In this study, we investigated the effect of reaction factors on enzymatic hydrolysis of Hizikia fusiforme, which is brown algae in marine biomass resource, using commercial enzymes. The composition of H. fusiforme is 38.9% of reducing sugar, 4.8% of moisture, 17.8% of ash, and 38.5% of others. In the condition of 1-5% substrate, the increase of substrate concentration enhanced the increase of reducing sugar formation; however, the hydrolysis yield did not increase after 24 h. After reaction of 75 h, conversion yield of reducing sugar were obtained to 16.45%, 17.99%, and 14.55% at 1, 2.5, and 5% substrate, respectively. As a result of effect of enzyme amount, the formation of reducing sugar did not show considerable change at 1% substrate. However, in the condition of 2.5% substrate, the great change of reducing sugar formation was observed by the increase of enzyme amount. The conversion yields of reducing sugar were obtained to 18.77% and 22.83% at 1% and 2.5% substrate with 30% enzyme, respectively. As a result of heat treatment of biomass, the high yield was obtained in 2.5% substrate and the yields were increased to 0.06-7.2% by the heat treatment. This result will provide the basic information for production process of biofuels and chemicals from marine biomass H. fusiforme.

Study of the oriental medical literature for Hysterorrhea (대하(帶下) 치료(治療)에 대한 문헌적에 고찰)

  • Ryou, Dong-Hoon;Yoo, Dong-Youl
    • Journal of Haehwa Medicine
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    • v.13 no.2
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    • pp.303-315
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    • 2004
  • 1. The acupuncture & moxibustion of hysterorrhea is focussed on bloody uterine discharge, leukorrhea and we must carefully diagnose the etiology & the machanism of disease. 2. The causes of hysterorrhea are dampness, impairment of seven emotion, irregular food intake, excessive intercourse and they are impotantly related to liver, spleen, kidney, the ren channel the chong channel 3. Using external medical treatment for Leucorrhea is washing and fumigation on vagina, to wash vagina, to insert vagina, cleansing theraphy and use with Suppository such as YONGYEOMGO(龍鹽膏), KAMISASANGJASAN(加味蛇床子散), SASANGSACHUNGSEJE(蛇床子洗劑). 4. The efficacy of medicines to use external medical treatment is as follow to helpcirculation of blood, to warm spleen and stomach, to warm blood, to warm uterus and remove cold, to remove heat and dry moisture, to down heat-product, to contract bloodvessel, to counteract poison and destory virus, to make enerey and blood.. 5. The diagnosis is grossly divided into the flowing downward of damp-heat, the weaknessof the qi of the spleen, dificiency of yuan of the kidney and according to the each diagnosis we should select adquate points representing the treatment of cooling(zhongji, yinlingquan, xingjian, etc), desiccation, heiping qi(qihai, zusanli, sanyinjiao, etc), tonificating yang (guanyuan, mingmen, shinshu, etc). 6. The moxibustion is the warming the lower jiao and eliminating the cold, the points are the mingmen point, the zhongji point, the guanyuan point, etc 7. Besides the acupuncture & moxibustion of hysterorrhea, we can make use of acusetor, ear acupuncture, endermosis, dong shi shen fa.

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Effect of Moisture in a Vacuum Chamber on the Deposition of c-BN Thin Film using an Unbalanced Magnetron Sputtering Method (비대칭 마그네트론 스퍼터링 방법에 의한 질화붕소막의 증착시 반응실내의 초기 수분이 입방정질화붕소 박막의 형성에 미치는 영향)

