• Title/Summary/Keyword: hazardous

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Characterization of Heavy Metals Including Mercury and Fine Particulate Emitted from a Circulating Fluidized Bed Power Plant Firing Anthracite Coals (무연탄 순환유동층 발전소로부터 배출되는 수은을 포함한 중금속 및 미세분진의 배출 특성)

  • Kim, Jeong-Hun;Yoo, Jong-Ik;Seo, Yong-Chil
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.268-274
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    • 2010
  • Emission of heavy metals as hazardous air pollutants has been focused with tightening regulatory limits due to their hazardousness. Measurements and characteristic investigations of heavy metals emitted from a commercial power plant burning anthracite coal have been carried out. The plant consists of a circulating fluidized bed combustor, a cyclone, a boiler and an electrostatic precipitator(ESP) in series. Dust and gaseous samples were collected to measure main heavy metals including gaseous mercury before ESP and at stack. Dust emissions as total particulate matter (TPM), PM-10 and PM-2.5 at inlet of ESP were very high with 23,274, 9,555 and $7,790mg/Sm^3$, respectively, as expected, which is much higher than those from pulverized coal power plants. However TPM at stack was less than $0.16mg/Sm^3$, due to high dust removal efficiency by ESP. Similarly heavy metals emission showed high collection efficiency across ESP. From particle size distribution and metal enrichment in sizes, several metal concentrations could be correlated with particle size showing more enrichment in smaller particles. Mercury unlike other solid metals behaved differently by emitting as gaseous state due to high volatility. Removal of mercury was quite less than other metals due to it's volatility, which was 68% only. Across ESP, speciation change of mercury from elemental to oxidized was clearly shown so that elemental mercury was half of total mercury at stack unlike other coal power plants which equipped wet a scrubber.

Field Application of an Eco-Friendly Solidification Material for Forest Road Pavement (친환경 고화재를 이용한 임도포장의 현장 적용성 연구)

  • Lee, Kwan-Hee;Ko, Chi-Ung;Kim, Dong-Hyun;Oh, Se-Wook;Kim, Dong-Geun
    • Journal of Korean Society of Forest Science
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    • v.106 no.1
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    • pp.70-76
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    • 2017
  • Among the forest road pavement methods, the majority of current constructions utilize concrete pavements but it has disadvantages as follows: many cracked concrete pavements generated by the erosion of underlying soil layers, could not be used as forest roads in steep slope during winter, and cement contains hazardous chemicals (hexavalent chromium, etc.). In order to supplement the limitations of the use of concrete pavement, this study was conducted to investigate the operation process and cost, the strength and compaction of the experimental forest road pavement(85 m) utilizing eco-friendly solidification material at Goryeong-gun, Gyeongsangbuk-do. The work elements of experimental forest road paving were classified into: preparation, Roadbed excavation, Roadbed grading, subgrade compaction, form work, collection and selection of site soil, mixing site soil and eco-friendly solidification material, paving by eco-friendly solidification material, compaction by vibrating roller and curing. The result of economic analysis using construction cost shows that for concrete costs total to $38,681won/m^3$ while for the eco-friendly paving material it is $38,245won/m^3$. Thus the construction costs for concrete and the eco-friendly paving material are similar. And the results of the Schmidt Hammer test for strength analysis by curing period are 10.5-13.5 MPa for 7 days, 18.1-22.7 MPa for 14 days, and 20.8-23.0 MPa for 28 days.

A Study on KSNP Environmental Color Design (개선형 한국 표준 원자력 발전소의 친환경 색채디자인 연구)

