• Title/Summary/Keyword: heat of hydration heat

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The research about properties of modified low heat slag cement (개질 처리된 저발열 슬래그시멘트 특성에 관한 연구)

  • Kim, Hong-Joo;Kim, Won-Ki;Kim, Hoon-Sang;Lee, Won-Jun;Shin, Jin-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.677-680
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    • 2008
  • The surface of particles was energetically modified by inter-grinding OPC and BFS in vibration mill for improvement of the early strength and low-heat evolution of concretes. BFS was pre-grinding in ball-mill to 2535(BS2) and 3245 $cm^2/g$(BS3), in blaine surface area. The inter-grinding time in vibration mill was changed from 10 minutes to 30 minutes. And Mixing ration of BFS to OPC was changed in 60, 70, 80%. After inter-grinding, the change of specific surface area, particle size distribution, hydration heat of cement and compressive strength of mortar were measured. As the result of comparison test with LHC, it was found that the mixture and inter-grinding time satisfying the value of over 100% of compressive strength for 7 days and under 170J/g of heat of hydration for 72 hours. and it was confirmed that the possibility of low heat slag cement utilizing blast furnace slag(BS2, BS3) with the low fineness in high volumes.

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A Study of Effecting Factor in the Reology and Physical Properties of Cements (시멘트 유동성과 물성에 미치는 영향인자에 관한 연구)

  • 엄태선;최상흘
    • Journal of the Korean Ceramic Society
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    • v.34 no.10
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    • pp.1027-1036
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    • 1997
  • The reology and several physical properties of cements are studied by varying the different mineral composition and particle size distribution(PSD) of cements with closed circuit ball mill for high workability, low heat of hydration, and high strength. In this study, we found that the workability of concretes is related to the viscosity of cement, and affects to strength. Here, this workability is affected by mineral composition (C3A) and the PSD. Especially, rosin-rammer index and 44${\mu}{\textrm}{m}$ residue in the PSD of cements are affected to water demand, casting property, slump loss, strength of cements. From the above results, the conditions of cement for high workability, low heat of hydration and high strength are to use low C3A clinker, 5-10% slag addition, and to grind cement below 0.7 rosin-rammer index, above 3.5-4.5% 44 ${\mu}{\textrm}{m}$ residue, 4000$\pm$100 $\textrm{cm}^2$/g blaine. Such cements are, therefore, supurior to super low heat cement and slag-blended cement in comparing the physical properties of strength, slump, slump-flow, adiabetic temperature, etc.

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Synthesis of Highly Dispersed Graphene Oxide-functionalized Carbon Nanotubes Complexes and its Effect on the Reinforcing the Properties of Cement Paste (산화그래핀-기능성 탄소나노튜브 복합체 합성 및 시멘트 내 혼입 시 물성에 미치는 영향)

  • Li, Pei-Qi;Liu, Jun-Xing;Suh, Heong-Won;Bae, Sung-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.27-28
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    • 2020
  • In this paper, we investigated the performance of synthetic graphene oxide-functionalized carbon nanotubes (GF) to promote cement hydration and increase the mechanical properties of cement paste. The enhancement effect of GF on the various properties of cement paste was evaluated via the mechanical strength, X-ray diffraction, and heat of hydration of cement paste. The results clearly showed that GF incorporation into cement paste promotes the early hydration of cement paste, generates more hydration products, which results in the mechanical improvement of cement paste. The compressive and splitting tensile strength were increased by 32.17% and 17.31%, respectively, compared to ordinary Portland cement at 28 days of hydration.

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Effect of Sodium Gluconate on the Hydration of Tricalcium Aluminate(II) Early Hydration Behavior (3CaO.$Al_2O_3$의 수화반응에 미치는 글루콘산 나트륨의 영향(II) 초기 수화 거동)

  • 김창은;이승헌
    • Journal of the Korean Ceramic Society
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    • v.23 no.6
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    • pp.1-6
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    • 1986
  • The hydration of $C_3A$ and $C_3A-CaSO_4$.$2H_2O$ was investigated with varying concentration (0.1-1.0%) of sodium gluconate solution. gluconate solution. Sodium gluconate accelerates cation dissolution from $C_3A$ for the first several minutes but depresses the rate of heat evolution in the course of $C_3A$ hydration. The hydration of $C_3A$ in the presence of sodium gluconate was modified such that the formation of the intermediate hydrate C4AH$\chi$ crystal was much reduced and most of the product became amorphous. The retardation of $C_3A-CaSO_4$.$2H_2O$ hydration in the presence of sodium gluconate was controlled by the competitive adsorption between gluconate anion and $SO_4^{-2}$ onto $C_3A$ surface.

