• Title/Summary/Keyword: group polarization

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Hesperidin Attenuates Ultraviolet B-Induced Apoptosis by Mitigating Oxidative Stress in Human Keratinocytes

  • Hewage, Susara Ruwan Kumara Madduma;Piao, Mei Jing;Kang, Kyoung Ah;Ryu, Yea Seong;Han, Xia;Oh, Min Chang;Jung, Uhee;Kim, In Gyu;Hyun, Jin Won
    • Biomolecules & Therapeutics
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    • v.24 no.3
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    • pp.312-319
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    • 2016
  • Human skin cells undergo pathophysiological processes via generation of reactive oxygen species (ROS) upon excessive exposure to ultraviolet B (UVB) radiation. This study investigated the ability of hesperidin ($C_{28}H_{34}O_{15}$) to prevent apoptosis due to oxidative stress generated through UVB-induced ROS. Hesperidin significantly scavenged ROS generated by UVB radiation, attenuated the oxidation of cellular macromolecules, established mitochondrial membrane polarization, and prevented the release of cytochrome c into the cytosol. Hesperidin downregulated expression of caspase-9, caspase-3, and Bcl-2-associated X protein, and upregulated expression of B-cell lymphoma 2. Hesperidin absorbed wavelengths of light within the UVB range. In summary, hesperidin shielded human keratinocytes from UVB radiation-induced damage and apoptosis via its antioxidant and UVB absorption properties.

A Study of Asset Portfolio and Impact Variables affecting on the Aged (노인가계 포트폴리오 구성 및 영향변수에 대한 연구)

  • Bae, Mi-Kyeong;Hong, Gong-Sook
    • Korean Journal of Human Ecology
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    • v.15 no.6
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    • pp.973-984
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    • 2006
  • This study examined the asset allocation of the aged and analyzed the impact variables on the portfolio ratio of different kind of finanical assets. The aged was divided three groups, 55-65, 65-75 and 75 over. The results showed that the aged are not likely to invest on risky asset and their assets composed of mostly real estates and bank account. The study include four different assets, such as liquid asset, risky assets, horne equity and other real estates, which reflects the liquidity problems of households asset allocation for the aged in Korea. The aged who do not participate on stock market are likely to have more liquid assets. Households lived in Daegu, Kwangju, ChungCheong and CheonRa tend to have more liquid assets compared to those in Seoul. Total income is appeared having positive relationship with illiquid assets including stock, bonds, and private pension. Age group with 75yrs over tend to have greater mean of illiquid assets and it may caused by the polarization of assets, which gives intuition for the future study.

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Dielectric Properties of Epoxy Composites with Variation of Additives and Curing Conditions (첨가제 및 경화조건 변화에 따른 에폭시 복합체의 유전특성)

  • Park, Kyung-Tae;Lee, Ho-Shik;Chung, Il-Hyung;Wang, Jong-Bae;Lee, Joon-Ung
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.879-882
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    • 1992
  • In order to study electrical properties of epoxy composites with various additives rates and curing conditions, dielectric measurements have been performed over a frequency range from 30 [Hz] to 3 [MHz] and a temperature range of 20[$^{\circ}C$]$\sim$180[$^{\circ}C$] The observed higher values of dielectric permittivity and loss In the case of filled epoxy are attributed to MWS polarization effect. The low temperature peak assigned to the $\beta$-relaxation process is attributed to the enhenced rotation of the methyl group attached to the main chain and the presence of filler. And the high temperature peak ($\alpha$-relaxation process)is associated with the segmental motion or glass transition process.

