• Journal of Magnetics
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• 제10권1호
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• pp.14-22
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• 2005

Precisely refined Mossbauer study and nano structure observation revealed that intergranular phase formed between a-Fe and Nd₂Fe₁₄B phase in NdFeNbB alloys plays a significant role on the magnetic properties. The intergranular interaction was characterized in term of Henkel Plot (δM plot), and hyperfine field, quardrupole splitting and isomer shift were refined to predict the presence and role of the intergranular phase. By the addition of Nb into Nd₈Fe₈₆B₆ composition, coercivity was found to increase by 25% due to the refinement of average grain size of both the soft and hard magnetic phases which was decreased from 50 nm of virgin Nd/sub 8/Fe/sub 86/B/sub 6/ to 25 nm in Nd₈Fe ₈₅Nb₁B₆ alloys. The role of Nb addition was confirmed to stabilize the Nd₂Fe₁₄B lattice preventing from thermal vibration of the corresponding sites substituted Fe by Nb atoms in all sites in the Nd₂Fe₁₄B lattice. The enhanced coercivity was originated from the exchange hardening of soft and amorphous phases surrounding the hard magnetic Nd₂Fe₁₄B crystal.

• Nuclear Engineering and Technology
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• 제49권1호
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• pp.178-188
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• 2017

To study the effects of zirconium (Zr) addition on the microstructure, hardness and the tensile properties of oxide dispersion strengthened (ODS) ferritic-martensitic steels, two kinds of 9Cr-ODS ferritic-martensitic steels with nominal compositions (wt.%) of $Fe-9Cr-2W-0.3Y_2O_3$ and $Fe-9Cr-2W-0.3Zr-0.3Y_2O_3$ were fabricated by the mechanical alloying (MA) of premixed powders and then consolidated by hot isostatic pressing (HIP) techniques. The experimental results showed that the average grain size decreases with Zr addition. The trigonal ${\delta}$-phase $Y_4Zr_3O_{12}$ oxides and body-centered cubic $Y_2O_3$ oxides are formed in the 9Cr-Zr-ODS steel and 9Cr non-Zr ODS steel, respectively, and the average size of $Y_4Zr_3O_{12}$ particles is much smaller than that of $Y_2O_3$. The dispersion morphology of the oxide particles in 9Cr-Zr-ODS steel is significantly improved and the number density is $1.1{\times}10^{23}/m^3$ with Zr addition. The 9Cr-Zr-ODS steel shows much higher tensile ductility, ultimate tensile strength and Vickers hardness at the same time.

• 대한치과보철학회지
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• 제59권2호
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• pp.248-260
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• 2021

코발트-크롬 합금은 다양한 치과보철물 제작에 이용되고 있고, 다른 합금에 비해 저렴한 가격과 우수한 기계적 특성이 장점이다. 최근, 기존 제작 방식의 단점을 극복하기 위해 적층제조 방식인 선택적 레이저 용융 방법이 보철물 제작에 이용되고 있다. 선택적 레이저 용융 방법의 공정 중 급속 가열과 냉각 과정은 제작된 합금의 미세구조와 결정립을 미세화하고, 기포를 감소시켜 기존 제작 방식에 의한 합금에 비해 기계적 특성을 향상시킨다. 반면, 적층과 급속 가열 및 냉각은 다량의 잔류응력 축적을 초래하는데, 추후 기계적 특성에 악영향을 미칠 수 있다. 따라서, 잔류응력을 제거하기 위해 주로 열처리를 시행하고, 회복과 재결정화에 의한 잔류응력의 감소뿐만 아니라 상변태, 석출물 및 미세구조의 균질화가 동반되어 기계적 특성의 복잡한 변화가 나타난다. 본 문헌고찰에서 코발트-크롬 합금의 제작 방식 비교 및 선택적 레이저 용융 방법으로 제작된 합금의 특징에 대해 알아보고자 한다.

