• Title/Summary/Keyword: hazardous

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Associations of Dietary Calcium Intake and Serum Calcium Level with Blood Lead Levels in Korean Male Lead Workers

  • Kim, Hee-Seon;Song, Ok-Young;Kim, Kyung-Min;Lee, Sung-Soo;Young Hwangbo;Ahn, Kyu-Dong;Lee, Byung-Kook
    • Journal of Community Nutrition
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    • v.3 no.2
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    • pp.96-102
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    • 2001
  • A cross-sectional study was performed to estimate the nutritional status of Korean male lead workers and to assess the relationship between calcium nutritional status and blood lead levels. A flood consumption survey was conducted by the 24-hr recall method with 118 lead workers and 63 non-lead exposed controls. Blood lead levels were analyzed from whole blood and serum calcium concentrations were also assessed. Results of dietary analysis showed Korean lead workers consumed relatively sufficient nutrients (more than 75% of RDA) except, calcium. Mean dietary calcium intake of lead workers was 502.2mg(72% of RDA) while that of the non-lead workers was estimated as 600.8mg(86% of RDA). Intakes of protein, iron, niacin and vitamin C of lead workers were significantly lower than those of non-lead workers. There was a wide range of blood lead levels(5.5 to 73.5$\mu\textrm{g}$/㎗) observed while mean blood lead level of lead workers was 30.9$\mu\textrm{g}$/㎗. However, 98% of lead workers showed normal serum ca1cium concentrations (range ; 8.9 to 10.7mg/㎗, mean ; 9.77mg/㎗) while 66% of lead workers were estimated to intake a dietary calcium lower than 75% of RDA. Mean blood lead levels of non-1ead workers were significantly lower(mean ; 5.1$\mu\textrm{g}$/㎗, p < 0.001) and the serum calcium concentration was significantly higher(mean ; 10.20mg/㎗, p < 0.001) than lead workers. Results of unadjusted correlation showed that serum calcium level and dietary calcium intake were negatively correlated with blood lead concentration. In a multiple regression of blood lead levels with variables known as affecting blood lead 1eve1 such as age, body mass index and occupational lead exposure, serum calcium was insignificant while dietary calcium intake showed statistically significant(p < 0.05) relation. Since calcium is a very important nutrient to reduce hazardous effects of lead, it should be strongly recommended that lead workers need to increase dietary calcium intake.

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Evaluation of the Feasibility of Oyster-Shell and Eggshell Wastes for Stabilization of Arsenic-Contaminated Soil (농축수산 폐기물(굴껍질 및 달걀껍질)을 이용한 비소 오염토양의 안정화 효율 평가)

  • Lim, Jung-Eun;Moon, Deok-Hyun;Kim, Dong-Jin;Kwon, Oh-Kyung;Yang, Jae-E.;Ok, Yong-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.12
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    • pp.1095-1104
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    • 2009
  • The objective of this research was to evaluate the feasibility of using oyster-shell and eggshell wastes for the stabilization of arsenic-contaminated soil. Artificial As(V) contaminated soil was mixed with 0~5% oyster-shell and eggshell wastes and each sample was incubated for 30 days in a controlled environment. The efficiency of each treatment was evaluated using various single extractants (1 N HCl, 0.1 N NaOH and 0.5 N $H_2SO_4$). The concentration of As(V) was reduced by 10% upon a 5% oyster-shell or eggshell waste treatments based on the Korea Standard Test method (1 N HCl extraction). Analogous trends were observed in the 0.1 N NaOH or 0.5 N $H_2SO_4$ extractions. In addition, the oyster-shell and eggshell waste treatments increased the pH of each soil from 6.54 (Control) to 7.62~7.94. The exchangeable Ca in each soil also sharply increased from 6.87 cmol(+)/kg (Control) to 12.77~20.18 cmol(+)/kg. Further research is needed to increase the effectiveness of the oyster-shell and eggshell waste for the stabilization of As(V) in the contaminated soil.

A Survey on the Heavy Metal Concentration of Soil Samples around Onsan Industrial Complex (온산공단(溫山工團)주변토양의 중금속(重金屬) 농도조사)

  • Lee, Su-Rae;Song, Ki-Joon
    • Korean Journal of Environmental Agriculture
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    • v.4 no.2
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    • pp.88-94
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    • 1985
  • In order to investigate the pollution potential of soils after the construction of Onsan Industrial Complex(non-ferrous metal refineries), concentrations of hazardous heavy metals were analyzed for soil samples collected from paddy, upland, orchard and forest soils around the Complex during the period of March 1978 to May 1979. The results are summarized as follows. 1) The concentrations of heavy metals (air-dry basis) for cultivated soil samples from 46 sites were obtained in the range of trace-9.3 ppm As, trace-0.6 ppm Cd, 4${\sim}$22 ppm Cu, trace-0.37 ppm Hg, 6${\sim}$43 ppm Pb and 27${\sim}$93 ppm Zn, which were regarded as non-polluted when compared with the whole Korea data for non-polluted paddy soils. 2) When the heavy metal concentrations were compared with respect to paddy, upland and orchard soils, no significant difference was observed in As, Cd, Cu and Zn whereas significant difference was observed in Hg and Pb. When they were compared with respect to region surrounding the Complex, no significant difference was observed in As, Cd, Hg whereas significant difference was observed in Cu and Pb. 3) Soil samples from several sites near Korea Zinc Refinery were contaminated with Cd, Pb and Zn, due to the accidental emission during its testing operation. Any further contamination was not observed after regular operation of the Refinery.

