• Title/Summary/Keyword: geochemical analysis

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Developmental Characteristics and Weathering Processes of Tafoni at Golgulsa Temple, Gyeongju, South Korea (경주 골굴사 타포니의 발달 특성과 풍화 과정)

  • Shin, Jae Ryul;Choo, Chang Oh;Lee, Jin Kook;Park, Kyung Geun
    • Journal of the Korean association of regional geographers
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    • v.23 no.1
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    • pp.168-177
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    • 2017
  • In order to reveal formation factors and developmental processes of tafoni this study was conducted with petrological analysis including microscopic observation, measurement of water content and water analysis at Golgulsa temple in Gyeongju, South Korea. The direction of the entrance to tafoni at Golgulsa temple tends to coincide with the direction of slope, and this is thought to be related to the direction of wind flow and water supply. Tafoni's initial developmental processes is judged to have grown as a result of a breakaway of rock fragments along with beddings and cracks in rock. Then, tafoni have been enlarged along at the spots that sufficiently accommodate water supply depending on the direction of wind. The results of water analysis of the stagnant water in gnamma implies that a high meltage of Na and Cl compared to other inland areas can be from the adjacent shore. The effects of such saline substances on rock weathering and development of taponi are currently under way through electronic microscopy and geochemical analysis.

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Understanding of Surface Water-Groundwater Connectivity in an Alluvial Plain using Statistical Methods (통계기법을 활용한 충적층내 지하수-지표수 연계 특성 해석)

  • Kim, Gyoo-Bum;Son, Young-Chul;Lee, Seung-Hyun;Jeong, An-Chul;Cha, Eun-Jee;Ko, Min-Jeong
    • The Journal of Engineering Geology
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    • v.22 no.2
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    • pp.207-221
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    • 2012
  • A statistical analysis of time series of water level at 27 groundwater monitoring wells was conducted to analyze the surface water-groundwater connectivity in the wide alluvial plains surrounding the Nakdong River, Korea. Change in groundwater level is strongly related to river water level, yielding an average cross-correlation coefficient of 0.601, which is much higher than that between rainfall and groundwater level (0.125). Principal component analysis of groundwater level indicates that wells in the study area can be classified into two groups: wells in Group A are located close to a river, have water levels closely related to river level, and generally show a large increase in groundwater level during heavy rainfall. On the other hand, wells in Group B located far from a river are relatively less related to river level. Including hydrologic and statistical analyses, geochemical analysis and temperature monitoring are additionally required to reveal the relationship between surface water level and groundwater level, and to assess the possibility of groundwater flooding.

The Effects of Bed-rock Formations on Water Quality and Contamination : Statistical Approaches (수자원의 수질과 오염에 대한 기반암의 영향 연구 : 통계학적 접근)

  • 이병선;우남칠
    • Economic and Environmental Geology
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    • v.36 no.6
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    • pp.415-429
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    • 2003
  • This study was objected to identify the difference of water quality and the characteristics of water contamination in adjacent bed-rock areas of Upper Hwajeonni and Guryongsan Formations in Miwon, Choongchungbuk-do, Korea. Water samples showed mainly (Ca, Mg)-$HCO_3$ type in Upper Hawjeonni Formation and (Ca, Mg)-$SO_4$ and (Ca, Mg)-$HCO_3$ types in Guryongsan Formation indicating the enrichment of $SO_4$ in major compositions. Groundwater quality could be divided into two groups based on the major weathering processes, implied by the ratio of bicarbonate to silica. Carbonate-silicate weathering predominates in Upper Hwajeonni Formation, and silicate weathering in Guryongsan Formation. Stream-water quality also appeared to be controlled by water-rock interaction. Cluster analysis identified three groups of groundwater and four groups of stream-water with distinctive geochemical characteristics. The results of factor analysis indicated that the levels of each chemical constituent in water samples derived from both natural weathering reactions and anthropogenic contamination sources. To delineate the pollution potential of water resources, Modified Pollution Index(M.P.I.) was developed. M.P.I. scores of water samples ranged from -0.08 to 0.18, with mostly positive along the rock quarry in Guryongsan Formation areas. M.P.I. scores appeared to be a useful predictor of metal contamination of water resources.