• Corrosion Science and Technology
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• 제18권1호
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• pp.1-7
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• 2019

To find proper lathe machining parameters for SA182 Grade 304 stainless steel (SS), six kinds of samples with different machining surface states were prepared using a lathe. Surface morphologies and microstructures of near surface deformed layers on different samples were analysed. Surface morphologies and chemical composition of oxide films formed on different samples in simulated primary water with $100{\mu}g/L\;O_2$ at $310^{\circ}C$ were characterized. Results showed that surface roughness was mainly affected by lathe feed. Surface machining caused grain refinement at the top layer. A severely deformed layer with different thicknesses formed on all samples. In addition to high defect density caused by surface deformation, phase transformation, residual stress, and strain also affected the oxidation behaviour of SA182 Grade 304 SS in the test solution. Machining parameters used for # 4 (feed, 0.15 mm/r; back engagement, 2 mm; cutting speed, 114.86 m/min) and # 6 (feed,0.20 mm/r; back engagement, 1 mm; cutting speed, 73.01 m/min) samples were found to be proper for lathe machining of SA182 Grade 304 SS.

• Metals and materials international
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• 제24권6호
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• pp.1376-1385
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• 2018

Ultrasonic melt treatment (UST) was applied to an A390 hypereutectic Al-Si alloy in a temperature range of $750-800^{\circ}C$ and its influence on the solidification structure and the consequent increase in strength was investigated. UST at such a high temperature, which is about $100^{\circ}C$ above the liquidus temperature, had little effect on the grain refinement but enhanced the homogeneity of the microstructure with the uniform distribution of constituent phases (e.g. primary Si, ${\alpha}-Al$ and intermetallics) significantly refined. With the microstructural homogeneity, quantitative analysis confirmed that UST was found to suppress the formation of Cu-bearing phases, i.e., $Q-Al_5Cu_2Mg_8Si_6$, $Al_2Cu$ phases that form in the final stage of solidification while notably increasing the average Cu contents in the matrix from 1.29 to 2.06 wt%. A tensile test exhibits an increase in the yield strength of the as-cast alloy from 185 to 208 MPa, which is mainly associated with the solute increment within the matrix. The important role of UST in the microstructure evolution during solidification is discussed and the mechanism covering the microstructure-strengthening interrelationship of the ultrasonically treated A390 alloy is proposed.

• Tribology and Lubricants
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• 제34권6호
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• pp.270-278
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• 2018

STS 316L prepared by additive manufacturing (AM) exhibits deterioration of mechanical properties and wear resistance due to the presence of defects such as black-of-fusion defects, internal porosity, residual stress, and anisotropy. In addition, high surface roughness (integrity) of AM products remains an issue. This study aimed to apply ultrasonic nanocrystal surface modification (UNSM) technology to STS 316L prepared by AM to increase the surface hardness, to reduce the surface roughness, and to improve the friction and wear behavior to the level achieved by bulk material manufactured using traditional processes. Herein, the as-received and polished specimens were treated by UNSM technology and their resulting properties were compared and discussed. The results showed that UNSM technology increased the surface hardness and reduced the surface roughness of the as-received and polished specimens. These results can be attributed to grain size refinement and pore elimination from the surface. Moreover, the friction of the as-received and polished specimens after UNSM technology was lower compared to those of the as-received and polished specimens, but no significant differences in wear resistance were found.

• Tribology and Lubricants
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• 제35권3호
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• pp.176-182
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• 2019

The primary objective of this study is to treat a monocrystalline silicon (Si) wafer having a thickness of $279{\mu}m$ by employing the ultrasonic nanocrystal surface modification (UNSM) technology for improving the efficiency and service life of nano-electromechanical systems (NEMSs) and micro-electromechanical systems (MEMSs) by enhancing of wear and corrosion resistances. The wear and corrosion resistances of the Si wafer were systematically investigated before and after UNSM treatment, wherein abrasive, oxidative and spalling wear mechanisms were applied to the as-received and subsequently UNSM-treated Si wafer. Compared to the asreceived state, the wear and corrosion resistances of the UNSM-treated Si wafer are found to be enhanced by about 23% and 14%, respectively. The enhancement in wear and corrosion resistances after UNSM treatment may be attributed to grain size refinement (confirmed by Raman spectroscopy) and modified surface integrity. Furthermore, it is observed that the Raman intensity reduced significantly after UNSM treatment, whereas neither the Raman shift nor new phases were found on the surface of the UNSM-treated Si wafer. In addition, the friction coefficient values of the as-received and UNSM-treated Si wafers are found to be about 0.54 and 0.39, respectively. Hence, UNSM technology can be effectively incorporated as an alternative mechanical surface treatment for NEMSs and MEMSs comprising Si wafers.

