• Journal of the Korean Ceramic Society
• /
• v.16 no.4
• /
• pp.237-242
• /
• 1979

In order to improve hydration reactivity of blast furnace slag, it's composition was changed by adding of CaO. The slags were quenched in water at 1,400℃. Hydration reactivityof modified slags was studied by x-ray diffractometer, conduction calorimeter and so on. Experimental results were summarized as follows. 1. Glass content and hydration reactivity of slag depend significantly on quenching temperature of the slag melt. To enhance the reactivity, slag melts which belongs to Frenkel-type liquid, must be quenched above 1,300℃. 2. Vitrification of slag melts was confirmed as CaO/SiO2 ratio increased up to 1.57 with flux, 1.51 without flux, also their hydration reactivity was improved.

• Journal of the Korean Ceramic Society
• /
• v.17 no.3
• /
• pp.158-162
• /
• 1980

The experiments of suspension hydration were performed in the mixtures of slag and water or NaOH solutions which were made up with a liquid/solid ratio of 10. The liquid phase of the suspension was chemically analysed and discussed. When slag was in contact with water, CaO component was released from slag grains into the solution. The amounts of $SiO_2$ and $Al_2O_3$ liberated in the solution were very low as compared with CaO, for the impermeable coating of $SiO_2$, $Al_2O_3$-rich gel was formed on the surface of slag grains. The hydration was considered to be inhibited by this impermeable coating. The weak hydraulic property of slag was based on slowly released CaO and dissolved Na, K components which increased pH in the solution.

• Korean Journal of Materials Research
• /
• v.13 no.2
• /
• pp.94-100
• /
• 2003

The interface between low carbon steel and blended cement pastes containing slag was investigated using impedance spectroscopy. In addition, the pastes were characterized by several analytical methods (XRD, EDX, electrode potential, pH and ICP). The electrical behavior of the interface in the blended slag systems is correlated to its corresponding pore solution chemistry and the products present in the interface. Passivation occurred at the paste/steel interfaces, in cement pastes up to containing from 0 to 75% slag content. 100% slag paste induced corrosion of the low carbon steel, which could be explained by the influence of sulfur on the system.

• International Journal of Concrete Structures and Materials
• /
• v.9 no.3
• /
• pp.381-390
• /
• 2015

Investigating the microstructure of hardened cement mixtures with the aid of advanced technology will help the concrete industry to develop appropriate binders for durable building materials. In this paper, morphological, mineralogical and thermogravimetric analyses of autoclave-cured mixtures incorporating ground dune sand and ground granulated blast furnace slag as partial cementing materials were investigated. The microstructure analyses of hydrated products were conducted using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), differential thermal analysis (DTA), thermo-graphic analysis (TGA) and X-ray diffraction (XRD). The SEM and EDX results demonstrated the formation of thin plate-like calcium silicate hydrate plates and a compacted microstructure. The DTA and TGA analyses revealed that the calcium hydroxide generated from the hydration binder materials was consumed during the secondary pozzolanic reaction. Residual crystalline silica was observed from the XRD analysis of all of the blended mixtures, indicating the presence of excess silica. A good correlation was observed between the compressive strength of the blended mixtures and the CaO/$SiO_2$ ratio of the binder materials.

• Journal of the Korea Institute of Building Construction
• /
• v.18 no.6
• /
• pp.527-532
• /
• 2018

The objective of the present study is to evaluate a practical approach for enhancing the compressive strength and minimizing deforming of aerated concrete. Test results measured in the aerated concrete mixes that were produced using 40% ground granulated blast-furnace slag (GGBS) as a replacement of cement and cured under different conditions (i.e., high temperatures of $40^{\circ}C$ and $60^{\circ}C$ for 10 hrs or 15 hrs) were compared with those obtained from the specimens cured under room temperature. No deforming was observed in the mixes with 40% GGBS. The compressive strength of the prepared aerated concrete cured under high temperature was higher than that of the concrete cured at room temperature, even at the lower ranges of the apparent dry density. However, the curing time is needed to be controlled as not exceeding 10 hrs at the temperature of $60^{\circ}C$ to prevent the decrease in the compressive strength due to foam mergences.

• International Journal of Highway Engineering
• /
• v.13 no.2
• /
• pp.85-93
• /
• 2011

This study experimented to evaluate the environment friendly high performance ternary cement concrete deck overlay pavement using mineral admixture such as fly ash and ground granulated blast-furnace slag. It was measured to find best binder mixing according to replacement rate of mineral admixture with compressive strength and flexural strength. After finding best binder, it is also experimented to evaluate durability on chloride penetration resistance, freezing- thawing resistance, scaling resistance of deicing chemicals, abrasion resistance, alkali-silica reactivity test and bonded environment friendly high performance ternary cement concrete deck overlay pavement experimented to evaluate bonded old deck and new concrete overlay pavement using special polymer cement mortar. In additions, bonded environment friendly high performance ternary cement concrete deck overlay pavement by experimental construction was evaluated at interchange bridge of North Yeoju. Result, examination was indicated better binding with binder replacement of cement 70%, ground granulated blast-furnace slag 15% and fly ash 15%. And special polymer cement mortar used in old deck and new overlay concrete was indicated better bonding both laboratory and construction.

