• Title/Summary/Keyword: green reducing agent

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Synthesis of ZnO:Zn Phosphors with Reducing Atmosphere and Their Luminescence Properties (환원분이기에 따른 ZnO:Zn 형광체의 합성 및 그 형광 특성)

  • 김봉철;백종봉;한윤수;이남양;이병교
    • Journal of the Korean Ceramic Society
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    • v.37 no.1
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    • pp.1-5
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    • 2000
  • Cathodoluminescence(CL) properties of ZnO:Zn green phosphor were investigated. ZnO:Zn phosphor was synthesized by varying reducing agents and firing temperatures. ZnS, charcoal and 5% H2 gas mixed with 95% N2 gas(5H2-95N2) were used as the reducing agent and atmosphere. The highest CL intensity of ZnO:Zn phosphor was observed under the condition of 5H2-95N2 atmosphere and firing temperature of 90$0^{\circ}C$ for 1h. Charocal and ZnO as reducing agents in the syntehsis of ZnO:Zn phosphor exhibited about 60% and 40%, respectively, of the CL intensity obtained with 5H2-95N2 atmosphere.

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A modified electrode by a facile green preparation of reduced graphene oxide utilizing olive leaves extract

  • Baioun, Abeer;Kellawi, Hassan;Falah, Ahamed
    • Carbon letters
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    • v.24
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    • pp.47-54
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    • 2017
  • Different phytochemicals obtained from various natural plant sources are used as reduction agents for preparing gold, copper, silver and platinum nanoparticles. In this work a green method of reducing graphene oxide (rGO) by an inexpensive, effective and scalable method using olive leaf aqueous extract as the reducing agent, was used to produce rGO. Both GO and rGO were prepared and investigated by ultraviolet and visible spectroscopy, Fourier-transform infrared, scanning electron microscopy, atomic force microscopy, thermogravimetric analysis, cyclic voltammetry, X-ray photoelectron spectra, electrochemical impedance spectroscopy and powder X-ray diffraction.

Qualitative comparison of chemical and green synthesized Fe3O4 nanoparticles

  • Gokila, V.;Perarasu, V.T.;Rufina, R. Delma Jones
    • Advances in nano research
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    • v.10 no.1
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    • pp.71-76
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    • 2021
  • Synthesis of nanoparticles using green technology using plants is gaining significant attention as it is an environmentally friendly substitute to conventional physical and chemical methods. The present study was focused on the chemical and green synthesis of Iron Oxide nanoparticles from ferric chloride. The green synthesis was achieved by utilizing the bio components of Hibiscus rosa-sinensis. The Fe3O4 nanoparticles with the size range of 87-400 nm were synthesized by wet chemical reduction technique which are unstable, prone to aggregation while in green synthesis the phytochemicals present in the leaf extract acts as the capping as well as the reducing agent thus the green synthesized iron (III) oxide nanoparticles were naturally stabilized, spherical shaped and are in the size range of 2-80 nm. The results of both the protocols are compared and presented briefly.

Resazurin Redox Reaction Mechanism Using Silver Nanoparticles Synthesized with Monosaccharides and Disaccharides (단당류와 이당류를 환원제로 합성한 은 나노입자의 Resazurin 산화환원반응 메커니즘)

  • Park, Young Joo;Chang, Ji Woong
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.299-304
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    • 2020
  • Nanoparticles play an important role as a catalyst in many chemical syntheses. Colloidal nanoparticles were usually synthesized with reducing, capping, and shape directing agents which induce surface poisoning of catalysts. A new green synthesis for silver nanoparticles was developed by utilizing less additives which could be a hazardous waste. A crystallization technique was employed to reduce the amount of reducing and capping agents during synthesis resulting in less surface poisoning of the nanoparticle. The synthesized Ag nanoparticles using monosaccharides and disaccharides as reducing agents could be used as a catalyst for the redox reaction of resazurin and the mechanism of the reaction using Ag nanoparticles was studied.

Synthesis and Characterization of Water Soluble Fluorescent Copper Nanoparticles

  • Yu, Ji Soo;Kim, Sung Hun;Man, Minh Tan;Lee, Hong Seok
    • Applied Science and Convergence Technology
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    • v.27 no.4
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    • pp.75-77
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    • 2018
  • The electrostatic interaction between emerging quantum-confined nanostructures with plasmonic structures is crucial for future biological applications. Water-soluble green fluorescent copper nanoparticles (Cu-NPs) were fabricated. We demonstrate that L-ascorbic acid is considered as a key to precisely control small Cu-NPs and the capability of the surface ligands, while cetyltrimethylammonium bromide is used as a stabilizing agent controls the particle growth, and stabilizes the nanoparticles. Water-soluble green fluorescent Cu-NPs are tunable through modification of the reaction periods.

