• Title/Summary/Keyword: heat and mass transfer

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Predictions of Heat and Mass Transfer Rates to a Spray Droplet Experiencing Condensation (응축을 수반하는 분무수적으로의 열 및 질량전달률 예측)

  • 이상균;조종철;신원기;조진호;서정일
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.5
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    • pp.1763-1773
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    • 1991
  • 본 연구에서는 포화수증기와 공기의 혼합기내에서 분무수적으로의 열 및 질량 전달률을 계산하기 위하여 수적의 부분혼합모형과 비혼합모형에 대하여 수적내 과도온 도분포의 해석해를 적용성이 보장되면서도 계산상의 어려움이 수반되지 않는 형태로 구하기 위하여 수적내부의 열전도해석에 있어서 적분법을 적용하였다. 적분법으로 얻어지는 과도온도분포의 해는 유한차의 다항식으로 표시되어 비혼합모형인 경우 각시 간 구간의 경계에서의 온도분포가 연속성을 유지하면서 물성치들의 온도에 대한 종속 성이 쉽게 고려되고 계산도 용이한 형태이다. 본 보에서 제시하는 해석결과의 적용 성을 조사하기 위하여 완전혼합모형을 포함하는 세가지 수적모형들에 대한 계산결과들 로부터 얻어진 시간변화에 따른 수적의 무차원 체적평균온도변동을 유효한 실험결과들 과 비교, 검토하였으며, 부분혼합모형에 대하여 혼합기의 압력, 수적의 초기온도, 혼 합기 속에 포함되어 있는 수증기의 체적분율, 수적의 초기크기, 수적의 초기속도 및 분사각도가 주위혼합기로부터 수적으로 전달되는 열 및 질량전달에 미치는 영향을 조] 사하고 도출된 대표적인 검토 결과를 제시하였다.

Characteristics of Bio-oil by Pyrolysis with Pig Feces (돈분을 이용한 열분해공정 바이오오일의 특성)

  • Kun, Zhu;Choi, Hong L.
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.4
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    • pp.57-63
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    • 2008
  • The characteristics of the bio-oil produced by the pyrolysis process with pig feces was investigated in this paper. The continuous auger-type reactor produced bio-oil was maintained at the temperature range of 400 to $600^{\circ}C$, which was higher than a typical that in a conventional pyrolysis system. The pig feces was used as the feedstock. The bio-oil and its compositions were characterized by water analysis, heating values, elemental analysis, bio-oil compounds, by Gas Chromatography/Mass Spectrometry (GC/MS), and functional group by $^1H$ NMR spectroscopy. It was found that the maximum bio-oil yields of 21% w.t. was achieved at $550^{\circ}C$. This result suggested that this auger reactor might be a potential technology for livestock waste treatment to produce bio-oil because it is able to be improved to reach higher efficiency of bio-oil production in further study. The pyrolysis system reported herein had low heat transfer into the feedstock in the auger reactor so that it needs improve the heat conduction rate of the system in further study.

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Experimental Study on the Dependence of Variation in Performance of a High-Temperature Generator on Its Operating Conditions (운전조건 변화가 고온재생기의 성능에 미치는 영향에 관한 실험적 연구)

  • Bae, Kyungjin;Kwak, Myoungseok;Cho, Honghyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.5
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    • pp.389-397
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    • 2014
  • An absorption chiller-heater using only a natural refrigerant hardly causes any environmental pollution. In an absorption chiller-heater, the performance of its high-temperature generator, which uses exhaust gases, is essential to achieving superior system performance. To investigate the performance of such a high-temperature generator, a laboratory-scale high-temperature generator working with exhaust gases was designed and tested. Changes in the performance of the high-temperature generator as a function of inlet conditions of the absorbing solution, such as air inlet temperature and mass flow, were investigated. It was observed that when the air mass flow rate ratio was increased from 80% to 120%, the heat capacity was increased by 30%, 33%, 34%, and 37%, respectively. Additionally, when the air inlet temperature was elevated from $170^{\circ}C$ to $210^{\circ}C$ for absorption solution concentrations of 56%, 55%, 545, and 53%, the heat capacity increased by 140%, 160%, 220%, and 224%, respectively.