• Journal of the Korea Concrete Institute
• /
• v.27 no.3
• /
• pp.245-252
• /
• 2015

As people have more interest in environment-friendly structures recently, many researchers are actively researching non-sintered cement in Korea and other countries. Non-sintered cement shows various characteristics of its reaction products and hardeners, depending on the kind of alkali activators. Thus, this study manufactures ground granulated blast furnace slag based non-sintered cement binder by using circulating fluidized bed combustion ash, which is a kind of industrial byproduct, as a stimulant, and investigated its hardening characteristics and hydration, depending on the rate of circulating fluidized bed combustion ash. Besides, this study investigated its insulation property according to the weight lightening of non-sintered cement. As a result, ettringite and C-S-H were mainly formed in the hydration, and it was possible to manufacture a non-sintered cement hardener over 50 MPa. Lastly, it was possible to manufacture a non-sintered cement hardener in a thermal conductivity level of $0.127W/m{\cdot}K$ when the compressive strength was 10 MPa for weight lightening.

• Journal of the Korea Institute of Building Construction
• /
• v.18 no.5
• /
• pp.439-446
• /
• 2018

The PHC pile has been increasingly used due to its implementation of the top-base method, which is advantageous in high penetration rate and bearing capacity reinforcement. Typically, when a PHC pile is manufactured, high-strength mixed materials are mainly used to enhance the compressive strength. However, recent studies have been conducted to utilize ground granulated blast-furnace slag (GGBS) in terms of economic efficiency. For this reason, this study manufactured PHC pile considering the replacement ratio and curing conditions of GGBS instead of high-strength mixed materials, and further investigated the engineering properties of the PHC pile. According to the experimental results, the compressive strength of GGBS-replaced PHC pile increased by steam curing, and particularly, PHC pile with 20% replacement of GGBS under $80^{\circ}C$ steam curing condition showed a compressive strength of approximately 84MPa. Furthermore, the experimental results confirmed that more hydration products were generated under the $80^{\circ}C$ steam curing condition than that under the $20^{\circ}C$ steam curing condition, which would affect the higher density of the PHC pile as well as the increase in the compressive strength.

• Journal of the Korea Concrete Institute
• /
• v.15 no.3
• /
• pp.400-408
• /
• 2003

Chloride ion inside concrete destroys the so-called passive film surrounding reinforcing bars inside concrete so that the so-called salt attack accelerates corrosion which is the most critical factor for durability as well as structural safety of reinforced concrete structures. Recently, as a solution of the salt attack, the ground granulated blast-furnace slag(GGBFS) have been used as binder or blended cement more extensively. In this paper, characteristics of chloride ion diffusion for the GGBFS concrete, which is known to possess better resistance to damage due to the chloride ion penetration than ordinary portland cement(OPC) concrete possesses, are analyzed and a chloride ion diffusion model for the GGBFS concrete is proposed by modifying an existing diffusion model for the OPC concrete. The proposed model is verified by comparing diffusion analysis results using the model accelerated chloride penetration test results for concrete specimens as well as field test results for an RC bridge pier. Then, an optimal resistance condition to chloride penetration for the GGBFS concrete is obtained according to degrees of fineness and replacement ratios of the GGBFS concrete. The result shows that the GGBFS concrete has better resistance to chloride ion penetration than OPC concrete has and the resistance is more affected by the replacement ratio than the degree of fineness of the GGBFS.

• Journal of the Korea Concrete Institute
• /
• v.23 no.1
• /
• pp.49-55
• /
• 2011

The distresses of alkali-silica reaction (ASR) was recently reported at highway cement concrete pavement in Korea, which showed typical cracking and spalling patterns of ARS. Korea is was no longer safe zone against ASR, needding to find a control methodology against ASR. The purpose of this research was to provide a control methodology against ASR using mineral admixtures through a series of laboratory test program. Laboratory works included the accelerated mortar bar test (AMBT) by ASTM C 1260 regulation with five types of aggregate and three types of mineral admixtures (fly ash, ground granulated blast-furnace slag and silica fume). The result of ASTM C 1260 test for five types of aggregates without mineral admixtures showed that Siltstone and Mudstone were found to be "reactive." Tuff and Andesite-1 were found to be "possiblely reactive." In case of concrete mixed with 10, 20, and 30% fly ash, all specimens except Mudstone mixed with 10% FA were found to be "non-reactive". In cases of concrete mixed with 30, 40, and 50% ground granulated blast-furnace slag and 5, 7.5, and 10% silica fume, all specimens were found to be "non-reactive." These results could be selectively applied in constructions in Korea.