  • Kim, Yeon-Jung
    • Archives of design research
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    • v.17 no.4
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    • pp.233-240
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    • 2004
  • Living in the modern age with well-developed scientific technologies, all of us are enjoying convenient lives because of 'energy'. Korea, poor in resources, is importing a large portion of its energy sources from abroad but energy consumption shows an upward tendency due to the continuing economic growth and the improvement of living conditions. The atomic energy is considered a self-reliant, alternative energy source like our country. However, it is necessary to educate the people on and publicize atomic power generation in the face of the widespread negative recognition that the atomic power plant is a hazardous facility. The study approaches to these matters with a human-friendly and environment-friendly coloring plan in the perspective of environment coloring plan. The study aims to minimize negative images of the atomic power, while highlighting its friendly and positive images so as to enhance the confidence of the people on the atomic power and to create a clean image for the atomic power. For this goal, the study examined and analyzed cases of Japanese nuclear power plants and domestic nuclear power plants, and also carried out an on-site survey in the sites in which nuclear power plants would be constructed to extract concrete colors through the analyses of their natural environment and actual conditions. The study also carried out a survey of residents in the regions to induce their participation, and reflected the survey results to the coloring plan. The study is expected to create a stable and friendly image of the nuclear power plant through materializing its environment-friendly image and remove negative recognition that the people have on the nuclear power plant. It also attempted an external environment-coloring plan a s a strategic means for positive publicity and through this, is expected to ultimately contribute to the creation of the new images of nuclear ower plants.

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Arsenic Speciation and Risk Assesment of Hijiki (Hizikia fusiforme) by HPLC-ICP-MS (HPLC-ICP-MS를 이용한 톳의 비소 화학종 분석 및 위해성 평가)

  • Ryu, Keun-Young;Shim, Sung-Lye;Hwang, In-Min;Jung, Min-Seok;Jun, Sam-Nyeo;Seo, Hye-Young;Park, Jong-Seok;Kim, Hee-Yeon;Om, Ae-Sun;Park, Kyung-Su;Kim, Kyong-Su
    • Korean Journal of Food Science and Technology
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    • v.41 no.1
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    • pp.1-6
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    • 2009
  • This study investigated arsenic speciation and risk assesment in 30 samples of hijiki purchased from local market in 10 Korean cities. The mean arsenic concentration of the hijiki samples was 45.65 mg/kg (dryness; moisture content of 91.1${\pm}$1.6%), and the major arsenic compound was arsenate [As(V)]. The concentrations of As(V) and As(III), as inorganic arsenic compounds, were detected to be 40.36 mg/kg and 0.37 mg/kg, respectively, and made up 88.6% (40.46 mg/kg) of the arsenic in the hijiki. Among the samples, the highest inorganic arsenic concentration was identified at 9.19 mg/kg (wet), and for an adult with a body weight of 60 kg was within an acceptable level as 0.7% (6.43 mg/60 kg/week) when compared with the provisional tolerable weekly intake (PTWI) (900 mg/60 kg/week), and would be considered safe with respect to health-hazardous effects.

The compensation for damage by space accidents (우주손해배상법에 관한 약간의 고찰)

  • Kim, Sun-Ihee
    • The Korean Journal of Air & Space Law and Policy
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    • v.22 no.2
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    • pp.3-25
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    • 2007
  • In 2002 Republic of Korea successfully launched a self-made mined proportion rocket and it is expected that she will be able to have own space launching system by 2010. According to Article 14 of the Space Exploration Promotion Act, a new law should be established to impose the limit of compensation for the damage by space accident. Therefore, The Space Accident Liability Act was passed in Korean Congress on Nov. 22, 2007 and it will be enforced in six months. The purpose of this Act is to provide reparation for the damage of the third parties that a launch causes; and the Commonwealth should be insured against any possible space accidents to pay for such a damage. Here space accident means the damages to our life, body, and properties from the launching of space objects. There should be an actual loss to establish the compensation of Liability Act. Article 2 in Liability Act defines "damage" as follows: the term "damage" means loss of life, personal injury or loss of or damage to property of persons. Physical and material damages are included in the conception of damage. The meaning of a launching includes any test launch and launch for a real arrangement which will ultimately provides a wide range of compensation. Article 4 indicates that absolute liability should be imposed in compensating for damage by space accidents. Article 4 also indicates that a launching party should be absolutely liable to compensate for the damage caused by its space object on the surface of the Earth. In general, liability stands where fault is. But if the activity is ultra-hazardous and causes serious harm, the individual needs to compensate for the damage unlimitedly. Because of the many launchings for the Seattleite launching, a launching organization is obligated to the liability insurance in preparation for the space accidents. According to the Article 6 of Space Accident Liability Act, to be insured for the compensation for damage is obligatory. It says: "In accordance with Article 11 in the Space Exploration Promotion Act, the person who wants to receive an approval f3r launching needs to be insured in compensation for the possible damage by space accidents.