Research on the Performance of Total Heat Exchanger in a Solar Air-Conditioning System (태양열 이용 냉난방 공조시스템 중 전열교환기 성능에 관한 연구)

  • Kim, K.H.;Choi, K.H.;Kum, J.S.;Kim, B.C.;Kim, J.R.
    • Solar Energy
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    • v.19 no.4
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    • pp.45-53
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    • 1999
  • This report Introduces a total heat exchanger in a solar air-conditioning system using Lithium Chloride(LiCl) solution. The hot and humid outside air is cooled and dehumidified by LiCl solution that is sprayed on the packed layer of the total heat exchanger. LiCl solution once diluted is concentrated again in a regenerator using solar energy. Three types as the packed materials were used in this experiment and the dehumidification performance was evaluated by the value of $k_xa(kg/h{\cdot}m^3{\cdot}{\Delta}x)$, overall mass transfer coefficient based on a humidity ratio potential difference, the influence of inlet LiCl solution flow rate, air flow rate, packed layer height on $k_xa$ was investigated. It was found that air flow rate, LiCl solution flow rate, packed layer height for all types had a great influnce on the value of $k_xa$.

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Development of Summer Leaf Vegetable Crop Energy Model for Rooftop Greenhouse (옥상온실에서의 여름철 엽채류 작물에너지 교환 모델 개발)

  • Cho, Jeong-Hwa;Lee, In-Bok;Lee, Sang-Yeon;Kim, Jun-Gyu;Decano, Cristina;Choi, Young-Bae;Lee, Min-Hyung;Jeong, Hyo-Hyeog;Jeong, Deuk-Young
    • Journal of Bio-Environment Control
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    • v.31 no.3
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    • pp.246-254
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    • 2022
  • Domestic facility agriculture grows rapidly, such as modernization and large-scale. And the production scale increases significantly compared to the area, accounting for about 60% of the total agricultural production. Greenhouses require energy input to create an appropriate environment for stable mass production throughout the year, but the energy load per unit area is large because of low insulation properties. Through the rooftop greenhouse, one of the types of urban agriculture, energy that is not discarded or utilized in the building can be used in the rooftop greenhouse. And the cooling and heating load of the building can be reduced through optimal greenhouse operation. Dynamic energy analysis for various environmental conditions should be preceded for efficient operation of rooftop greenhouses, and about 40% of the solar energy introduced in the greenhouse is energy exchange for crops, so it should be considered essential. A major analysis is needed for each sensible heat and latent heat load by leaf surface temperature and evapotranspiration, dominant in energy flow. Therefore, an experiment was conducted in a rooftop greenhouse located at the Korea Institute of Machinery and Materials to analyze the energy exchange according to the growth stage of crops. A micro-meteorological and nutrient solution environment and growth survey were conducted around the crops. Finally, a regression model of leaf temperature and evapotranspiration according to the growth stage of leafy vegetables was developed, and using this, the dynamic energy model of the rooftop greenhouse considering heat transfer between crops and the surrounding air can be analyzed.

Effect of physicochemical properties and feed mix ratios on the carbothermic reductions of iron ore with coke