Tin-Based Nanoparticles Prepared by a Wet Chemical Synthesis using Green Reducing and Capping Agents (화학적 습식 합성법에서 친환경 슈거 환원제 및 젤라틴 캡핑제에 의한 주석계 나노입자의 제조)

  • Chee, Sang-Soo;Yun, Young-En;You, Eun-Sun;Park, Sang-Hyun;Park, Sung-Young;Lee, Seok-Hee;Park, In-Seon;Lee, Jong-Hyun
    • Journal of the Microelectronics and Packaging Society
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    • v.19 no.4
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    • pp.25-31
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    • 2012
  • In the synthesis of nanoparticles (NPs) via wet chemical reduction using tin(II) acetate precursor, the effects of green reducing agents (sugar) and a capping agent (gelatin) on the formation of NPs were analyzed as functions of synthesis conditions and time. When glucose was used as the reducing agent, it was observed that irregular chainlike shapes, aggregates of NPs, were formed during the synthesis at $70-110^{\circ}C$. The NPs were determined as $SnO_2$ from the fast Fourier transform (FFT) pattern. In the synthesis at $110^{\circ}C$ by using sucrose, fine spherical NPs of ~10 nm in diameter were formed after the synthesis time of 3 h. As the time increased to 9 h, the chainlike NP aggregates besides irregularly aggregated spherical NPs were also formed locally. However, the chainlike NP aggregates were only observed when the synthesis was conducted at $130^{\circ}C$. The spherical NPs and chainlike NP aggregates were analyzed to be pure Sn and $SnO_2$, respectively.

Green Synthesis of Silver and Gold Nanoparticles Using Lonicera Japonica Flower Extract

  • Nagajyothi, P.C.;Lee, Seong-Eon;An, Minh;Lee, Kap-Duk
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2609-2612
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    • 2012
  • A simple green method was developed for rapid synthesis of silver and gold nanoparticles (AgNPs and AuNPs) has been reported using Lonicera japonica flower extract as a reducing and a capping agent. AgNPs and AuNPs were carried out at $70^{\circ}C$. The successful formation of AgNPs and AuNPs have been confirmed by UV-Vis spectro photometer, fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), energy dispersive X-ray Analysis (EDAX), scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM). To our knowledge, this is the first report where Lonicera japonica flower was found to be a suitable plant source for the green synthesis of AgNPs and AuNPs.

Constructing Landscape as an Operational Multi-Environmental Control Utility and Green Infrastructure - Landscape Design for National Marine Biology Resource Institute - (작동하는 복합환경조절장치 및 녹색기반시설로서 조경 - 국립해양생물자원관 옥외공간 설계 -)

  • Sung, Jongsang
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.15 no.2
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    • pp.41-56
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    • 2012
  • Landscape space can and should play as a multi-functional agent : healing contaminated soil, reducing natural hazards, supporting living things, making comfortable environment for human, and appealing to human aesthetics, etc. This article aims to show the possibility and role of landscape space as such agent. In landscape design for National Marine Biology Resource Institute, distributed rain water treatment system and rain gardens are introduced to replace a mono-functioning large detention pond which was suggested by disaster impact assesment. Phytoremediation and vegetation filtering system with muti-cell wetlands are also adapted to heal the contaminated soil. This kind of landscape as a 'living machine' which can play as an operational control utility of multi-environment and thus can be combined effectively into green infrastructure is important for post-industrial city, especially in an era of climate change.

The Importance of Essential-Oils in the Green Synthesis of Silver Nanoparticles

  • Barzinjy, Azeez Abdullah
    • Journal of the Korean Chemical Society
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    • v.66 no.4
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    • pp.284-297
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    • 2022
  • The antibacterial activity of metallic nanoparticles (NPs), especially silver (Ag), has been investigated during the course of time in various chemical reactions for antibiotics free agents. Green synthesis of metallic NPs using either microorganisms or plant-extracts has appeared as a simple and replacement to chemical and physical methods. The synthesizing of these NPs through ecofriendly methods signifies an exceedingly applicable approach for offering economical, preferring scalability and possessing negligible ecological influences. Essential-oils are among the subordinate metabolites of plants and their antibacterial anti-inflammatory characteristics have been investigated widely and are commonly attained from the aromatic plants. The usage of essential-oils as reducing agents in biosynthesizing of Ag NPs bring together the interaction of a vital antibacterial agent that simplify the nucleation and growth process within the NPs formation. This review article is offering a progressive process of Ag NPs synthesis using essential oils along with proposing the most applicable formation mechanisms and their antibacterial activities.

Study on Tribo-chemistry Properties of Some Additives on Base Oils of Friendly Environmentally Lubricants

  • Bin, Ye;De-hua, Tao
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.263-264
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    • 2002
  • The tribological characteristic of several environmentally friendly lubricating base stocks was examined, and the effect of some commonly used additives on th tribological behavior of the lubricating oils was comparatively investigated on a four-ball machine. It has been found that the commercial additives including butene sulfide, wax chloride, zinc dialkyldithiophosphate and ashless P-N type agent helped to improve the friction-reducing and antiwear properties as well as the extreme pressure behavior. Non-toxic nanoscale $(CF)_x$ showed the best friction-reducing ability, though it registered relatively poor extreme pressure properties. The mechanism on friction of nano-scale material is discussed.

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