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Transverse Wave Propagation in [ab0] Direction of Silicon Single Crystal

  • Yun, Sangjin;Kim, Hye-Jeong;Kwon, Seho;Kim, Young H.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.35 no.6
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    • pp.381-388
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    • 2015
  • The speed and oscillation directions of elastic waves propagating in the [ab0] direction of a silicon single crystal were obtained by solving Christoffel's equation. It was found that the quasi waves propagate in the off-principal axis, and hence, the directions of the phase and group velocities are not the same. The maximum deviation of the two directions was $7.2^{\circ}$. Two modes of the pure transverse waves propagate in the [110] direction with different speeds, and hence, two peaks were observed in the pulse echo signal. The amplitude ratio of the two peaks was dependent on the initial oscillating direction of the incident wave. The pure and quasi-transverse waves propagate in the [210] direction, and the oscillation directions of these waves are perpendicular to each other. The skewing angle of the quasi wave was calculated as $7.14^{\circ}$, and it was measured as $9.76^{\circ}$. The amplitude decomposition in the [210] direction was similar to that in the [110] direction, since the oscillation directions of these waves are perpendicular to each other. These results offer useful information in measuring the crystal orientation of the silicon single crystal.

Degradation of Polymer Electrolyte Membrane under Low Current/Low Humidity Conditions (저전류/저가습 조건에서 고분자전해질 막 열화)

  • Kim, Tae-Hee;Lee, Jung-Hun;Lee, Ho;Lim, Tae-Won;Park, Kwon-Pil
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.2
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    • pp.157-163
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    • 2007
  • During PEMFC operation, low current and low humidity conditions accelerate the degradation of perfluorosulfonic acid membrane. But, there have been no studies that clearly explain why these conditions accelerate the membrane degradation. In this study, the hydrogen permeability through the membrane, I-V polarization of MEA, fluoride emission rate(FER) in effluent water were measured during cell operation under low current densities and low relative humidity(RH). The experimental results were evaluated with oxygen radical mechanism the most commonly known for membrane degradation. It seems that low RH of anode is a good condition for $H{\cdot}$ radical formation on the Pt catalyst and the low current condition accelerates the $H{\cdot}$ to form $HO_2{\cdot}$ radical attacking the polymer membrane.

Carbon-13 CP MAS NMR Study on Structures of Octadecyl Chains Influenced by Co-Presence of 3-Aminopropyl Chains on SBA-15

  • Han, Oc-Hee;Bae, Yoon-Kyung;Jeong, Soon-Yong
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.405-407
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    • 2008
  • Functionalized SAB-15 samples by octadecyltrimethoxysilane (OTC) were studied by 13C magic angle spinning (MAS) cross polarization (CP) nuclear magnetic resonance (NMR) spectroscopy. In the SBA-15 sample fully functionalized by 3-aminopropyltrimethoxysilane (APS) and OTC in 1:1 molar ratio, octadecyl chains were observed to have, on average, more trans conformation than those in the SBA-15 samples fully modified by OTC only. Our results confirm that long chain molecules tend to organize themselves better in the co-presence of short chain molecules on the surface of mesoporous materials by packing of the different length chains in an interdigitized fashion even when the short chains are long enough to have three carbons and a functional group at the ends. In addition, our results indicate that solid-state 13C CP MAS NMR spectroscopy is a simple and non-destructive method to probe the molecular structures of the domains composed of long alkyl chains.

Mechanical and electrical properties of cement paste incorporated with pitch-based carbon fiber

  • Rhee, Inkyu;Kim, Jin Hee;Park, Sang Hee;Lee, Sungho;Ryu, Bong Ryeul;Kim, Yoong Ahm
    • Carbon letters
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    • v.23
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    • pp.22-29
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    • 2017
  • The compressive strength and electrical resistance of pitch-based carbon fiber (CF) in cementitious materials are explored to determine the feasibility of its use as a functional material in construction. The most widely used CFs are manufactured from polyacrylonitrile (PAN-based CF). Alternatively, short CFs are obtained in an economical way using pitch as a precursor in a melt-blown process (pitch-based CF), which is cheaper and more eco-friendly method because this pitch-based CF is basically recycled from petroleum residue. In the construction field, PAN-based CFs in the form of fabric are used for rehabilitation purposes to reinforce concrete slabs and piers because of their high mechanical properties. However, studies have revealed that construction materials with pitch-based CF are not popular. This study explores the compressive strength and electrical resistances of a cement paste prism using pitch-based CF.

