• The Journal of Korean Academy of Prosthodontics
• /
• v.31 no.3
• /
• pp.385-393
• /
• 1993

Injection processing of denture base resin was introduced by Pryer in 1942, in an attempt to reduce processing shrinkage. More recently a continuous-pressure injection type technique has been developed (SR-Ivocap, Ivoclar AG, Schaan, Liechtenstein.), and it reduced processing error and increased resin density. The purpose of this study was to compare tensile bond strength of heat-cured, cold-cured, and light-cured denture base resin bonded to continuous-pressure injection type resin. To know it, 60 cylindrical resin specimens were fabricated, and tensile bond strength were measured. The results were as follows : 1. The mean tensile bond strength bonded to continuous-pressure injection type resin was lower than bonded to conventional heat cured resin. But tensile bond strength of conventional heat cured resin bonding with light cured resin was lower than continuous-pressure injection type resin. 2. Of the tensile bond strength bonded to continuous-pressure injection type resin, tensile bond strength bonding with continuous-pressure injection type resin was the greatest(but not significantly different from bonding with conventional heat cured resin), followed by cold-cured, light-cured resin. 3. Of the tensile bond strength bonded to conventional heat cured resin, tensile bond strength bonding with conventional heat cured resin was the greatest and followed by continuous-pressure injection type resin, cold-cured resin, light-cured resin. According to these results, bonding of continuous-pressure injection type resin with conventional heat cured resin or continuous-pressure injection type resin is acceptable, but bonding with light-cured resin is questionable.

• The Journal of Korean Academy of Prosthodontics
• /
• v.24 no.1
• /
• pp.33-43
• /
• 1986

The purpose of this study was to compare the wear resistance of heat pressure-cured microcomposite(SR-Isosit-N), photo-cured microcomposite(Dentalcolor), unfilled heat-cured resin(Thermojel) and that of human enmel. Specimens were made with specially designed die and finally polished with #3,000 diamond paste. After 100,000 strokes of tooth brushing at electric tooth-brushing machine, mean thickness loss of each specimen was measured by using surface profile and integration. The results were as follows 1. Mean thickness loss were $84.3{\pm}27.3{\mu}m$ in unfiled heat-cured resin, $9.4{\pm}2.5{\mu}m$ in photocured microcomposite, $7.6{\pm}2.1{\mu}m$ in heat.pressure-cured microcomposite and $0.97{\pm}0.42{\mu}m$ in enamel. 2. Heat.pressure-cured microcomposite and photo-cured microcomposite had no difference in mean thickness loss(p>0.05). 3. Unfilled resin and microcomposite had much differences in mean thickness loss (p<0.005). 4. ha resins used in this experiment had too much mean thickness loss as compared with enamel (p<0.005).

• The Journal of Korean Academy of Prosthodontics
• /
• v.31 no.1
• /
• pp.11-18
• /
• 1993

Autopolymerising and visible light cured resin are used to reline dentures. But relined surface are easily contaminated by water or saliva in the mouth during clinical procedure. This study was to find out the effect of surface contamination on the transverse strength of the relined denture base. To accomplish this, the specimens of $65\times10\times3mm$ were made with heat-cured(Lucitone 199), visible light-cured(Triad), and autopolymerizing resin(Kooliner). Measurements of transverse strength were taken for each specimen. Specimens made of heat-cured resins, sizing $65\times10\times1.5mm$, were relined with heat-cured, light-cured, and autopolymerizing resin, respectively. Specimens relined with autopolymerizing and light-cured resins were further classified into not-contaminated, water-contaminated and saliva-contaminated groups. Again, measurements of the transverse strength were taken for each group. The results were as follows 1. The transverse strength of heat-cured resin was superior to all the other resins. 2. The transverse strength of each specimen decreased after relining in the following order, heat-cured, visible light-cured, and autopolymerizing resin. 3. Surface contamination produced an decrease in transverse strength, especially in the saliva contaminated group. According to these results, water or saliva contamination should be avoided during intraoral relining procedures.

• Restorative Dentistry and Endodontics
• /
• v.20 no.2
• /
• pp.827-831
• /
• 1995

This study was designed to etermine the changes in the degree of conversion for composite resins after heat curing following the methods proposed by Lee & Park(1995). 8-mm diameter hole was made in 1mm teflon plate and one of three types of composites (Charisma, Brilllant, Z100) was placed and light cured for 60seconds. The samples were devided into 3 groups according to the placing composites. After light curing, the samples were separated from the moulds. Using this method, 10 samples were prepared in each group; 5 samples from each group were heat cured according to the methods proposed by manutfactures, These samples were then thinned to 50-$70{\mu}m$ and analysed with a Fourier Transform Infrared Spectrometer. Standard baseline technique was used to calculate the degree of conversion. When the samples were light cured, the degrees of conversion in each groups were 47.1 % (charisma), 53.3% (Z100), and 70.1 % (Brilliant). The degree of conversion after heat curing were; 60.1 % (Charisma), 71.1 % (Z100), and 73.3 % (Brillant). Once the samples were heat cured, there were significant increases in degree of conversion.