Application of Laser-Induced Breakdown Spectroscopy (LIBS) for In-situ Detection of Heavy Metals in Soil (토양내 중금속 실시간 탐지를 위한 레이저 유도붕괴 분광법의 활용에 대한 소개)

  • Ko, Eun-Joung;Hamm, Se-Yeong;Kim, Kyoung-Woong
    • Economic and Environmental Geology
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    • v.40 no.5
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    • pp.563-574
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    • 2007
  • Laser induced breakdown spectroscopy (LIBS) is a recently developed analytical technique that is based upon the measurement of emission lines generated by atomic species close to the surface of the sample, thus allowing their chemical detection, identification and quantification. With powerful advantages of LIBS compared to the conventional analytical methodology, this technique can be applied in the detection of heavy metals in the field. LIBS allows the rapid analysis by avoiding laborious chemical steps. LES have already been applied for the determination of element concentration in a wide range of materials in the solid, liquid and gaseous phase with simplicity of the instrument and diversity of the analytical application. These feasibility of rapid multi elemental analysis are appealing proprieties for the in-situ analytical technique in geochemical investigation, exploration and environmental analysis. There remain still some limitations to be solved for LIBS to be applied in soil environment as an in-situ analytical technology. We would like to provide the basic principle related to the plasma formation and laser-induced breakdown of sample materials. In addition, the matrix effect, laser properties and the various factors affecting on the analytical signal of LIBS was dealt with to enhance understanding of LIBS through literature review. Ultimately, it was investigated the feasibility of LIBS application in soil environment monitoring by considering the basic idea to enhance the data quality of LIBS including the calibration method for the various effects on the analytical signal of LIBS.

GIS-based Spatial Integration and Statistical Analysis using Multiple Geoscience Data Sets : A Case Study for Mineral Potential Mapping (다중 지구과학자료를 이용한 GIS 기반 공간통합과 통계량 분석 : 광물 부존 예상도 작성을 위한 사례 연구)

  • 이기원;박노욱;권병두;지광훈
    • Korean Journal of Remote Sensing
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    • v.15 no.2
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    • pp.91-105
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    • 1999
  • Spatial data integration using multiple geo-based data sets has been regarded as one of the primary GIS application issues. As for this issue, several integration schemes have been developed as the perspectives of mathematical geology or geo-mathematics. However, research-based approaches for statistical/quantitative assessments between integrated layer and input layers are not fully considered yet. Related to this niche point, in this study, spatial data integration using multiple geoscientific data sets by known integration algorithms was primarily performed. For spatial integration by using raster-based GIS functionality, geological, geochemical, geophysical data sets, DEM-driven data sets and remotely sensed imagery data sets from the Ogdong area were utilized for geological thematic mapping related by mineral potential mapping. In addition, statistical/quantitative information extraction with respective to relationships among used data sets and/or between each data set and integrated layer was carried out, with the scope of multiple data fusion and schematic statistical assessment methodology. As for the spatial integration scheme, certainty factor (CF) estimation and principal component analysis (PCA) were applied. However, this study was not aimed at direct comparison of both methodologies; whereas, for the statistical/quantitative assessment between integrated layer and input layers, some statistical methodologies based on contingency table were focused. Especially, for the bias reduction, jackknife technique was also applied in PCA-based spatial integration. Through the statistic analyses with respect to the integration information in this case study, new information for relationships of integrated layer and input layers was extracted. In addition, influence effects of input data sets with respect to integrated layer were assessed. This kind of approach provides a decision-making information in the viewpoint of GIS and is also exploratory data analysis in conjunction with GIS and geoscientific application, especially handing spatial integration or data fusion with complex variable data sets.