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A Study on the Mortality in Oxygen and Toxic Gas Concentration According using Experimental Animals (실험동물을 이용 산소 및 유해가스 농도에 따른 치사율 연구)

  • Kim, Hyeon-Yeong
    • Journal of the Korean Institute of Gas
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    • v.17 no.4
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    • pp.18-25
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    • 2013
  • It may occur health hazards or death by suffocation or acute poisoning in case of oxygen deficiency in ambient or exposure to harmful gas. As a part of accident prevention, we studied the change of activity and lethal dose by changing the concentration of several hazardous gas with inhalation exposure chamber and laboratory animals. We investigated the lethality and motility change during either the 4 hrs whole body exposure to oxygen, nitrogen, toluene, $H_2S$, CO and 48 recovery. As results, it is estimated that 5% oxygen concentration as lethal concentration and 5.5% as $LC_{50}$ (rat, 4 hrs) with statistics for dose-response. The results of lethality in oxygen deficient condition (approximately 6%), the lethalities were 40%, 20% with 20 ppm $H_2S$, 600 ppm CO respectively, and was not increased the lethality with 8% CO. Thus, it was confirmed that the $H_2S$, CO had influence to lethal dose, while toluene had low fluence.

Setting of Regional Priorities in Preparedness for Marine HNS Spill Accident in Korea by using Concentration Index (집중도 지수를 활용한 HNS 사고 대비 우선지역 선정)

  • Ha, Min-Jae;Jang, Ha-Lyong;Kim, Tae-Hyung;Yun, Jong-Hwui;Lee, Moon-Jin;Lee, Eun-Bang
    • Journal of Navigation and Port Research
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    • v.41 no.6
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    • pp.437-444
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    • 2017
  • The concentration of the HNS Accident for each region was confirmed to prepare against an HNS Spill accident by using a Concentration Index which is used to assess industry concentration trend. This is to present the HNS Accident Concentration Index by combining HNS Accident Scale Concentration Index and an HNS Accident Frequency Concentration Index based on the data of marine spill accidents including the HNS accident. Based on the HNS Accident Concentration Index, Ulsan was identified as a top priority region for preparedness, Yeosu, Busan and Taean were identified as priority regions for preparedness, Gunsan, Mokpo, Wando, Incheon, Tongyeong, Pyeongtaek and Pohang were identified as necessary regions for preparedness, Donghae, Boryeong, Buan, Seogwipo, Sokcho, Jeju and Changwon, in which no marine spill accidents occurred, were identified as support regions for preparedness.

Isolation and Antibiotic Susceptibility of Enterococcus spp. from Fermented Soy Paste (콩발효식품에서의 장구균과 항생제 내성특성)

  • Kang, Tae-Mi;Park, Jong-Hyun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.5
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    • pp.714-720
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    • 2012
  • To evaluate the antibiotic risk of $Enterococcus$ in fermented soy paste, $Enterococcus$ spp. were isolated and identified from 31 $Cheongkukjang$ and 17 $Doenjang$, samples. Exactly 123 $Enterococcus$ spp., 119 from $Cheongkukjang$ and four from $Doenjang$, were ultimately isolated. The most frequently collected $Enterococcus$ isolates in $Cheongkukjang$ were 69 strains of $E.$ $faecium$ and 20 strains of $E.$ $faecalis$. All four $Enterococcus$ spp. from $Deonjang$ were identified as $E.$ $faecium$. All isolates were sensitive to ampicillin, chloramphenicol, penicillin, and tetracyclin $E.$ However, they showed broad spectra from sensitivity to resistance to erythromycin, ripampin, and streptomycin. Vancomycin minimum inhibition concentration (MIC) of $Enterococcus$ spp. from $Cheongkukjang$ ranged from 0.25 to 8 ${\mu}g/mL$. Almost all strains were sensitive to vancomycin, but eight strains showed intermediate resistance to vancomycin. Seventeen strains showing the highest MIC of 8 ${\mu}g/mL$ among all isolates were evenly distributed among $E.$ $faecalis$, $E.$ $faecium$, $E.$ $gallinarum$, and $E.$ $casselifalvus$, in which the strong resistant genes of $van$A and $van$B for vancomycin were not detected. Overall antibiotic resistance of $Enterococcus$ isolates was relatively low and particularly low vancomycin resistance was similar to those of $Enterococcus$ isolates obtained from other foods. Therefore, the antibiotics resistance of $Enterococcus$ and especially vancomycin-resistant $Enterococcus$ spp. from $Cheongkukjang$ and $Doenjang$, is not hazardous.