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Prediction of temperature distribution in hardening silica fume-blended concrete

  • Wang, Xiao-Yong
    • Computers and Concrete
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    • v.13 no.1
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    • pp.97-115
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    • 2014
  • Silica fume is a by-product of induction arc furnaces and has long been used as a mineral admixture to produce high-strength, high-performance concrete. Due to the pozzolanic reaction between calcium hydroxide and silica fume, compared with that of Portland cement, the hydration of concrete containing silica fume is much more complex. In this paper, by considering the production of calcium hydroxide in cement hydration and its consumption in the pozzolanic reaction, a numerical model is proposed to simulate the hydration of concrete containing silica fume. The heat evolution rate of silica fume concrete is determined from the contribution of cement hydration and the pozzolanic reaction. Furthermore, the temperature distribution and temperature history in hardening blended concrete are evaluated based on the degree of hydration of the cement and the mineral admixtures. The proposed model is verified through experimental data on concrete with different water-to-cement ratios and mineral admixture substitution ratios.

An Experimental Study on Workability for Practical Use of High-Performance Concrete (고성능 콘크리트의 실용화를 위한 시공특성에 관한 실험적 연구)

  • Yang, Keun-Hyeok;Lee, Young-Ho
    • Journal of the Korea Institute of Building Construction
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    • v.3 no.1
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    • pp.139-146
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    • 2003
  • The special requirements of high-performance concrete(HPC) could be enhanced property over others such as compressive strength, durability, and construction practices. In order to satisfy these requirements a series of laboratory trial mixes and following mock-up test of reinforced concrete wall at field were performed in this study. The objective of this study was to quantitatively evaluate the workability, compressive strength, and the increased heat of hydration caused by the increase of the specific weight of cement according to various variables. Six example series designed about a minimum compressive strength of 500kgf/$\textrm{cm}^2$ at 28 days, and an approximately slump and slump flow of 25cm and 60cm respectively were tested. The selection process of the specific weight of water and the percentage of fly-ash transposition determined to be most suitable for the production of HPC is presented in the following paper.

Comparative Analysis of Temperature and Setting Time of Concrete According to Types of Cements (시멘트 종류 변화에 따른 콘크리트의 온도 및 응결시간 비교분석)

  • Choi, Yoon-Ho;Kim, Sang-Min;Hyun, Seung-Yong;Kim, Jong;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.29-30
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    • 2020
  • In this study, as part of the foundation for advancing the material compounding aspect to reduce hydration heat cracks in the mat foundation on which the mass concrete is constructed, the degree of concrete varieties of cement is used. The setting time was measured and comparative analysis was performed. Results It was confirmed that the concrete using LHC was more effective than the concrete using OPC in reducing the use of SP, the calorific value of the concrete was low, and it was more effective in preventing cracks. It is also terminated after 10 hours and it is determined that the use of LHC can reduce the cracks caused by the heat of hydration of the mat foundation.

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A Study of Properties of Drying Shrinkage and Creep of Concrete Incorporating Hwangtoh and Blast Furnace Slag (황토와 고로슬래그를 첨가한 콘크리트의 건조수축 및 크리프 특성에 관한 연구)

  • Kang, Hong-Ki;Yang, Keun-Hyeok;Lee, Young-Ho;Hwang, Hey-Zoo;Chung, Heon-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.612-615
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    • 2004
  • The objective of this experimental study was to understand inelastic strain of concrete incorporating hwangtoh or combination of hwangtoh and slag. Main variables were replacement level of admixtures, hwangtoh and slag. We studied the properties of concrete such as heat of hydration, drying shrinkage and creep according to the replacement level of hwangtoh and slag. Test results showed that the heat of hydration of concrete decrease with increasing hwangtoh and slag replacement. Also drying shrinkage and creep of concrete increase with increasing hwangtoh replacement.

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A Method on the Control of Hydration Heat of Mass Concrete Considering the Difference of Setting Time (응결시간차를 활용한 매스콘크리트의 수화열 조정공법)

  • 심보길;윤치환;한민철;김기철;오선교;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.379-384
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    • 2001
  • This Paper Presents field application test results of mass concrete using super retarding agent. The field test was carried out at mat foundation(thickness 1m) of newly constructed information center of Chongju university. Placing lift composed of 2 layers, and each layer is 50cm. Fly ash and flowing method is also applied. Difference of setting time of concrete between with super retarding agent and without super retarding agent is considered. Concrete without super retarding agent is placed at upper layer and with super retarding agent at lower layer According to test results, the reducing method of hydration heat considering difference of setting time with super retarding agent can reduce the highest temperature about 3~4$^{\circ}C$, and delay the peak time about 3~4days. Compressive strength using super retarding agent is somewhat higher than that of normal concrete. Accordingly, super retarding agent does not affect the strength development.

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Physical Properties of Cement Mortar using Aluminum Sulfate as Admixture for Early Strength (초기강도 증진을 위한 황산알루미늄 혼입 시멘트 모르타르의 물리적 특성)

  • 강내민;문경주;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.293-296
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    • 2003
  • The purpose of this study is to examine the effect of aluminium sulfate on setting time and compressive strength of cement mortar as focused on formation of ettringite by the reaction between aluminium sulfate and calcium hydrate. The specific parameter was the addition ratio of aluminium sulfate to cement mortar. After specimens made by admixing aluminium of 0~7% by weight of cement, respectively, to cement mixtures, the experimental items such as setting time, compressive strength and heat of hydration in this study were carried out. As a result of this study, it is possible that aluminium sulfate could be added into cement mixture from a standpoint of increasing early compressive strength as considering the setting time and heat of hydration.

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