• The Journal of Korean Academy of Prosthodontics
• /
• v.30 no.3
• /
• pp.401-410
• /
• 1992

The purpose of this study was to investigate the dimensional changes and surface morphology of dentures processed by various polymerization conditions. The measurements were done by taking radiograph and using vernier calipers and each specimen was observed on scanning electron microscope. Results obtained were as follows. 1. The difference of dimensional stability was not recognized between various polymerization conditions(heat-cured resin, pour-type resin, microwave-cured resin, and injection molding resin). 2. There were expansion and shrinkage in the occlusal dimension, shrinkage in the frontal dimension, and expansion in the lateral dimension. 3. Scanning electron microscope pictures of heat-cured resin showed dense and regular surface morphology. 4. Microwave-cured resin surface appeared more regular and smooth than pour-type resin but less dense and more irregular than heat-cured resin. 5. Scanning electron microscope pictures of pour-type resin with the lowest dimensional change showed the most irregular surface morphology.

• Restorative Dentistry and Endodontics
• /
• v.24 no.2
• /
• pp.265-285
• /
• 1999

The purposes of this investigation were to observe the reaction kinetics of five commercial dual cured resin cements (Bistite, Dual, Scotchbond, Duolink and Duo) when cured under varying thicknesses of porcelain inlays by chemical or light activation and to evaluate the effect of the porcelain disc on the rate of polymerization of dual cured resin cement during light exposure by using thermal analysis. Thermogravimetric analysis(TGA) was used to evaluate the weight change as a function of temperature during a thermal program from $25{\sim}800^{\circ}C$ at rate of $10^{\circ}C$/min and to measure inorganic filler weight %. Differential scanning calorimetry(DSC) was used to evaluate the heat of cure(${\Delta}H$), maximum rate of heat output and peak heat flow time in dual cured resin cement systems when the polymerization reaction occured by chemical cure only or by light exposure through 0mm, 1mm, 2mm and 4mm thickness of porcelain discs. In 4mm thickness of porcelain disc, the exposure time was varied from 40s to 60s to investigate the effect of the exposure time on polymerization reaction. To investigate the effect on the setting of dual cured resin cements of absorption of polymerizing light by porcelain materials used as inlays and onlays, the change of the intensity of the light attenuated by 1mm, 2mm and 4mm thickness of porcelain discs was measured using curing radiometer. The results were as follows 1. The heat of cure of resin cements was 34~60J/gm and significant differences were observed between brands (P<0.001). Inverse relationship was present between the heat of reaction and filler weight % the heat of cure decreased with increasing filler content (R=-0.967). The heat of reaction by light cure was greater than by chemical cure in Bistite, Scotchbond and Duolink(P<0.05), but there was no statistically significant difference in Dual and Duo(P>0.05). 2. The polymerization rate of chemical cure and light cure of five commercially available dual cured resin cements was found to vary greatly with brand. Setting time based on peak heat flow time was shortest in Duo during chemical cure, and shortest in Dual during light cure. Cure speed by light exposure was 5~20 times faster than by chemical cure in dual cured resin cements. The dual cured resin cements differed markedly in the ratio of light and chemical activated catalysts. 3. The peak heat flow time increased by 1.51, 1.87, and 3.24 times as light cure was done through 1mm, 2mm and 4mm thick porcelain discs. Exposure times recommended by the manufacturers were insufficient to compensate for the attenuation of light by the 4mm thick porcelain disc. 4. A strong inverse relationship was observed between peak heat flow and peak time in chemical cure(R=0.951), and a strong positive correlations hip was observed between peak heat flow and the heat of cure in light cure(R=0.928). There was no correlationship present between filler weight % or heat of cure and peak time. 5. The thermal decomposition of resin cements occured primarily between $300^{\circ}C$ and $480^{\circ}C$ with maximum decomposition rates at $335^{\circ}C$ and $440^{\circ}C$.

• The Journal of Korean Academy of Prosthodontics
• /
• v.41 no.3
• /
• pp.360-368
• /
• 2003