Fine Structure on the Pigment Epithelial Cell and the Bruch's Membrane of the Rat Retina after X-Irradiation (X-선 조사를 받은 흰쥐 망막의 색소상피세포와 기저복합층의 미세구조)

  • Ko, Jeong-Sik;Shin, Ki-Ho;Ahn, E.Tay;Yang, Nam-Gil;Park, Kyung-Ho;Kim, Jin-Gook
    • Applied Microscopy
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    • v.23 no.2
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    • pp.11-26
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    • 1993
  • This experiment was performed to study the morphological responses of the pigment epithelial cell and the Bruch's membrane of the retina of rat following X-ray irradiation. Male rats were divided into normal and experimental groups. The heads of the rats, under sodium thiopental anesthesia, were exposed to 3,000 rads or 6,000 rads of radiation in a single dose, respectively. The source was a Mitsubishi Linear Accelerator ML-4MV. The target to skin distance was 80cm, and the. dose rate was 200 rads/min. The experimental groups were sacrificed on the 6th hour, 2nd and 6th day after X-ray irradiation. Under anesthesia, 1% glutaraldehyde-1% paraformaldehyde solution(0.1M Millonig's phosphate buffer, pH 7.3) was perfused through the left ventricle and ascending aorta. Pieces of the tissue taken from the posterior region of the retina were fixed in 2.5% glutaraldehyde-1.5% paraformaldehyde(0.1M Millonig's phosphate buffer, pH 7.3) and 1% osmium tetroxide(0.1M Millonig's phosphate buffer, pH7.3), and embedded in araldite mixture. The ultrathin sections contrasted with uranyl acetate and lead citrate were observed with JEM 100 CX-II electron microscope. The results were as follow; 1. The morphological changes of the pigment epithelial cells were not pronounced after exposure to 3,000 rads of X-ray. But on the 6th hour after exposure to 6,000 rads of X-ray, bulging nuclear membrane protruding into the cytoplasm and nuclear chromatin clumped into numerous masses along the nuclear membrane were observed. At the 2nd and 6th day post-irradiation, partial cytolysis or necrosis were seen. 2. The thickness of the Bruch's membrane of the experimental groups were increased in the time and dose range covered by this study, and splitting or diffusing basal laminae of the choriocapillary layer were observed frequently in the experimental group. Above results suggest that large amount(6,000 rads) of head irradiation induce direct hazardous effects on the pigment epitherial cells and Bruch's membrane of the retina of the rat, but pigment epithelial cells are more radioresistant than Bruch's membrane.

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Anti-atopic Activity of Sargassum micracanthum Ethanol Extracts (잔가시 모자반 에탄올 추출물의 항아토피 효과)

  • Jeong, Da-Hyun;Kim, Koth-Bong-Woo-Ri;Kim, Min-Ji;Kang, Bo-Kyeong;Bark, Si-Woo;Pak, Won-Min;Kim, Bo-Ram;Park, Hong-Min;Im, Moo-Hyeog;Ahn, Dong-Hyun
    • Microbiology and Biotechnology Letters
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    • v.42 no.1
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    • pp.82-88
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    • 2014
  • Atopic dermatitis (AD) is a common chronic inflammatory disease preceding the development of allergic disorders. The aim of this study was to evaluate the effect of Sargassum micracanthum ethanol extract (SMEE) on AD. AD was induced by spreading 2,4-dinitrochlorobenzen (DNCB) on the back sides of BALB/c mice. The efficacy of SMEE was tested by observing the skin clinical severity score, proliferations of Raw 264.7 cells and the secretion of cytokines and IgE. The secretion of IL-4, and IgE was significantly decreased by SMEE in a dose dependent manner, while IFN-${\gamma}$ was increased. In addition, SMEE alleviated the AD symptoms better when compared to the positive controls. In conclusion, these results suggest that SMEE has an inhibitory effect on AD, and may serve as a useful biomaterial for the development of cosmeceuticals.