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Physico-chemical stability of pesticide formulations under different storage conditions (저장조건별 농약제품의 물리.화학적 안정성)

  • Lee, Hee-Dong;Kim, Kwang-Ho;Rhi, Ja-Hyeun;Shin, Wook-Cheol;Park, Hyeon-Ju;Lee, Soo-Hyung;Park, Seung-Soon
    • The Korean Journal of Pesticide Science
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    • v.8 no.2
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    • pp.103-106
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    • 2004
  • To confirm physico-chemical stability of formulated products, this study was conducted under different storage conditions; room temperature and accelerated temperature of $54^{\circ}C$. The tested pesticide formulations were dichlorvos 50% EC, acephate 50% WP, hymexazol 4% DP, thiram 80% WP and isoprothiolane 12% GR. The selected formulations were stored for 10 weeks and 5 years under the given temperature in maximum and contents of active ingredients were also analyzed by GLC or HPLC after each time of storage. The degradation rates of 5 active ingredients under the two conditions showed a similar trend except acephate. Acephate was rapidly decomposed at $54^{\circ}C$ but slowly decomposed at room temperature, and the degradation rate under the accelerated condition was 2.4 to 5-fold higher than that under the room temperature. Consequently, the stability test on active ingredients in pesticide formulations was able to recommend to be carried out under the accelerated condition except acephate. And the physical properties of all formulations tested under two storage conditions were good.

Analysis of some pesticides in urine by GC/MS (GC/MS를 이용한 뇨중 몇가지 농약의 분석)

  • Park, Seong-Soo;Park, Song-Ja;Pyo, Hee-Soo;Cho, Jung-Hee;Kim, Hye-Soo;Park, Taek-Kyu
    • The Korean Journal of Pesticide Science
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    • v.4 no.1
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    • pp.1-10
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    • 2000
  • The purpose of this study is to establish the assessment techniques of hazardous chemicals by the development of analytical method of biological samples. In this study, we have developed an extraction method of nine pesticides used for rice paddy that resulted in high recovery from the spiked human urine by the liquid-liquid extraction with diethyl ether at pH 7.0. Calibration curve obtained from each pesticide standard using by gas chromatography/mass spectrometry/selected ion monitoring has shown good linearity and detection limits were the range of $0.4{\sim}2.0$ ng/mL in urine. As a biological monitoring, urine samples of local farmers exposed directly to nine pesticides in the field were collected and analyzed by GC/MS. Of the tested pesticides, metabolites of phenthoate assumed were identified by GC/MS analysis. No parent compound was detected.

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Contents of Arsenic in Some Fisheries Caught in Western Coast (서해안 지역 수산물의 비소함량에 관한 연구)

  • 김애정;김선여;이완주;박미정
    • Journal of Food Hygiene and Safety
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    • v.13 no.3
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    • pp.201-205
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    • 1998
  • In Korea, a small proportion of fishery products are contaminated with a considerable amount of potentially hazardous contaminants. So, there is generally a high risks to consumers. Inorganic contaminants with the greatest potential for toxicity are Sb, As, Cd, Pb, Hg, Se and the Sulfides. As appears to be much more variable than the others. This study was performed to assess the levels of the As in fisheries caught from the waters of the western coast of Korea. The samples included 26 kinds of fishes, 18 kinds of Mollusca, 3 kinds of Crustacea and 7 kinds of salted fishes. The Moisture content of molluscans was significantly higher than that of others (p<0.05). And the As contents of crustaceans were significantly higher than those of fishes, molluscans and salted fishes (p<0.05). The As content of Turban shell was 51.62 ppm, which was the highest among the samples. Also, the As contents of eel, cuttle fish and blue crab were found to be higher than in other fisheries. This variability offers a solution for the reduction of exposure to As through restricting the harvest of aquatic organism from the western coast of Korea.