Prehistoric subsistence and pottery use in the ancient Korean Peninsula: New evidence from organic geochemical analysis of potsherds (토기 내 잔존유기물을 활용한 한반도 선사·고대의 토기 사용과 식생활에 관한 연구)

  • Kwak, Seungki;Shin, Sookjung
    • Korean Journal of Heritage: History & Science
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    • v.52 no.3
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    • pp.146-159
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    • 2019
  • This study focuses on the understanding of human subsistence and pottery use during ancient times on the Korean peninsula through lipid analysis of potsherds from several major prehistoric settlement sites. Ancient human subsistence has been one of the long-standing topics in Korean archaeology. However, since the high acidity of sediments does not allow long-term preservation of organic remains, we still lack some critical information related to the prehistoric diet. Pottery contains relatively well-preserved organic remains created during past cooking events. Though pottery is one of the most studied material cultures in Korean archaeology, almost no attention has been given to analyzing the pottery itself. This is a surprising omission and represents a serious gap in our understanding of prehistoric technology and subsistence. The analysis of ancient lipids extracted from the pottery matrix using GC-MS and isotope analysis can contribute to our understanding of the true nature of past subsistence strategies. Potsherd samples for the analyses in this study were collected from six prehistoric and early historic settlement sites located in the central part of the Korean peninsula. The results showed that subsistence strategies differed by both location and time period. For example, at Jungdo, an inland open-air Bronze Age settlement site in Chuncheon City, we were able to see the presence of terrestrial mammals. At Gahak-dong, Gwangmyeong City, marine resources were utilized, as the location of the site is not far from the coastline. At the early historic site of Guwol-dong, Incheon City, we were able to detect dairy products. The results of this study suggest that there was utilization of a wider range of resources among ancient dwellers in the central part of the Korean peninsula.

Burial Age and Flooding-origin Characteristics of Coastal Deposits at Gwangseungri, Gochanggun, Korea (고창군 광승리 연안 퇴적층의 퇴적 시기와 범람 기원 특성)

  • Kim, Jong Yeon;Yang, Dong Yoon;Shin, Won Jeong
    • Journal of the Korean earth science society
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    • v.36 no.3
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    • pp.222-235
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    • 2015
  • Samples were collected from both places including the coastal area within the height of 5 m above the mean sea level (msl) (DH) and the top of the coastal terrace of 10-15 m msl (KS) high in Gwangseungri, Gochanggun, Korea. To find the origin of the deposit in the coastal area, granulometric analysis and geochemical analysis were performed. The result showed that the DH samples were originated from the reddish soils overlaying weathered bedrock which presented gradual change of chemical composition from the bottom toward the top. Clay minerals were found from the DH samples. These results concluded that the DH samples were found as in-situ weathered materials. The KS samples were originated from the soil layer covering gravel layer at the foot slope of the hill along the coast. The KS samples contained different chemical compositions from the DH. It is inferred that some of this layer was disturbed or experienced the influx of foreign material. The particle size of the KS samples was different from those found on the beach. The particle size of lower parts of KS site was finer than that on the beach, but the particle size of middle part of the site was coarser than that on the beach. The sorting of the KS site was poorer than that on the beach. Thus, it is inferred that some parts of the layer were formed by short-lived high energy event rather than sustained and continuous action of tidal currents and/or waves. Analysis using an optically stimulated luminescence (OSL) method showed that the burial age of samples from KS site were found 0.65-0.71 ka. Though the characteristics of the sediment layer and forming event in this area should be further studied, it can be inferred that this sedimentary layer formed by coastal flooding with storm.