  • Lee, Eun-Sook;Park, Jong-Keuk;Lee, Wook-Seong;Seong, Tae-Yeon;Baik, Young-Joon
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.620-624
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    • 2012
  • The role of moisture remaining inside the deposition chamber during the formation of the cubic boron nitride (c-BN) phase in BN film was investigated. BN films were deposited by an unbalanced magnetron sputtering (UBM) method. Single-crystal (001) Si wafers were used as substrates. A hexagonal boron nitride (h-BN) target was used as a sputter target which was connected to a 13.56 MHz radiofrequency electric power source at 400 W. The substrate was biased at -60 V using a 200 kHz high-frequency power supply. The deposition pressure was 0.27 Pa with a flow of Ar 18 sccm - $N_2$ 2 sccm mixed gas. The inside of the deposition chamber was maintained at a moisture level of 65% during the initial stage. The effects of the evacuation time, duration time of heating the substrate holder at $250^{\circ}C$ as well as the plasma treatment on the inside chamber wall on the formation of c-BN were studied. The effects of heating as well as the plasma treatment very effectively eliminated the moisture adsorbed on the chamber wall. A pre-deposition condition for the stable and repeatable deposition of c-BN is suggested.

The Expansive Properties of leaf tobacco by Nitrogen Gas (질소기체를 이용한 잎담배 팽화특성)

  • 김병구;정한주
    • Journal of the Korean Society of Tobacco Science
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    • v.19 no.1
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    • pp.70-75
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    • 1997
  • The expansive properties of leaf tobacco by nitrogen gas was investigated with cut tobacco AB3O-1, CD3L-1(NC82). Major factors for the best expansion of the tobacco by the gas were an impregnated pressure and expansion temperature. The expansion rate for AB3O-1 and CD3L-1 at 250℃, 750kg/cm2 was 96.6%, 99.4% respectively. The shred size and fineness index at 96.6% of expansion rate for AB3O-1 was almost the same as at 58.3% for CD3L-1. The time reaching at equilibrium moisture under of RH 57% was 36hr in non-treated leaf tobacco, but it was 20hr in expanded tobacco. We confirmed that total sugar contents of leaf tobacco by the expansion was decreased with 9.3∼10.9%. Total alkaloid was decreased with 17.5∼21.1% and ether extracts was declined with 4.9∼9.3%. These results suggest that the expansion method of leaf tobacco by nitrogen gas is a useful method without any serious environmental troubles. Key words : expansion, nitrogen gas, heat treatment, tobacco.

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A Study on the Silicidation of Thick Co/Ti Bilayer (두꺼운 이중층 Co/Ti 막의 실리사이드화에 관한 연구)

  • 이병욱;권영재;이종무;김영욱
    • Journal of the Korean Ceramic Society
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    • v.33 no.9
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    • pp.1012-1018
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    • 1996
  • To investigate the final structures and reactions of silicides a somewhat thick Ti monolayer Co monolayer and Co/Ti bilayer films were deposited on single Si(100) wafer by electron beam evaporation followed by heat treatment using RTA system in N2 ambient. TiO2 film formed between Ti and TiSi2 layers due to oxgen or moisture in the Ti monolayer sample. The final layer structure obtained after the silicidation heat-treatment of the Co/Ti bilayer sample turned out to be TiSi2/CoSi2/Ti-Co-Si alloy/CoSi2/Si sbustrate. This implies that imperfect layer inversion occurred due to the formation of Ti-Co-Si intermediate phase.

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Study on Heat Treatment of Red Pine Log (소나무 원목의 열처리에 관한 연구)

  • Eom, Chang-Deuk;Han, Yeonjung;Shin, Sang Chul;Chung, Yeong Jin;Jung, Chan Sik;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.6
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    • pp.50-56
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    • 2007
  • FAO standard for heat sterilization of wood, International standards for phytosanitary measures (ISPM) No.15, must meet heat-treated wood core temperature to be higher than $56^{\circ}C$ and keep the temperature for more than 30 minutes. This study was carried out to analyze the heat treatment characteristics of domestic pinewood sterilized with the FAO standard. To enhance the effectiveness of heat treatment process in mountainous district energy consumption and time required to reach target temperature were evaluated at various temperature and relative humidity conditions and moisture contents of wood. Heat-treatment of high temperature and high humidity reduced the required heating time. Lower humidity levels at same temperature reduced energy consumption per unit time. However, lower humidity levels could not reduce total energy consumption greatly because longer treatment time was required at that condition. It is necessary to estimate energy consumption and predict treatment time in dynamic heating and cooling situations, because it frequently happens not to meet optimum treatment condition due to poor surrounding climates and operation performance of heat treatment facility in real field.