Statement of Problem: The residual monomer of denture base materials causes hypersensitivity on oral mucosa and intereferes with the mechanical properties of the cured resin. The amount of residual monomer is influenced by materials, curing cycle, processing method, and etc. Purpose: The aim of this study was to investigate the residual methyl methacrylate(MMA) content of injection molded denture base polymer, and to compare this with the self-cured resin and the conventional compression molded heat-cured resin. Materials and Methods: Disc shaped test specimens (50mm in diameter and 3mm thick) were prepared in a conventional flasking technique with gypsum molding. One autopolymerized denture base resins (Vertex Sc. Dentimex. Netherlands) and two heat-cured denture base resins (Vertex RS. Dentimex. Netherlands, Ivocap. Ivoclar Vivadent, USA) were used. The three types of specimens were processed according to the manufacturer's instruction. After polymerization, all specimens were stored in the dark at room temperature for 7 days. There were 10 specimens in each of the test groups. 3-mm twist drills were used to obtain the resin samples and 650mg of the drilled sample were collected for each estimation. Gas chromatography (Agillent 6890 Plus Gas Chromatograph, Agillent Co, USA) was used to determine the residual MMA content of 10 test specimens of each three types of polymer. Results: The residual monomer content of injection molded denture base resins was $1.057{\pm}0.141%$. The residual monomer content of injection molded denture base resins was higher than that of compression molded heat cured resin ($0.867{\pm}0.169%$). However, there was no statistical significant difference between two groups (p>0.01). The level of residual monomer in self cured resin($3.675{\pm}0.791$) was higher than those of injection molded and compression molded heat cured resins (p<0.01). Conclusion: With respect to ISO specification pass / fail test (2.2% mass fraction) of residual monomer, injection molding technique($1.057{\pm}0.141%$) is a clinically useful and safe technique in terms of residual monomer.

• Proceedings of the KIEE Conference
• /
• 1996.07c
• /
• pp.1697-1699
• /
• 1996

EPDM compound can be cured with either the sulfur and peroxide based systems. In this study, heat resistance and weatherability of EPDM compounds depending on curing systems were investigated. The test results showed that the peroxide-cured EPDM was more resistant to heat ageing and UV photo-degradation than the sulfur-cured EPDM and it is due to C-C bond is more stable than C-S, S-S bond.

• Restorative Dentistry and Endodontics
• /
• v.19 no.1
• /
• pp.135-147
• /
• 1994

This study was conducted to evaluate whether the fatigue toughness of visible light cured composite resins could be improved and how much percentage of polymerzation shrinkage could be affected by additional heat treatment. 7 materials were investigated for this study: P-50, Lite-fil CR inlay, Pekafil, Clearfil CR inlay, Clearfil photo posterior, Z -100 and Progress. Diametral tensile strengths and linear shrinkages of composite resins were taken under visible light cured and additional post-cure heated condition and compared each other. A fatigue toughness of above materials was evaluated by measuring diametral tensile strength after they were repeatedly loaded with 120kgf/$cm^2$ up to 3000 cycles. The results obtained were as follows : 1. When composite resins were cured just by visible light, Lite fil CR inlay, Z -100 and Progress showed respectively higher diametral tensile strength than the other materials. Clearfil CR inlay, Clearfil photo posterior and Progress exhibited strong fatigue toughness compared to P-50 and Pekafil. 2. Post-cure heat treated composite resins had higher diametral tensile strengths than visible light cured composite resins at fatigue toughness test as well as no fatigue toughness test. 3. When Composite resins were additionally polymerized by post-cure heat treatment, P-50 showed weak fatigue toughness, on the contrary, Clearfil CR inlay, Z-100, Progress showed strong one. 4. When composite resins were cured just by visible light, percentage of polymerization linear shrinkage was the lowerest in Clearfil CR inlay, followed by, in ascending order, Clearfil photo posterior, Lite-fil CR inlay, Progress, Pekafil, P-50, and Z-100. In the case of post- cure heat treated composite resins, percentage of linear shrinkage was the lowest in Clearfil photo posterior, followed by, in ascending order, Lite-til CR inlay, Clearfil CR inlay, Progress, P-50, Pekafil and Z-100. 5. Percentage of polymerization linear shrinkage was greater in the post-cure heat treated composite resins than in the visible light cured composite resins and linear shrinkage increased significantly in Pekafil, Clearfil CR inlay, and Clearfil photo posterior between at the visible light cured and at the post-cure heat treated condition. The above results is saying that additional post-cure heat treatment on the composite resins for posterior restoration is able to affect on improvement of strength and fatigue toughness and lead to increase polymerization of composite resins.

• Textile Coloration and Finishing
• /
• v.11 no.6
• /
• pp.7-17
• /
• 1999

Aminophosphazene derivatives were prepared from hexachlorocyclotriphosphazene and used for the curing agents of epoxy resins. The effect of the curing agent on the dynamic viscoelastic properties, flame proofing, and heat resistance of the cured epoxy resins were investigated and compared with those for the epoxy resins cured with aliphatic and aromatic amines. The epoxy resin cured by 1,1-diamino-3,3,5,5-tetrachlorocyclotriphosphazene showed the highest storage modulus and glass transition temperature when cured at 19$0^{\circ}C$ for 6 hours. The epoxy resins cured with phosphazene derivatives showed superior flame proofing to those with aliphatic amine and aromatic amine. Particularly it is an effective curing agent for epoxy resins to enhance the storage modulus, flame proofing and resistance to heat.