Geostatistical Interpretation of Cs-137 and K-40 Result of the Lithosphere in the Vicinity of Youngkwang Nuclear Power Plant (지구통계학적 방법에 의한 영광원전주변 토층내 Cs-137 및 K-40 측정 결과의 해석)

  • 김경웅;이재석;문승현;박철승;고일원;고은정;조병옥;정철영;전수열
    • Economic and Environmental Geology
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    • v.35 no.6
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    • pp.545-552
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    • 2002
  • In order to investigate the influence of nuclear power plant operation on its nearby environment, soil, stream and marine sediment samples were collected in the vicinity of the Youngkwang Nuclear Power Plant in Korea, and analyzed for artificial and natural radionuclide radioactivity. From the analytical result, Cs-137 was detected in most soil samples. but it may have been derived fiom past nuclear weapon tests because Cs-134 having short half-live was not detected. The radioactivities of Cs-137 in the sediment samples were also detected which are within the normal range in the sediments based upon the published literature between 1997 and 1999. For the quality control of radioactivity analysis of environmental samples, sets of marine sediments in the Gamami area were analyzed using two HPGe Gamma-ray Spectroscopes (30% and 45%) according to the geostatistical sampling strategy, and Cs-137 and K-40 results were interpreted by analysis of variance (ANOVA). In the two-way ANOVA, variances derived from the geochemical variation were significant, but errors from sampling and analytical procedures are negligible. In conclusion. all the radioanalytical procedures of this study including sampling are validated to be acceptable.

Natural Background and Enrichment Characteristics of the Stream Sediments from the Hamyang-Sancheong Area (함양-산청지역 하상퇴적물의 자연배경치 및 부화특성)

  • Park, Young-Seog;Park, Dae-Woo;Kim, Jong-Kyun
    • Economic and Environmental Geology
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    • v.42 no.3
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    • pp.195-206
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    • 2009
  • We investigated natural background and enrichment characteristics and predicted geochemical disaster for stream sediments in the Hamyang-Sancheong area. Stream sediments samples were collected 95 ea in study area. The stream sediments were well known that had not possibility of contamination effect and represented drainage basins. We got the major and hazardous elements concentrations by XRF, ICP-AES and NAA analysis methods. Acid decomposition for the ICP-AES has been used $HClO_4$ and HF with $200^{\circ}C$ heating at 1st and after that $HClO_4$ HF and HCl with $200^{\circ}C$ heating at 2nd stage. We could know the characteristics that concentration of Cu and Co decreased when concentration of $SiO_2$ increased in correlation analysis. The enrichment factor of the stream sediments was below 2 in study area. This result indicated that study area belonged to moderate enrichment. The stream sediments of Hamyang area were enriched in order of Pb>Th>Cr>V>Co>Cu and those of Sancheong area were enriched in order of Pb>Th>Cr>Co>V>Cu. The enrichment factor(E.F.) of the Pb, Cr, Co and V was similar between Hamyang and Sancheong area. The enrichment factor of the Th was higher in Hamyang area and that of the Cu was higher in Sancheong area. The enrichment factor of the Pb was highly enriched in all study area than earth crust mean. But we could know that study area was not exposed to the pollution of the Pb through the tolerable level.

A Role of Standard Material in Rare Earth Element Analysis by ICP-MS (ICP-MS를 이용한 희토류원소 분석시 표준시료의 선택이 미치는 영향)

  • Lee Seung-Gu;Kim Kun-Han;Song Yong Sun;Kim Yongje
    • The Journal of the Petrological Society of Korea
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    • v.14 no.4 s.42
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    • pp.237-250
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    • 2005
  • In order to clarify the effect of standard rock material in the chemical analysis of rare earth element abundance with ICP-MS, we measured rare earth element abundance of KIGAM granite standard rock material (KG-1), USGS granite standard rock material (G-2), GSJ granite standard rock materials (JG-1a and JG-2). In REE analysis, we used conventional calibration standard solutions, KG-1, JG-1a, JG-2 and G-2 as standard material, respectively. Chondrite-normalized LREE patterns of low granite standard material correspond well each other in the recommended value and the estimated value regardless of a kind of standard rock. However, the HREE patterns of the estimated value based on G-2 or JG-2 and the recommended value are different from each other. Such difference may be due to the wrong recommended value or a specific geochemical properly of the standard rock material itself, The chondrite-normalized REE patterns of four standard rock materials estimated on the basis of KG-1 or JG-1 a show little deviation compared to the those of the recommended values. This suggests that KG-1 and JG-1a may be a optimum standard material for granitoids.