  • S.R.R. Munusamy;S. Manogaran;F. Abdullah;N.A.M. Ya'akob;K. Narayanan
    • Advances in materials Research
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    • v.13 no.3
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    • pp.161-171
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    • 2024
  • This study aimed to investigate the effect of physicochemical properties and mix ratios of iron ore (oxide feed): coke (reductant) on the carbothermic reductions of iron ore. Coke size was fixed at ≤63 ㎛ while iron ore size varied between 150-63 ㎛ and ≤63 ㎛ respectively. Mix ratios were changed from 100:0 (reference) to 80:20 and 60:40 while the temperature, heating rate and soaking duration in muffle furnace were fixed at 1100 ℃, 10 ℃/min and 1 hour. Particle size analyzer, XRF, CHNS and XRD analyses were used for determination of raw feed characteristics. The occurrence of phase transformations from various forms of iron oxides to iron during the carbothermal reductions were identified through XRD profiles and supported with weight loss (%). XRF analysis proved that iron ore is of high grade with 93.4% of Fe2O3 content. Other oxides present in minor amounts are 2% Al2O3 and 1.8% SiO2 with negligible amounts of other compounds such as MnO, K2O and CuO. Composite pellet with finer size iron particles (≤63 ㎛) and higher carbon content of 60:40 exhibited 45.13% weight lost compared to 32.30% and 3.88% respectively for 80:20 and 100:0 ratios. It is evident that reduction reactions can only occur with the presence of coke, the carbon supply. The small weight loss of 3.88% at 100:0 ratio occurs due to the removal of moisture and volatiles and oxidations of iron ore. Higher carbon supply at 60:40 leads into better heat and mass transfer and diffusivity during carbothermic reductions. Overall, finer particle size and higher carbon supply improves reactivity and gas-solid interactions resulting in increased reductions and phase transformations.

Numerical Study on the Injector Shape and Location of Urea-SCR System of Heavy-duty Diesel Engine for Preventing $NH_3$ Slip (대형 디젤엔진용 SCR 시스템의 암모니아 슬립 억제를 위한 인젝터의 형상 및 위치에 관한 수치적 연구)

  • Jeong Soo-Jin;Lee Sang Jin;Kim Woo-Seung;Lee Chun Beom
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.1
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    • pp.68-78
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    • 2006
  • In the past few years, considerable efforts have been directed towards the further development of Urea-SCR(selective catalytic reduction) technique for diesel-driven vehicle. Although urea possesses considerable advantages over Ammonia$(NH_3)$ in terms of toxicity and handling, its necessary decomposition into Ammonia and carbon dioxide complicates the DeNOx process. Moreover, a mobile SCR system has only a short distance between engine exhaust and the catalyst entrance. Hence, this leads to not enough residence times of urea, and therefore evaporation and thermolysis cannot be completed at the catalyst entrance. This may cause high secondary emissions of Ammonia and isocyanic acid from the reducing agent and also leads to the fact that a considerable section of the catalyst may be misused for the purely thermal steps of water evaporation and thermolysis of urea. Hence the key factor to implementation of SCR technology on automobile is fast thermolysis, good mixing of Ammonia and gas, and reducing Ammonia slip. In this context, this study performs three-dimensional numerical simulation of urea injection of heavy-duty diesel engine under various injection pressure, injector locations and number of injector hole. This study employs Eulerian-Lagrangian approach to consider break-up, evaporation and heat and mass-transfer between droplet and exhaust gas with considering thermolysis and the turbulence dispersion effect of droplet. The SCR-monolith brick has been treated as porous medium. The effect of location and number of hole of urea injector on the uniformity of Ammonia concentration distribution and the amount of water at the entrance of SCR-monolith has been examined in detail under various injection pressures. The present results show useful guidelines for the optimum design of urea injector for reducing Ammonia slip and improving DeNOx performance.

Hydrogen Absorption and Desorption Behaviors of the Metal Hydride Fuel Tank for Hydrogen Vehicle (수소저장합금을 이용한 수소자동차 연료저장탱크의 수소흡수-방출거동에 관한 연구)