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Information Management System of Solid Waste Landfill based on 3 Dimensional Method (3차원기법을 이용한 폐기물매립지 정보관리시스템 구축 연구)

  • Park, Jin-Kyu;Cho, Sung-Youn;Kim, Byung-Tae;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.4
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    • pp.39-48
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    • 2016
  • An information management system for a solid waste landfill site was developed, in this study, to optimize the operation and management of solid waste landfill in real time in addition to provide the information of landfill status to the landfill operator, public official concerned and local residents. The landfill information management system is composed of two systems (Solid waste landfill history management system and landfill operation and performance management system). The solid waste landfill history management system based on automated RFID/LPR system allows landfill operators to provide information of waste collection vehicles and received waste. In addition, the system aids in the identification of 3-dimensional (3D) position for landfilled solid wastes. Using the landfill operation and performance management system based on 3D laser scanner delivers information about landfill volume, settlement, landfill density, and current landfill capacity to landfill operators in real time, resulting in optimum space utilization. Ultimately, this system would dramatically reduce exposure of landfill operators to hazardous materials and improve the productivity of landfill operations.

Developing status of the Preparedness and Response System for HNS accident (HNS 해상사고 대비.대응체제구축 추진현황)

  • Im, T.S.;Lee, S.H.;Choi, J.W.
    • Proceedings of KOSOMES biannual meeting
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    • 2006.05a
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    • pp.65-70
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    • 2006
  • The regulation of HNS has been intensified by the international trends including OPRC-HNS Protocol and '96 Convention which was driven by the high amounts of cargo. Due to the characteristics of HNS that would possibly bring potential damage with personnel and assets, effective management and prompt actions are required definitely. In order to respond effectively against HNS accidents, Korea Coast Guard (KCG) is in the process q development of HNS accident response manual and information system which allows On-Scene Coordinator(OSC) and personnels for rescue including an information for hazardous materials, sensitive area to be affected, solution methods and more. Furthermore, KCG is also building up establishment of national and local contingency plans for HNS in accordance with OPRC-HNS Protocol. It is also advised to proceed for the government to solve the anticipated obstacles that include protection equipments to get close to the site, experts allowing to manage accidents and organizations specialized for overall HNS related matters. The proposed issues described above are planned to conducted on basis of government.

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A Study on the Selection of VTS Marine Incident Classification Criteria at the Busan Port (VTS 관점의 준해양사고 분류기준 선정에 관한 연구 - 부산항을 대상으로 -)

  • Ha, Jong-Min;Park, Young-Soo;Park, Sang-Won;Jeong, Jae-Yong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.6
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    • pp.615-623
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    • 2020
  • In order to prevent the dangers of major marine accidents, it is very important to be aware of in advance through marine incidents in the background of Heinrich's law, formulated by the safety pioneer who is credited with focusing on workplace safety with emphasis on the human element. At least 11 cases of collision accidents occurred in the Busan VTS area from January 1st to December 31st, 2019, and 24 cases of VTS marine incidents were reported during the same period. According to Heinrich's law, there could be many more potentially risky situations besides the 24 reported cases. In this study, the criteria for VTS marine incidents were established through advanced research and a survey of VTS operators, and analysis of 24 cases of VTS marine incidents in the Busan VTS area. Traffic surveys were conducted for three days to identify potentially hazardous situations. According to the survey, there were 216 cases of VTS marine incidents, and within a year, it is estimated there could be about 26,280 cases. Even if conditions such as "missing VHF communication feedback" which is an important cause of marine incidents, are not reflected, there are many potential risks in the VTS area. Thus, it is vital to strengthen the VTS marine incident reporting system.

Evaluation on Feasibility of Industrial By-products for Development of Mono-Layer Landfill Cover System (산업부산물을 이용한 단층형 매립지 복토시스템 개발을 위한 적용 타당성 평가)

  • Kim, Soon-Oh;Kim, Pil-Joo;Yu, Chan
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.11
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    • pp.1075-1086
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    • 2008
  • In order to investigate the applicability and suitability of the industrial by-products to apply mono-layer cover system for non-sanitary landfill sites, 6 different industrial by-products, such as construction waste, bottom ash, gypsum, blast furnace and steel manufacture slags, and stone powder sludge, were evaluated. Various physicochemical and hydrodynamic properties of the industrial byproducts were investigated. The environmental safety was monitored using batch and long-term leaching tests as well. In addition, the flexibility of plants was observed by cultivating them in the industrial by-products. The results for physicochemical properties indicate that most of the materials considered appeared to be suitable for landfill cover. Particularly, the concentration levels of hazardous elements regulated by the Korean Law for Waste Management did not exceed the regulatory limits in all target materials. In addition, the concentrations of regulated elements for the Korean Soil Conservation Law were examined below the regulatory limits in most of materials considered, except for the stone powder sludge. The results of batch and long-term experiments showed bottom ash and construction waste were the most suitable materials for landfill cover among the industrial by-products considered. The results of plant studies indicate that the bottom ash among industrial by-products considered was most effective in developing vegetation on landfill site, showing fast germination and large growth index. At the final covering system made of mixture of soil and bottom ash, the optimum application rate of farmyard manure was observed to be 40-50 Mg/ha.