Effects of Casting Method and Rolling on the Corrosion Behaviors of Pb Alloys for a Lead Acid Battery (주조 방식 및 압연에 따른 연축전지용 납 합금 기판의 부식 특성)

  • Oh, KkochNim;Lee, Kyu Hyuk;Jang, HeeJin
    • Corrosion Science and Technology
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    • v.20 no.5
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    • pp.315-323
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    • 2021
  • In this study, we examined corrosion behaviors of two types of Pb alloys for a lead acid battery comparatively. One containing 6.6 wt% Sn, 36 mg/kg Bi, and 612.4 mg/kg Ca was prepared by twin-roll continuous casting. The other containing 5.2 wt% Sn, 30.5 mg/kg Ag, and 557 mg/kg Ca was made by twin-belt continuous casting. Potentiodynamic polarization tests were performed to evaluate corrosion resistance. Cyclic voltammetry was done to examine oxidation and reduction reactions occurring on the surface of each alloy in 4.8 M H2SO4 solution. Electrochemical test results implied that the Pb alloy prepared with the twin-belt casting method was less stable than that cast with the twin-roll method. Such results might be due to precipitations formed during the casting process. Rolling did not appear to affect the corrosion behavior of the twin-roll samples with Ag < 10 mg/kg, while it reduced the anodic reaction of Ag on the surface of the twin-belt sample with 30.5 mg/kg Ag.

In-depth Investigation on Interfacial Resistance of Stainless Steel by Using Dynamic Electrochemical Impedance Spectroscopy (Dynamic Electrochemical Impedance Spectroscopy를 이용한 스테인리스 강의 계면 저항 분석)

  • Heo, Jung-Ho;Lee, Yong-Heon;Shin, Heon-Cheol
    • Korean Journal of Metals and Materials
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    • v.47 no.10
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    • pp.644-651
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    • 2009
  • The passivation (or deactivation) of a metal surface during oxide film formation has been quantitatively explored for a ferritic stainless steel by using dynamic electrochemical impedance spectroscopy (DEIS). For this purpose, the electrochemical impedance spectra were carefully examined as a function of applied potential in the active nose region of the potentiodynamic polarization curve, to separate the charge transfer resistance and oxide film resistance. From the discrepancy in the potential dependence between the experimental charge transfer resistance and the semi-empirically expected one, the degree of passivation could be quantitatively estimated. The sensitivity of passivation of the steel surface to anodic potential, which might be the measure of the quality of the oxide film formed under unit driving force or over-potential, decreased by 31% when 3.5 wt% NaCl was added to a 5 wt% $H_2SO_4$ solution.

Optical Imaging Technology for Real-time Tumor Monitoring

  • Shin, Yoo-kyoung;Eom, Joo Beom
    • Medical Lasers
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    • v.10 no.3
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    • pp.123-131
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    • 2021
  • Optical imaging modalities with properties of real-time, non-invasive, in vivo, and high resolution for image-guided surgery have been widely studied. In this review, we introduce two optical imaging systems, that could be the core of image-guided surgery and introduce the system configuration, implementation, and operation methods. First, we introduce the optical coherence tomography (OCT) system implemented by our research group. This system is implemented based on a swept-source, and the system has an axial resolution of 11 ㎛ and a lateral resolution of 22 ㎛. Second, we introduce a fluorescence imaging system. The fluorescence imaging system was implemented based on the absorption and fluorescence wavelength of indocyanine green (ICG), with a light-emitting diode (LED) light source. To confirm the performance of the two imaging systems, human malignant melanoma cells were injected into BALB/c nude mice to create a xenograft model and using this, OCT images of cancer and pathological slide images were compared. In addition, in a mouse model, an intravenous injection of indocyanine green was used with a fluorescence imaging system to detect real-time images moving along blood vessels and to detect sentinel lymph nodes, which could be very important for cancer staging. Finally, polarization-sensitive OCT to find the boundaries of cancer in real-time and real-time image-guided surgery using a developed contrast agent and fluorescence imaging system were introduced.