  • Lee, Soo-Geun;Lee, Han-Ho;Jung, Jai-Han;Kim, Dong-Myung;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.5 no.2
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    • pp.81-90
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    • 1994
  • The hydrogen fuel tanks having hydrogen storing capacity of about 300g and 1200g are manufactured using $MmNi_{4.7}Al_{0.25}V_{0.05}Fe_{0.001}$ alloy. They are composed of several unit reactor made of Cu-tube(outer diameter = 50.1mm, thickness = 2mm). In order to increase the heat and mass transfer property of the hydride bed, Al-plates are inserted perpendicular to axial direction at intervals of 5mm and three arteries of diameter 8mm are installed symmetrically in each unit reactor. Hydrogen absorption is proceeded about 80% within 30 minute and is completed within 60 minute at the conditions of charging hydrogen pressure of 25atm and temperature of $22^{\circ}C$. On desorbing hydrogen at a constant rate of 30 slm at $20^{\circ}C$, discharging hydrogen pressure is sustained at 3~5atm for 120 minutes. The discharging pressure is increased upto 5~8atm as the increase of the reactor temperature to $30^{\circ}C$. From the experimental results and the brief discussions about the hydrogen absorption and disorption behaviors of the hydrogen storage tank, it is suggested that the behaviors of hydrogen charging and discharging could be controlled by adjusting the operating parameters and the reactor design parameters.

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Enzymatic Synthesis and Characterization of Galactosyl Trehalose Trisaccharides

  • Kim, Bong-Gwan;Lee, Kyung-Ju;Han, Nam-Soo;Park, Kwan-Hwa;Lee, Soo-Bok
    • Food Science and Biotechnology
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    • v.16 no.1
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    • pp.127-132
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    • 2007
  • [ ${\alpha},\;{\alpha}$ ]-Trehalose was efficiently modified by a transgalactosylation reaction of Escherichia coli ${\beta}-galactosidase$ using lactose as a donor to yield two galactosyl trehalose trisaccharides. The reaction products of trehalose by the enzyme were observed by thin layer chromatography (TLC) and high performance anion exchange chromatography (HPAEC) and were purified by BioGel P2 gel permeation chromatography and recycling preparative HPLC. Liquid chromatography-mass spectrometry (LC-MS) and ^{13}C$ nuclear magnetic resonance (NMR) analyses revealed that the structures of the main products were $6^2-{\beta}-D-galactosyl$ trehalose (1) and $4^2-{\beta}-D-galactosyl$ trehalose (2). A reaction of 30%(w/v) trehalose and 15%(w/v) lactose at pH 7.5 and $45^{\circ}C$ resulted in a total yield of approximately 27-30% based on the amount of trehalose used. The galactosyl trehalose products were not hydrolyzed by trehalose. In addition the mixture of transfer products (9:1 ratio of 1 to 2) showed higher thermal stability than glucose, lactose, and maltose, but less than trehalose, against heat treatment over $100^{\circ}C$ at pH 4 and 7. It also exhibited better thermal stability than sucrose at pH 4 alone.

Analysis on the Pyrolysis Characteristics of Waste Plastics Using Plug Flow Reactor Model (Plug Flow Reactor 모델을 이용한 폐플라스틱의 열분해 특성 해석)

  • Sangkyu, Choi;Yeonseok, Choi;Yeonwoo, Jeong;Soyoung, Han;Quynh Van, Nguyen
    • New & Renewable Energy
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    • v.18 no.4
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    • pp.12-21
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    • 2022
  • The pyrolysis characteristics of high-density polyethylene (HDPE), low-density polyethylene (LDPE), and polypropylene (PP) were analyzed numerically using a 1D plug flow reactor (PFR) model. A lumped kinetic model was selected to simplify the pyrolysis products as wax, oil, and gas. The simulation was performed in the 400-600℃ range, and the plastic pyrolysis and product generation characteristics with respect to time were compared at various temperatures. It was found that plastic pyrolysis accelerates rapidly as the temperature rises. The amounts of the pyrolysis products wax and oil increase and then decrease with time, whereas the amount of gas produced increases continuously. In LDPE pyrolysis, the pyrolysis time was longer than that observed for other plastics at a specified temperature, and the amount of wax generated was the greatest. The maximum mass fraction of oil was obtained in the order of HDPE, PP, and LDPE at a specified temperature, and it decreased with temperature. Although the 1D model adopted in this study has a limitation in that it does not include material transport and heat transfer phenomena, the qualitative results presented herein could provide base data regarding various types of plastic pyrolysis to predict the product characteristics. These results can in turn be used when designing pyrolysis reactors.