• 대한금속재료학회지
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• 제46권9호
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• pp.545-553
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• 2008

Dynamic deformation behavior of ultra-fine-grained pure coppers fabricated by equal channel angular pressing (ECAP) was investigated in this study. Dynamic torsional tests were conducted on four copper specimens using a torsional Kolsky bar, and then the test data were analyzed by their microstructures and tensile properties. The 1-pass ECAP'ed specimen consisted of fine dislocation cell structures elongated along the ECAP direction, which were changed to very fine, equiaxed subgrains of 300~400 nm in size as the pass number increased. The dynamic torsional test results indicated that maximum shear stress increased with increasing ECAP pass number. Adiabatic shear bands were not found at the gage center of the dynamically deformed torsional specimen of the 1- or 4-pass ECAP'ed specimen, while some weak bands were observed in the 8-pass ECAP'ed specimen. These findings suggested that the grain refinement according to the ECAP was very effective in strengthening of pure coppers, and that ECAP'ed coppers could be used without serious reduction in fracture resistance under dynamic torsional loading as adiabatic shear bands were hardly formed.

• Nuclear Engineering and Technology
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• 제54권6호
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• pp.1972-1981
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• 2022

A typical ferritic/martensitic (F/M) steel sheet was subjected to pulsed laser surface remelting (LSR) and corrosion test in lead-bismuth eutectic (LBE) at 550 ℃. There present two modification zones with distinct microstructures in the LSRed specimen: (1) remelted zone (RZ) consisting of both bulk δ-ferrite grains and martensitic plates and (2) heat-affected zone (HAZ) below the RZ, mainly composed of martensitic plates and high-density precipitates. Martensitic transformation occurs in both the RZ and the HAZ with the Kurdjumov-Sachs and Nishiyama-Wassermann orientation relationships followed concurrently, resulting in scattered orientations and specific misorientation characteristics. Hardnesses of the RZ and the HAZ are 364 ± 7 HV and 451 ± 15 HV, respectively, considerably higher than that of the matrix (267 ± 3 HV). In oxygen-saturated and oxygen-depleted LBE, thicknesses of oxide layers developed on both the as-received and the LSRed specimens increase with prolonging corrosion time (oxide layers always thinner under the oxygen-depleted condition). The corrosion resistance of the LSRed F/M steel in oxygen-saturated LBE is improved, which can be attributed to the grain-refinement accelerated formation of dense Fe-Cr spinel. In oxygen-depleted LBE, the growth of oxide layers is very low with both types of specimens showing similar corrosion resistance.

• 한국결정성장학회지
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• 제33권6호
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• pp.282-287
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• 2023

본 연구에서는 Laser Powder bed fusion(L-PBF) 공정을 사용하여 제작된 Ti-6Al-4V 합금 적층성형품의 응력제거 열처리 온도와 시간의 변화에 따른 미세조직, 잔류응력 그리고 경도의 변화를 연구하였다. 잔류응력 제거를 위한 열처리 시험 결과 823 K에서는 240분, 873K에서는 60분 이상 열처리시 치수변화 및 기계적 특성 저하를 야기하는 결정립 성장 및 상변화 발생 없이 대부분의 잔류응력이 3 0 MPa 이하로 감소되는 것을 확인하였다. 또한, 열처리 온도 및 시간의 증가와 함께 경도가 증가하는 경향을 보였다. 이러한 결과는 XRD 및 SEM-EBDS의 phase map 분석을 통해 확인되지 않지만, 773~873 K 온도범위에서 등온 열처리시 국부적인 침상 Martensitic α' 상의 미세화가 원인으로 추정된다.